Observation of Pore Spaces and Microcracks Using a Fluorescent Technique in Some Reservoir Rocks of Oil, Gas and Geothermal Fields in the Green Tuff Region, Japan

Abstract: Pore spaces and microcracks in representative oil, gas and geothermal reservoir rocks from the Green Tuff region, Japan, were examined using a fluorescent technique. This technique was developed to visualize microscopically pore spaces and microcracks filled with synthetic resin mixed with fluorescent paint under ultraviolet light. Various morphology of pore spaces and microcracks was clearly identified. Spaces in studied reservoir rocks are classified into following three types: pore spaces in matrix, pore spaces in particles, and microcracks. It is observed that valuable oil and gas reservoir rocks relatively include many pore spaces, while microcracks are important for geothermal rocks. Correlation between textural characteristics and porosity or permeability was found in the oil reservoir rocks. Effective permeability depends upon pore spaces in matrix more than upon other components such as pore spaces in particles and microcracks. Looseness in matrix caused by larger grain size of particles is strongly correlated with permeability. Pore spaces play an important role as a reservoir in oil and gas fields, but are less important in geothermal field. Instead, microcracks are important for geothermal reservoir system.     

A comparative study of the modelling of cement hydration and cement-rock laboratory experiments

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.     

Ionospheric currents and fields during the solar eclipse

We calculate electric fields and currents in the ionosphere during the solar eclipse. Three dimensional anisotropic and inhomogeneous conductivity distribution is taken into consideration. Electrical conductivity is assumed to be decreased by the solar eclipse, but winds are not altered. It is shown that the additional currents and fields due to the eclipse are essentially understood as those generated by the obstruction to Sq currents. However, the currents flow preferably in the region nearer to the noon meridian and at the Equator and partly escape through the field-aligned currents to the opposite hemisphere, and therefore the effect of the solar eclipse is also seen in the opposite hemisphere in the deformed shape.     

Observations of disks around protostellar sources with nobeyama millimeter array

We present results from a survey observation of circumstellar disks around protostellar sources associated with the Taurus molecular cloud. Our result shows that the 98 GHz continuum emission tends to be weaker for embedded sources than for visible T Tauri stars, which is consistent with our previous interpretation of disk formation. Direct observations of the formation of a centrifugally supported viscous accretion disk around HL Tau is discussed.     

High sensitivity SiO maser survey for mira variables

Simultaneous observations of the six transitions of SiO for 106 late-type stars were made. The SiO maser emission was detected in 83 stars. Thev=3 maser emission was detected in eight stars, and the²⁹SiOv=0 emission in six stars. The²⁹SiOv=0 emission is stronger and narrower than that of²⁸SiO, suggesting that the²⁹SiO emission is masing.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Local time variation of geomagnetic transfer functions

The local time (LT) variation of the geomagnetic transfer function at the 32-min period was examined for observatories distributed worldwide. Two distinct variation types (types 1 and 2) were found in the real part of A. Type 1 is conspicuous at lower latitudes and its seasonal variation is small, whereas type 2 is found at higher latitudes and has its maximum in summer. These two types of LT variation are seen globally and are conspicuous when solar activity is high. The amplitudes of both types of variation vary from 0.018 to 0.078, and are independent of the mean values at each observatory. These values are relatively small, but the amplitude of Chambon la Foret is larger than the mean value, which shows that Au changes its sign in local time. The amplitudes of type 1 and 2 variations decrease and increase with geomagnetic latitude, respectively. These features suggest that they are generated by some global external fields. The most probable cause is the Sq field, although the Dp field may contribute to type 1 variation. On the other hand, for the islands of the Pacific Ocean at low latitudes, such as Honolulu and Chichijima, the type 1 variation appears not in the real but in the imaginary part of A, which suggests that currents induced in the ocean also contribute to the local time variation.     

Seasonal variability in carbon demand and flux by mesozooplankton communities at subarctic and subtropical sites in the western North Pacific Ocean

We investigated seasonal changes in carbon demand and flux by mesozooplankton communities at subtropical (S1) and subarctic sites (K2) in the western North Pacific Ocean to compare the impact of mesozooplankton communities on the carbon budget in surface and mesopelagic layers. Fecal pellet fluxes were one order higher at K2 than at S1, and seemed to be enhanced by copepod and euphausiid egestion under high chlorophyll a concentrations. The decrease in pellet volume and the lack of any substantial change in shape composition during sink suggest a decline in fecal pellet flux due to coprorhexy and coprophagy. While respiratory and excretory carbon by diel migrants at depth (i.e., active carbon flux) was similar between the two sites, the actively transported carbon exceeded sinking fecal pellets at S1. Mesozooplankton carbon demand in surface and mesopelagic layers was higher at K2 than S1, and an excess of demand to primary production and sinking POC flux was found during some seasons at K2. We propose that this demand was met by supplementary carbon sources such as feeding on protozoans and fecal pellets at the surface and carnivory of migrants at mesopelagic depths.     

Seasonal changes in the mesozooplankton biomass and community structure in subarctic and subtropical time-series stations in the western North Pacific

Seasonal changes in mesozooplankton biomass and their community structures were observed at time-series stations K2 (subarctic) and S1 (subtropical) in the western North Pacific Ocean. At K2, the maximum biomass was observed during the spring when primary productivity was still low. The annual mean biomasses in the euphotic and 200- to 1000-m layers were 1.39 (day) and 2.49 (night) g C m^?2 and 4.00 (day) and 3.63 (night) g C m^?2, respectively. Mesozooplankton vertical distribution was bimodal and mesopelagic peak was observed in a 200- to 300-m layer; it mainly comprised dormant copepods. Copepods predominated in most sampling layers, but euphausiids were dominant at the surface during the night. At S1, the maximum biomass was observed during the spring and the peak timing of biomass followed those of chlorophyll a and primary productivity. The annual mean biomasses in the euphotic and 200- to 1000-m layers were 0.10 (day) and 0.21 (night) g C m^?2 and 0.47 (day) and 0.26 (night) g C m^?2, respectively. Copepods were dominant in most sampling layers, but their mean proportion was lower than that in K2. Mesozooplankton community characteristics at both sites were compared with those at other time-series stations in the North Pacific and with each other. The annual mean primary productivities and sinking POC fluxes were equivalent at both sites; however, mesozooplankton biomasses were higher at K2 than at S1. The difference of biomasses was probably caused by differences of individual carbon losses, population turnover rates, and trophic structures of communities between the two sites.     

Utility of an automatic water sampler to observe seasonal variability in nutrients and DIC in the Northwestern North Pacific

Concentrations of nutrients (NO₃, NO₂, Si(OH)₄, PO₄ and dissolved inorganic carbon (DIC) were measured in a series of seawater samples collected over approximately 15 months in 2005 and 2006 by an automatic water sampler (Remote Access Sampler, RAS) in the Northwestern North Pacific. Seasonal variability and concentrations of NO₃ + NO₂ (NO_x and Si(OH)₄ were comparable to previous shipboard observations, although there were small errors associated with measurements of PO₄ and DIC. Concentrations of these nutrients began to decrease in late April. After the end of June, NO_x and Si(OH)₄ decreased rapidly, with large fluctuations. After October, these nutrients increased again until late spring 2006. The ratio of the decrease of Si(OH)₄ to that of NO_x suggests that numbers of biogenic opal-producing creatures, such as diatoms, increased after the end of June. This conclusion was supported by a rapid increase in biogenic opal flux recorded in a sediment trap at 150 m. The relationship between NO_x concentrations at the RAS depth of 35 m and NO_x integrated over the upper 100 m was determined using previous shipboard hydrocast data. This relationship was used to estimate integrated mixed layer NO_x concentration from RAS data. Estimated new production based on seasonal drawdown of integrated NO_x averaged approximately 156 mg-C m⁻²day⁻¹ annually, which agrees with previous estimates. Thus, an automatic seawater sampler that documents annual maximum and minimum nutrient concentrations and episodic events such as storms and spring blooms, which might be missed by an ordinary research vessel, will contribute to time-series observations of nutrients and, by extension, biological pump activity.