Sea water weathering effect on K-Ar age of submarine basalts

K-Ar dating and ⁴⁰Ar-³⁹Ar step heating experiments have been done for successive zones from the surface to the interior in two, altered dredged submarine basalts (16-2-6 and Aries V-23). The K contents show a systematic decrease (surface to the interior), whereas the K-Ar ages show a similar decrease in one sample (16-2-6) and almost no change in the other (Aries V-23).A simple diffusion model suggests that the K content decreases systematically from the surface to the interior, whereas the K-Ar age decreases or remains almost constant, depending on whether the times of solidification and of commencement of K-diffusion are close to each other or differ significantly. Comparison of the observed K content and K-Ar age variations within the rocks with the theoretical model then suggests that the solidification age of the sample Aries V-23 is much older than the commencement of the potassium-diffusion, the latter age perhaps being represented by the Eocene planktonic foraminifera on this sample. The ⁴⁰Ar-³⁹Ar isochron age obtained for the freshest specimen of Aries V-23 is 86.6 ± 3.7 m.y., supporting the above conclusion.The mathematical simulation indicates that an apparent concordance of the K-Ar age observed in some submarine basalts may be an artifact, only reflecting the significant gap between the solidification age and the time of the commencement of the K-diffusion in the rocks. Microprobe examination reveals that the potassium enrichment in the outer margin, is mainly due to K feldspar, which is an alteration product of plagioclase.     

Trapping of rare gases during the condensation of solids

Rare gas trapping during crystallization from vapor phases of (1) CdTe, (2) Zn, (3) Mg and (4) Fe₃O₄ has been studied. Samples were deposited as very fine crystals (about several hundred angströms) in ambient Ar atmospheres of various pressures. It was found that the amount of Ar trapped in the samples was proportional to the ambient Ar pressure. Stepheating degassing of the crystals showed that Ar was rather loosely trapped and released at relatively low temperatures. However, on a simple mechanical compaction of the crystal powder the retentivity of Ar was considerably enhanced.     

UT variation of internal Sq currents and the oceanic effect during 1980 March 1–18

Summary. UT variation of the internal part of S _q currents is examined using the geomagnetic data during 1980 March 1–18, and the effect of the ocean is found. The ratio of the internal currents to the external increases when the external current vortex comes above the Atlantic and Pacific Oceans, and the internal current vortex shifts to the oceans when the external vortex approaches the edge of the oceans. The existence of the ocean increases the total induced current by about 30 per cent and this amount is consistent with model calculations for S _q by previous workers.     

Occurrence of calcite in Sanbagawa pelitic schists: implications for the formation of garnet, rutile, oligoclase, biotite and hornblende

The frequency of occurrence of minerals in 1876 samples of Sanbagawa pelitic schist in central Shikoku is summarized on the basis of microscopic observation accompanied, in part, by use of an electron microprobe. All samples contain quartz, plagioclase, phengite, chlorite and graphite. More than 90% of samples contain clinozoisite, titanite and apatite. Garnet is present in 95% of samples from the garnet zone, and biotite is present in 64% of samples from the albite‐biotite zone. Calcite is found in about 40% of samples of the pelitic schist collected from outcrop, but occurs in 95% of the pelitic schist from drill cores. Calcite was apparently ubiquitous in the pelitic schist during the Sanbagawa metamorphism, but must have been dissolved recently by the action of surface or ground water. The mineral assemblages of the Sanbagawa pelitic schist have to be analyzed in the system with excess calcite, quartz, albite (or oligoclase), clinozoisite, graphite and fluid that is composed mainly of H₂O, CO₂ and CH₄. In the presence of calcite, reactions that produce garnet, rutile, oligoclase, biotite and hornblende, some of which define isograds of the metamorphic belt, should be written as mixed volatile equilibria that tend to take place at lower temperature than the dehydration reactions that have been proposed. The presence of calcite in pelitic schist suggests that fluid composition is a variable as important in determining mineral assemblages as pressure and temperature. Thus Ca‐bearing phases must be taken into account to analyze the phase relations of calcite‐bearing pelitic schist, even if CaO content of Sanbagawa pelitic schist is low. As calcite is a common phase, the mineral assemblages of the biotite zone pelitic schist may contravene the mineralogical phase rule and warrant further study.     

Mixing of asthenospheric and lithospheric mantle-derived basalt magmas as shown by along-arc variation in Sr and Nd isotopic compositions of Early Miocene basalts from back-arc margin of the NE Japan arc

We report trace element and Sr–Nd isotopic compositions of Early Miocene (22–18 Ma) basaltic rocks distributed along the back-arc margin of the NE Japan arc over 500 km. These rocks are divided into higher TiO₂ (> 1.5 wt.%; referred to as HT) and lower TiO₂ (< 1.5 wt.%; LT) basalts. HT basalt has higher Na₂O + K₂O, HFSE and LREE, Zr/Y, and La/Yb compared to LT basalt. Both suite rocks show a wide range in Sr and Nd isotopic compositions (initial ⁸⁷Sr/⁸⁶Sr (SrI) = 0.70389 to 0.70631, initial ¹⁴³Nd/¹⁴⁴Nd(NdI) = 0.51248 to 0.51285). There is no any systematic variation amongst the studied Early Miocene basaltic rocks in terms of Sr–Nd isotope or Na₂O + K₂O and K₂O abundances, across three volcanic zones from the eastern through transitional to western volcanic zone, but we can identify gradual increases in SrI and decreases in NdI from north to south along the back-arc margin of the NE Japan arc. Based on high field strength element, REE, and Sr–Nd isotope data, Early Miocene basaltic rocks of the NE Japan back-arc margin represent mixing of the asthenospheric mantle-derived basalt magma with two types of basaltic magmas, HT and LT basaltic magmas, derived by different degrees of partial melting of the subcontinental lithospheric mantle composed of garnet-absent lherzolite, with a gradual decrease in the proportion of asthenospheric mantle-derived magma from north to south. These mantle events might have occurred in association with rifting of the Eurasian continental arc during the pre-opening stage of the Japan Sea.     

Roles of Physical Processes in the Carbon Cycle Using a Simplified Physical Model

A simplified physical model is proposed in this article to describe differences among basins in substance distributions which were not well described by previous simplified models. In the proposed model, the global ocean is divided into the Pacific/Indian Ocean (PI), the Atlantic Ocean (AT), the Southern Ocean and the Greenland/Iceland/Norwegian Sea. The model is consisted of five physical parameters, namely the air-sea gas exchange, the thermohaline circulation, the horizontal and vertical diffusions, and the deep convection in the high-latitude regions. Individual values of these parameters are chosen by optimizing model distribution of natural ¹⁴C as a physical tracer. The optimal value for a coefficient of vertical diffusion in the low-latitude region is 7.5 × 10^–5 [m²s^–1]. Vertical transports by the Antarctic Bottom Water and the North Atlantic Deep Water are estimated at 1.0 Sv and 9.0 Sv. Global-mean air-sea gas exchange time is calculated at 9.0 years. Using these optimal values, vertical profiles of dissolved inorganic carbon without biological production in PI and AT are estimated. Oceanic responses to anthropogenic fluctuations in substance concentrations in the atmosphere induced by the industrialization and nuclear bomb are also discribed, i.e., the effects appear significantly in AT while a signal is extremely weak in PI. A time-delay term is effective to make the PI water older near the bottom boundary.     

Comparative analysis of measurements of stratospheric aerosol by lidar and aerosol sonde above Ny-Ålesund in the winter of 1995 [Comparative analysis of lidar and OPC observations]

Solid polar stratospheric cloud (PSC) layers observed by lidar and a balloon-borne optical particle counter (OPC) on 17 December 1995 are reexamined in a comparative analysis framework. The typical radius of solid particles in the observed PSC is determined through the comparative analysis to have been approximately 2.3 μm. A backward trajectory analysis for the air mass in which the solid particles were observed shows that the air mass had experienced temperatures 2–3 K below the frost point of nitric acid tri-hydrate (NAT) during the 4 days preceding the observations. The back-trajectory analysis traces the air mass back to northern Greenland and Ellesmere Island on 16 December, one day before the observations. A microphysical box model is used to investigate possible mechanisms of formation for the observed solid particles. The results of this model suggest that the solid particles formed under mesoscale temperature fluctuations associated with mountain lee wave activity induced by the relatively high terrestrial elevations of northern Greenland and Ellesmere Island.     

Diffuse X-ray spectrum from 10 to 40 keV measured with rocket-borne scintillation counters

The energy spectrum of the diffuse component of cosmic X-rays was measured with rocket-borne scintillation counters. Subtracting the environmental background unambiguously by means of the shutter method, the absolute values of the cosmic X-ray flux are obtained in a few keV band from 10 to 40 keV. The result indicates that the energy spectrum sharply changes its slope around 20–30 keV. Some trial functions for the spectrum are compared with our result; among them a thermal bremsstrahlung spectrum and a two-slope power law spectrum seem to fit very well. The former needs, however, another origin of X-rays in the lower and higher energy regions. ‘Sharpness’ of the break in the case of the latter is discussed, including a data point in high energy side from a balloon experiment. The acceptable range of the spectral index in the high energy side is 2.3–2.6, that of the break energy is 20–30 keV and the corresponding transition width is smaller than 50 keV, if the confidence level is to be better than 5%. Non-thermal X-ray generation due to the inverse Compton effect does not reproduce the X-ray spectrum, even if the electron spectrum shows a sharp break. Bremsstrahlung with the non-thermal electrons or protons with a sharp cut in the low energy side of the spectrum can reproduce our result, though such a cut seems unrealistic. Our result may suggest that current theories on the origin of the diffuse X-rays have to be revised.     

AMS 14C ages and petrological features for solidified fractures with carbonates at coastal outcrops of Yakushima Island, Japan

This paper describes the petrological features and the ages of rock fractures filled mainly with carbonates at coastal outcrops of Yakushima Island, Japan. Microscopic observation and geochemical analysis were used to investigate the petrological features and the compositions of the fracture fillings. In addition, AMS ¹⁴C dating was also performed to estimate the ages of them. Microscopic study indicated that the fracture fillings contain not only cementing materials but also lithic fragments from host rock and bioclasts. SEM observation showed that the cements exhibit the characteristic textures of beachrocks. The cements were identified as Mg-calcite from XRD analysis. It was also observed from geochemical analysis that there were at least two stages of precipitation within the fractures. In addition, AMS ¹⁴C dating for seventeen samples of fracture fillings showed that the ages range from 2,460 to 5,130 years BP which is found to be younger than that of the uplifted coral at Yakushima Island (approximately 5,300–5,600 years BP). The results suggest that the fractures were solidified after the coral was uplifted.     

Near-infrared imaging survey of faint companions around young dwarfs in the Pleiades cluster

We conducted a near-infrared imaging survey of 11 young dwarfs in the Pleiades cluster using the Subaru Telescope and the near-infrared coronagraph imager. We found ten faint point sources,with magnitudes as faint as 20 mag in the K-band,with around seven dwarfs.Comparison with the Spitzer archive images revealed that a pair of the faint sources around V 1171 Tau is very red in infrared wavelengths,which indicates very low-mass young stellar objects.However,the results of our follow-up proper motion measure...