Switch in chemical weathering caused by the mass balance variability in a Himalayan glacierized basin: a case of Chhota Shigri Glacier

Long-term data (2003–2015) on meltwater chemistry, mass balance and discharge of a benchmark glacier (Chhota Shigri Glacier, India) were studied to determine any association between these variables. To infer the factors governing the alteration of chemical weathering processes in glacierized basins, multi-annual records of the hydrochemical indices (Ca²⁺+Mg²⁺/Na⁺+K⁺) and the C-ratio were also examined. A succession of negative mass balance years has resulted in a decline in solute concentrations in the runoff, as discharge has increased. The (Ca²⁺+Mg²⁺/Na⁺+K⁺) and C-ratio are highest during periods of negative annual mass balance, when the spatial extent of the channelized drainage system increases. Conversely, these ratios are lowest in positive mass balance years, when the spatial extent of the channelized drainage system decreases, and chemical weathering in the distributed drainage system becomes more dominant. This paper is the first to show the inter-annual linkages between meltwater chemistry, mass balance and discharge for a valley glacier.     

Late Quaternary stratigraphy of the northern Rockall trough and Faeroe-Shetland channel,northeast Atlantic Ocean

A late Quaternary deep-water stratigraphic framework has been established for the deep-water areas (>450m) of the northern Rockall Trough and Faeroe-Shetland Channel. Four stratigraphic units (1–4) are identified; these are primarily biostratigraphic units based on dinoflagellate cyst evidence. Unit 1 represents the late Weichselian glacial (pre-13 000 yr BP); unit 2 the Late Glacial Interstadial (11 000-13 000 yr BP); unit 3 is of Younger Dryas age (10 000-11 000 yr BP); and unit 4 represents the Holocene interglacial (post-10 000 yr BP). This stratigraphy is supported by the discovery of the mixed Vedde Ash (10 600 yr BP) and North Atlantic Ash zone 1, and the Saksunarvatn Ash (9000–9100 yr BP), concentrated in units 3 and 4 respectively. The sedimentology indicates that the oceanographic regime underwent a major change between the glacial and interglacial stages. This is marked by the onset of strong bottom current activity, allied to the restoration of overflow of the Norwegian Sea Deep Water into the North Atlantic, towards the end of the Younger Dryas Stadial. Despite intense bioturbation and bottom-current reworking the basic stratigraphic framework is maintained. Recognition of two volcanic ash markers enables correlation with established onshore and offshore sequences of marine and non-marine environments.     

Palaeoenvironmental records in Holocene Spanish tufas: a stable isotope approach in search of reliable climatic archives

Tufa deposits are potential terrestrial archives of palaeoenvironmental and palaeoclimatic information. This study assesses the potential of stable isotopic archives from two closely juxtaposed Holocene tufa sites in SE Spain. The Ruidera site contains deep‐water lacustrine micrites and tufas, whereas the nearby Alcaraz site represents a shallow barrage tufa. Understanding site characteristics is critical to interpreting the stable isotopic variations. These Holocene lacustrine micrites have isotopic compositions consistent with modern European lake shore microbial carbonates, where the isotopic chemistry is strongly influenced by hydrological and residence time effects. All the lacustrine micrite δ¹³C values were influenced by microenvironmental microbial effects to some degree. Because of these effects, stable isotope data from lacustrine microbial micrites and tufas will not normally yield precise information on the isotopic composition of palaeoprecipitation, temperature or vegetation composition of an area. In contrast, Holocene tufas that formed in shallow, fast‐flowing riverine settings may contain valuable palaeoclimatic archives. The tufa deposits must be largely autochthonous, as at Alcaraz, where in situ reed stem encrustations are present. Records of relative change in air temperature and changes in the source of airmasses are potentially resolvable in the δ¹⁸O data. These interpretations can be verified by other independent climatic data where chronology is constrained. Variations in riverine tufa δ¹³C values probably record changes in local vegetation and/or soil respiration. Covariation between δ¹⁸O and δ¹³C values may be intrinsically linked to climatic factors such as aridity. Tentative palaeoclimatic interpretations for the middle Holocene at Alcaraz based on the isotope data suggest warming (or increasing influence of Mediterranean‐sourced precipitation) between approximately 5000–3000 radiocarbon years BP, accompanied by increased aridity. These interpretations are consistent with the sparse independent palaeoclimatic data and climate modelling results for the Holocene of SE Spain. This study supports the growing evidence that well‐chosen tufa sites could yield valuable palaeoclimatic information.     

The hydrochemistry of Lake Vostok and the potential for life in Antarctic subglacial lakes

Our understanding of Lake Vostok, the huge subglacial lake beneath the East Antarctic Ice Sheet, has improved recently through the identification of key physical and chemical interactions between the ice sheet and the lake. The north of the lake, where the overlying ice sheet is thickest, is characterized by subglacial melting, whereas freezing of lake water occurs in the south, resulting in ～210 m of ice accretion to the underside of the ice sheet. The accreted ice contains lower concentrations of the impurities normally found in glacier ice, suggesting a net transfer of material from meltwater into the lake. The small numbers of microbes found so far within the accreted ice have DNA profiles similar to those of contemporary surface microbes. Microbiologists expect, however, that Lake Vostok, and other subglacial lakes, will harbour unique species, particularly within the deeper waters and associated sediments. The extreme environments of subglacial lakes are characterized by high pressures, low temperatures, permanent darkness, limited nutrient availability, and oxygen concentrations that are derived from the ice that provides the meltwater. Copyright © 2002 John Wiley & Sons, Ltd.     

Corrigendum: Geological setting and origin of fuchsite‐bearing rocks near Menzies,Western Australia

Quartz‐andalusite‐fuchsite rocks in an Archaean greenstone belt at Menzies, Western Australia, are described in their geological setting. They are shown to have developed from intense metasomatism of layered rocks of komatiitic composition. Ratios of the immobile components Al₂O₃, TiO₂, Cr, V and Zr are consistent, despite wide variations in their absolute values, and compare closely with those of an underlying komatiite suite. Marked depletion of Ca, Na, Mg and Fe has led to a strongly peraluminous composition and enhanced Cr values. Silicification and introduction of K has also occurred. Most of the metasomatism took place before peak metamorphism, and the mineral assemblage is now dominated by andalusite, fuchsite, and recrystallized quartz. Schlieren or vein‐like segregations rich in andalusite, chromite, rutile and minor sulphides and tourmaline are interpreted as the original fluid pathways, where concentration of immobiles was achieved through solution of mobile components, and volume loss. They have been termed residual veins. Metasomatism is believed to have taken place by synvolcanic processes analogous to those operating in modern hot spring systems. The rocks were severely modified by metamorphism and tectonism. The fuchsitic rocks at Menzies are compared to similar rocks in other areas.     

Spatial interpolation schemes of daily precipitation for hydrologic modeling

Distributed hydrologic models typically require spatial estimates of precipitation interpolated from sparsely located observational points to the specific grid points. We compare and contrast the performance of regression-based statistical methods for the spatial estimation of precipitation in two hydrologically different basins and confirmed that widely used regression-based estimation schemes fail to describe the realistic spatial variability of daily precipitation field. The methods assessed are: (1) inverse distance weighted average; (2) multiple linear regression (MLR); (3) climatological MLR; and (4) locally weighted polynomial regression (LWP). In order to improve the performance of the interpolations, the authors propose a two-step regression technique for effective daily precipitation estimation. In this simple two-step estimation process, precipitation occurrence is first generated via a logistic regression model before estimate the amount of precipitation separately on wet days. This process generated the precipitation occurrence, amount, and spatial correlation effectively. A distributed hydrologic model (PRMS) was used for the impact analysis in daily time step simulation. Multiple simulations suggested noticeable differences between the input alternatives generated by three different interpolation schemes. Differences are shown in overall simulation error against the observations, degree of explained variability, and seasonal volumes. Simulated streamflows also showed different characteristics in mean, maximum, minimum, and peak flows. Given the same parameter optimization technique, LWP input showed least streamflow error in Alapaha basin and CMLR input showed least error (still very close to LWP) in Animas basin. All of the two-step interpolation inputs resulted in lower streamflow error compared to the directly interpolated inputs.     

Seagrass meadows in a globally changing environment

Seagrass meadows are valuable ecosystem service providers that are now being lost globally at an unprecedented rate, with water quality and other localised stressors putting their future viability in doubt. It is therefore critical that we learn more about the interactions between seagrass meadows and future environmental change in the anthropocene. This needs to be with particular reference to the consequences of poor water quality on ecosystem resilience and the effects of change on trophic interactions within the food web. Understanding and predicting the response of seagrass meadows to future environmental change requires an understanding of the natural long-term drivers of change and how these are currently influenced by anthropogenic stress. Conservation management of coastal and marine ecosystems now and in the future requires increased knowledge of how seagrass meadows respond to environmental change, and how they can be managed to be resilient to these changes. Finding solutions to such issues also requires recognising people as part of the social–ecological system. This special issue aims to further enhance this knowledge by bringing together global expertise across this field. The special issues considers issues such as ecosystem service delivery of seagrass meadows, the drivers of long-term seagrass change and the socio-economic consequences of environmental change to seagrass.     

Crustal Electrical Conductivity Structure of Southern Tibet from Magnetotelluric Survey

INTRODUCTIONAsatypicalintercontinent collisionarea ,Tibetanplateauisapresentlypopularregionnoticedbygeoscientistsallovertheworld ,sinceitisanidealandnaturallabforthestudyofthegeologicalevolutionoftheinnerlandmountain creatingzoneandoftheprocessofthecrust mantledeepdy namicsaswellasoftheinteractionbetweenthesurfaceandthecrustmovement.ThestudyoftheTibetanplateauevolutionisimportantnotonlyinsolvingsometheoreticalproblemsaboutcontinentaldynamicsandglobalchangesingeosciences ;butalsoinexplorin…     

Recognising the crystallographic signature of recrystallisation processes in deformed rocks: a study of experimentally deformed rocksalt

The microstructural development of synthetic rocksalt experimentally deformed at 100–200°C can be dominated either by grain boundary migration recrystallisation or by subgrain rotation recrystallisation, depending on water content. Samples taken from both regimes have been analysed using automated electron backscatter diffraction in order to collect crystallographic orientation and misorientation data. The frequency distribution of boundary misorientations, the boundary hierarchy characteristics and the nature of any crystallographic preferred orientation (CPO) have been used to determine the crystallographic signature of both recrystallisation processes. Dominant subgrain rotation recrystallisation results in many low to medium angle (4–20°) boundaries, a strong CPO and a continuous boundary hierarchy. Dominant grain boundary migration recrystallisation results in few low or medium angle boundaries, and a discrete boundary hierarchy. The causes of these differences and the potential application of crystallographic signatures to the study of naturally deformed rocks are discussed.     

NO<Subscript>3</Subscript> Vertical Profile Measurements from Remote Sensing Balloon-Borne Spectrometers and Comparison with Model Calculations

Eleven vertical profiles of stratospheric NO₃ have been obtained since 1992 using the AMON and SALOMON balloon-borne UV-visible spectrometers. The measurements are compared to the SLIMCAT 3D model and calculations based on the steady-state hypothesis for NO₃. The calculations cannot reproduce some parts of the profiles which exhibit strong concentration fluctuations over few kilometres, as a consequence of the dependence of NO₃ on local temperature variations. A statistical use of the data allows us to estimate the influence of the temperature dependence of the absorption cross-section on the data analysis, and the validity of the recommended reaction rates available in the literature. Discrepancies exist between the model based on recommended kinetics and observations at warmer temperatures. Nevertheless, the analysis is biased by local temperature inhomogeneities, and only a low-resolution vertical shape of the NO₃ profiles can be retrieved.