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Summary The greenhouse effect has been investigated predominantly with satellite measurements, but more than 90% of the greenhouse radiative flux affecting Earths surface temperature and humidity originates from a 1000 meter layer above the surface. Here we show that substantial improvements on surface longwave radiation measurements and very good agreement with radiative transfer model calculations allow the clear-sky greenhouse effect be determined with measured surface longwave radiation and calculated longwave outgoing radiation at the top of the atmosphere. The cloud radiative forcing is determined by measured net longwave fluxes and added to the clear-sky greenhouse effect to determine the all-sky greenhouse effect. Longwave radiation measurements at different altitudes were used to determine the clear-sky and all-sky annual and seasonal greenhouse effect and altitude gradients over the Alps. Linear altitude gradients are measured for clear-sky situations, whereas the all-sky greenhouse effect is strongly influenced by varying, cloud amounts at different altitudes. Large diurnal and seasonal variations show the importance of surface heating and cooling effects and demonstrate the strong coupling of the greenhouse effect to surface temperature and humidity.  相似文献   
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Identification of major nitrate sources that adversely impact groundwater quality in municipal well capture zones in areas of emerging nitrate contamination is essential to minimize leaching and prevent exceedance of the nitrate drinking water standard. Vertical profiles of nitrate leachate in deep soils provide an estimate of the amount of nitrate in transit beneath irrigated, row-cropped fields; depths of peak leachate; and the approximate rate of downward movement. Profiles of pore-water soil-nitrate concentrations in thick 60-feet (~18 m), fine-textured soils near Hastings, Nebraska clearly indicate that considerably more nitrate leached beneath furrow-irrigated than center-pivot irrigated fields. Peak leaching appeared to correlate with recorded periods of poor weather conditions during some growing seasons and may best be controlled by “spoon feeding” fertilizer to the crop through the sprinkler irrigation system at times of nutrient need. The presence of trace levels of atrazine and deethylatrazine to 60 feet (18 m) in core samples indicates that larger, more complex anthropogenic molecules also leach through the fine-textured soils. The light δ15NNO3 values in the surficial groundwater beneath fertilized and irrigated cropland indicate that ammonium fertilizer is a major N source and suggest that the natural soil-N contribution is negligible. δ15NNO3 values were most enriched in irrigation wells located within municipal well capture zones downgradient of a large feedlot. Dual isotope method (DIM) δ15NNO3 and δ18ONO3 values suggest that the Hastings’ municipal wells farther downgradient are contaminated with a mixture of nitrate from manure and commercial ammonium-based fertilizer. DIM values indicate an absence of denitrification, which has implications for long-term management of the water resources.  相似文献   
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Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.  相似文献   
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Paleolimnological and plant physiological literature were reviewed to determine which types of aquatic plant macrofossils are suitable for radiocarbon dating, with a particular focus on the uptake of reservoir-aged dissolved inorganic carbon (DIC) by emergent plants. Submerged aquatic plants utilize large amounts of DIC and are clearly not suitable for radiocarbon dating. Under certain environmental conditions, some emergent aquatic plants can metabolize DIC in quantities large enough to introduce old-carbon error to radiocarbon dates acquired from their remains (plant macrofossils). Over 300 plant macrofossil images are included in the online resource Tool for Microscopic Identification; http://tmi.laccore.umn.edu) along with guidance on identification and suitability for radiocarbon dating.  相似文献   
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On the basis of the GRIM4-S1 satellite-only Earth gravity model, being accomplished in a common effort by DGFI and GRGS, a combination solution, called GRIM4-C1, has been derivcd using 1° × 1° mean gravity anomalies and 1° × 1° Seasat altimeter derived mean geoid undulations. In the meantime improvements could be achieved by incorporating more tracking data (GEOSAT, SPOT2-DORIS) into the solution, resulting in the two new parallel versions, the satellite-only gravity model GRIM4-S2 and the combined solution GRIM4-C2p (preliminary). All GRIM4 Earth gravity models cover the spectral gravitational constituents complete up to degree and order 50.In this report the emphasis is on the discussion of the combined gravity models: combination and estimation techniques, capabilities for application in precise satellite orbit computation and accuracies in long wavelength geoid representation. It is shown that with the new generation of global gravity models general purpose satellite-only models are no longer inferior to combination solutions if applied to satellite orbit restitution.  相似文献   
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Magmatic rocks from the pre-Mesozoic basements of the Sambuco and Maggia nappes have been dated by U–Pb zircon ages with the LA-ICPMS technique. Several magmatic events have been identified in the Sambuco nappe. The mafic banded calc-alkaline suite of Scheggia is dated at 540 Ma, an age comparable to that of mafic rocks in the Austroalpine Silvretta nappe. The Sasso Nero peraluminous augengneiss has an age of 480–470 Ma, like many other “older orthogneisses” in Alpine basement units. It hosts a large proportion of inherited zircons, which were dated around 630 Ma, a Panafrican age indicating the Gondwanan affiliation of the Sambuco basement. The calc-alkaline Matorello pluton yielded ages around 300 Ma, similar to numerous Late Carboniferous intrusions in other basement units of the Lower Penninic (Monte Leone, Antigorio, Verampio) and Helvetic domains (Gotthard and other External Crystalline Massifs). Associated lamprophyric dykes are slightly younger (300–290 Ma), like similar dykes sampled in gneiss blocks included in the sedimentary cover of the underlying Antigorio nappe (290–285 Ma). The Cocco granodiorite and Rüscada leucogranite, both intruding the basement of the neighbouring Maggia nappe, yielded ages of ca. 300–310 Ma, identical within errors to the age of the Matorello pluton. They are significantly older than former age determinations. This age coincidence, coupled with remarkable petrologic similarities between the Cocco and Matorello granodiorites, strongly suggests paleogeographic proximity of the Sambuco and Maggia nappes in Late Carboniferous times. In recent publications these two nappes have been interpreted as belonging to distinct Mesozoic paleogeographic domains: “European” for Sambuco and “Briançonnais” for Maggia, separated by the “Valais” oceanic basin. In this case, the similarity of the Matorello and Cocco intrusions would demonstrate the absence of any significant transcurrent movement between these two continental domains. Alternatively, according to a more traditional view, Sambuco and Maggia might belong to a single large Alpine tectonic unit.  相似文献   
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