Computation and Analysis of the Global Distribution of the Radioxenon Isotope 133Xe based on Emissions from Nuclear Power Plants and Radioisotope Production Facilities and its Relevance for the Verification of the Nuclear-Test-Ban Treaty

Monitoring of radioactive noble gases, in particular xenon isotopes, is a crucial element of the verification of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The capability of the noble gas network, which is currently under construction, to detect signals from a nuclear explosion critically depends on the background created by other sources. Therefore, the global distribution of these isotopes based on emissions and transport patterns needs to be understood. A significant xenon background exists in the reactor regions of North America, Europe and Asia. An emission inventory of the four relevant xenon isotopes has recently been created, which specifies source terms for each power plant. As the major emitters of xenon isotopes worldwide, a few medical radioisotope production facilities have been recently identified, in particular the facilities in Chalk River (Canada), Fleurus (Belgium), Pelindaba (South Africa) and Petten (Netherlands). Emissions from these sites are expected to exceed those of the other sources by orders of magnitude. In this study, emphasis is put on ¹³³Xe, which is the most prevalent xenon isotope. First, based on the emissions known, the resulting ¹³³Xe concentration levels at all noble gas stations of the final CTBT verification network were calculated and found to be consistent with observations. Second, it turned out that emissions from the radioisotope facilities can explain a number of observed peaks, meaning that atmospheric transport modelling is an important tool for the categorization of measurements. Third, it became evident that Nuclear Power Plant emissions are more difficult to treat in the models, since their temporal variation is high and not generally reported. Fourth, there are indications that the assumed annual emissions may be underestimated by factors of two to ten, while the general emission patterns seem to be well understood. Finally, it became evident that ¹³³Xe sources mainly influence the sensitivity of the monitoring system in the mid-latitudes, where the network coverage is particularly good.     

Matrix approach to the solution of free toroidal elastic oscillations of the earth

Summary The propagator matrix is expressed in terms of cross-products of spherical Bessel functions and their derivatives. A fast computational algorithm is suggested. The matrix form of the variational principle with the boundary term is derived.

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u nu u u u, n¶rt; u¶rt; nu¶rt;u uu u u u nuo¶rt;. ¶rt; au u . ¶rt; u uau nuuna u .

     

Gene Expression Analysis for Exposure to Estrogenic Substances

Zebrafish (Danio rerio) were exposed with 17β‐estradiol (E2) and nonylphenol (NP) in different concentrations. Gene expression analysis was carried out by two different approaches. First, RT‐PCR experiments were performed for the examination of expression levels of the two marker genes vitellogenin and aromatase. This approach showed a significant increase in the expression of the vitellogenin gene in exposed male fish (500 ng/L 17β‐estradiol and 250 μg/L nonylphenol). This egg yolk protein is usually not synthesized in male vertebrates. A slight decrease of expression of the aromatase gene was observed in exposed female zebrafish. Aromatase is known to catalyze the conversion of androgens to estrogens. Second, DNA microarray experiments were carried out, which allow the simultaneous examination of the expression levels of a great number of marker genes. The microarray experiments resulted in an up‐regulation of vitellogenin up to 850‐fold. In addition, several other genes were identified to be up‐regulated by estrogens, for example the high mobility group box protein ssrp1 (78‐fold) or the chaperonin containing t‐complex polypeptide 1, beta subunit cctb (22‐fold).     

Quantification of contemporary storm-induced boulder transport on an intertidal shore platform using radio frequency identification technology

Extreme storm events are known to produce, entrain, transport and deposit sizable boulders along rocky coastlines. However, the extent to which these processes occur under moderate, fetch-limited wave conditions is seldom considered. In this study we quantify boulder transport at a relatively sheltered location subject to high-frequency, low-magnitude storm activity. This was achieved by deploying radio frequency identification (RFID) tags within 104 intertidal limestone boulders ranging in size from fine to very coarse (intermediate axis: 0.27–2.85 m). The study was conducted over 3 years (July 2015–July 2018) and encompassed numerous storm events. Tagged boulders were relocated during 17 field surveys and their positions recorded using a differential global positioning navigation satellite system (DGNSS). On completion, we identified boulder displacement in 69% of the tagged array. The accrued boulder transport distance amounted to 233.0 m from 195 incidents of displacement, including the movement of a boulder weighing an estimated 11.9 t. Transport was not confined to autumn and winter storms alone, as displacement was also recorded during summer months (April–September), despite the seasonally reduced wave magnitude. Boulder production by wave quarrying was documented in three tagged clasts, confirming observations that the shore platform is actively eroding. Incidents of overturning during transport were also recorded, including multiple overturning of clasts weighing up to 5 t. We further identify a statistically significant difference (maximum p-value ≤ 0.03) between the transport distances attributed to constrained and unconstrained boulders, suggesting that the pre-transport morphological setting exerts considerable control over boulder transport potential. The findings establish low to moderate storm waves as a key component in the evolution of the study site. More broadly, we claim that high-frequency, low-magnitude storms regularly modify these overlooked rocky coastal locations, suggesting that the hydrodynamic capability at such sites may previously have been underestimated. © 2020 John Wiley & Sons, Ltd.     

Results of a walk-above vertical seismic profiling survey acquired at the Thônex-01 geothermal well (Switzerland) to delineate fractured carbonate formations for geothermal development

This paper deals with the design, acquisition and processing of vertical seismic profiling data collected in 2016 at the directional Thônex-01 geothermal well, drilled in 1993 in the Geneva Canton (Switzerland). The aim of the study was to obtain additional information from existing-abandoned well for downhole geophysical characterization of potential geothermal reservoirs in the Geneva area. The main results obtained by this study allowed an improved subsurface image by multi-offset acquisitions near and around the deviated well. Specifically we were able to (1) improve the velocity model of the Geneva Basin, which, at present, is only constrained by one unique deep exploration well, located at the south-west of the basin, far away from the study area; (2) image the transition between the Tertiary Molasse siliciclastic sediments and the Mesozoic carbonates; (3) define an acquisition strategy for future vertical seismic profiling surveys in support of the geothermal exploration campaigns in the area. This study has demonstrated the value of vertical seismic profiling method for the refinement of the subsurface geology at local scale, and its usefulness to assist the planning of second well associated with geothermal doublets.     

Assessing “Urban Karst” Effects from Groundwater–Storm Sewer System Interaction in a Till Aquitard

Storm sewer systems and their associated utility trenches may strongly influence the effects of urbanization on a groundwater system. This study was undertaken to identify the causes of district-wide basement infiltration in an aquitard system. It comprised widespread continuous monitoring of utility trench wells and dye tracing from storm sewer system exfiltration tests. The results indicate that a major effect of urbanization on shallow groundwater is related to storm sewer system exfiltration, which is marked by a characteristic pattern of head variations in the aquitard unrelated to distributed surface infiltration. The aquitard constrains flow from storm sewer system exfiltration to the utility trench, creating an urban flow path for groundwater discharge. Temporary buildup of water levels in the utility trench drives relatively high-velocity flow through the permeable sewer bedding material of the utility trench to a separate foundation drainage collector system, ultimately causing a severe “urban karst” effect that produces system surcharging and widespread basement water infiltration. The main conditions causing the “urban karst” are the large hydraulic conductivity ratio between the utility trench material and the aquitard, and the shallow depth and low gradient of the storm sewer system imposed by a very flat drainage basin.     

DTSGUI: A Python Program to Process and Visualize Fiber-Optic Distributed Temperature Sensing Data

Fiber-optic distributed temperature sensing (FO-DTS) has proven to be a transformative technology for the hydrologic sciences, with application to diverse problems including hyporheic exchange, groundwater/surface-water interaction, fractured-rock characterization, and cold regions hydrology. FO-DTS produces large, complex, and information-rich datasets. Despite the potential of FO-DTS, adoption of the technology has been impeded by lack of tools for data processing, analysis, and visualization. New tools are needed to efficiently and fully capitalize on the information content of FO-DTS datasets. To this end, we present DTSGUI, a public-domain Python-based software package for editing, parsing, processing, statistical analysis, georeferencing, and visualization of FO-DTS data.     

Fluvial organic carbon composition and concentration variability within a peatland catchment—Implications for carbon cycling and water treatment

Fluvial organic carbon (OC) transformations are an important component of carbon cycling and greenhouse gas production in inland waters resulting in considerable recent interest in the fate of fluvial OC exported from carbon rich soils such as peatlands. Additionally, peatland catchments are important drinking water collection areas, where high OC concentrations in runoff have water treatment implications. This analysis presents the results from a year‐round intensive study within a water treatment catchment draining an area of peatland, considering carbon transformations along a continuum from headwater river, through a storage reservoir and pipe, to a water treatment works. The study uses a unique combination of methods (colourmetric, ultrafiltration, and ¹⁴C radiocarbon dating) to assess catchment wide changes in fluvial carbon composition (colour, size, and age) alongside concentration measures. The results indicate clear patterns of carbon transformations in the river and reservoir and dissolved low molecular weight coloured carbon to be most subject to change, with both loss and replacement within the catchment residence time. Although the evidence suggests dissolved OC (DOC) gains are from particulate OC breakdown, the mechanisms of DOC loss are less certain and may represent greenhouse gas losses or conversions to particulate OC. The transformations presented here appear to have minimal impact on the amount of harder to treat (<10 kDa) dissolved carbon, although they do have implications for total DOC loading to water treatment works. This paper shows that peatland fluvial systems are not passive receptors of particulate and dissolved organic carbon but locations where carbon is actively cycled, with implications for the understanding of carbon cycling and water treatment in peatland catchments.     

A Straightforward Random Walk Model for Fast Push‐Pull Tracer Test Evaluation

In this article, we present a straightforward random walk model for fast evaluation of push‐pull tracer tests. By developing an adaptive algorithm, we overcome the problem of manually defining how many particles have to be used to simulate the transport problem. Beside this, we validate the random walk model by evaluating a push‐pull tracer test with drift phase and confirm the results with MT3DMS. The random walk model took less than 1% of computational time of MT3DMS, thus allowing a remarkable faster evaluation of push‐pull tracer tests.     

Mafic and Felsic Magma Interaction in Granites: the Hercynian Karkonosze Pluton (Sudetes, Bohemian Massif)

The Hercynian, post-collisional Karkonosze pluton contains severallithologies: equigranular and porphyritic granites, hybrid quartzdiorites and granodiorites, microgranular magmatic enclaves,and composite and lamprophyre dykes. Field relationships, mineralogyand major- and trace-element geochemistry show that: (1) theequigranular granite is differentiated and evolved by smalldegrees of fractional crystallization and that it is free ofcontamination by mafic magma; (2) all other components are affectedby mixing. The end-members of the mixing process were a porphyriticgranite and a mafic lamprophyre. The degree of mixing variedwidely depending on both place and time. All of the processesinvolved are assessed quantitatively with the following conclusions.Most of the pluton was affected by mixing, implying that hugevolumes (>75 km³) of mafic magma were available. This maficmagma probably supplied the additional heat necessary to initiatecrustal melting; part of this heat could have also been releasedas latent heat of crystallization. Only a very small part ofthe Karkonosze granite escaped interaction with mafic magma,specifically the equigranular granite and a subordinate partof the porphyritic granite. Minerals from these facies are compositionallyhomogeneous and/or normally zoned, which, together with geochemicalmodelling, indicates that they evolved by small degrees of fractionalcrystallization (<20%). Accessory minerals played an importantrole during magmatic differentiation and, thus, the fractionalcrystallization history is better recorded by trace rather thanby major elements. The interactions between mafic and felsicmagmas reflect their viscosity contrast. With increasing viscositycontrast, the magmatic relationships change from homogeneous,hybrid quartz diorites–granodiorites, to rounded magmaticenclaves, to composite dykes and finally to dykes with chilledmargins. These relationships indicate that injection of maficmagma into the granite took place over the whole crystallizationhistory. Consequently, a long-lived mafic source coexisted togetherwith the granite magma. Mafic magmas were derived either directlyfrom the mantle or via one or more crustal storage reservoirs.Compatible element abundances (e.g. Ni) show that the maficmagmas that interacted with the granite were progressively poorerin Ni in the order hybrid quartz diorites—granodiorites—enclaves—compositedykes. This indicates that the felsic and mafic magmas evolvedindependently, which, in the case of the Karkonosze granite,favours a deep-seated magma chamber rather than a continuousflux from mantle. Two magma sources (mantle and crust) coexisted,and melted almost contemporaneously; the two reservoirs evolvedindependently by fractional crystallization. However, maficmagma was continuously being intruded into the crystallizinggranite, with more or less complete mixing. Several lines ofevidence (e.g. magmatic flux structures, incorporation of granitefeldspars into mafic magma, feldspar zoning with fluctuatingtrace element patterns reflecting rapid changes in magma composition)indicate that, during its emplacement and crystallization, thegranite body was affected by strong internal movements. Thesewould favour more complete and efficient mixing. The systematicspatial–temporal association of lamprophyres with crustalmagmas is interpreted as indicating that their mantle sourceis a fertile peridotite, possibly enriched (metasomatized) byearlier subduction processes. KEY WORDS: Bohemian Massif; fractional crystallization; geochemical modelling; hybridization; Karkonosze