An experimental comparison of three direct methods of marine source signature estimation

Three methods for estimation of the pressure wavefield generated by a marine airgun array are tested experimentally and compared. In the trial a variety of radiation angles and array configurations were used and some large synchronization errors were deliberately introduced. The source was equipped with near-field hydrophones and a subsource ministreamer. A tethered far-field hydrophone was used so that the three estimated far-field signatures could be compared with an independent measurement. The knowledge of the source signature is important for on-board source array QC, deconvolution, multiple attenuation, stratigraphic trap prediction, modelling and inversion, AVO analysis and reservoir monitoring. The methods perform very well and give estimates whose frequency-domain spectra match the measured spectra to within a few dB and within a few tens of degrees of phase over the tested bandwidth of 3.5–110 Hz. The time-domain error-energy is typically only a few per cent of the signal energy for radiation angles within about 30° of the vertical. The third method proved to be sensitive to an experimental shortcoming leading to overloading of the ministreamer and meaningful comparison was not possible for some test configurations.     

Age-dependent Large-scale Fabric of the Mantle Lithosphere as Derived from Surface-wave Velocity Anisotropy

—Systematic variations of the seismic radial anisotropy ξ to depths of 200–250 km in North America and Eurasia and their surroundings are related to the age of continental provinces, and typical depth dependences of ξ _R are determined. The relative radial anisotropy ξ _R in the mantle lithosphere of Phanerozoic orogenic belts is characterized by ν _SH > ν _SV , with its maximum depth of about 70 km, on the average, while beneath old shields and platforms, it exhibits a maximum deviation from ACY400 model (Montagner and Anderson, 1989) at depths of about 100 km with ν _SV ≥ν _SH signature. An interpretation of the observed seismic anisotropy by the preferred orientation of olivine crystals results in a model of the mantle lithosphere characterized by anisotropic structures plunging steeply beneath old shields and platforms, compared to less inclined anisotropies beneath Phanerozoic regions. This observation supports the idea derived from petrological and geochemical observations that a mode of continental lithosphere generation may have changed throughout earth's history.     

Weak Contrast PP Wave Displacement R/T Coefficients in Weakly Anisotropic Elastic Media

—Approximate PP plane wave displacement coefficients of reflection and transmission for weak contrast interfaces separating weakly but arbitrarily anisotropic elastic media are presented. The PP reflection coefficient for such an interface has been derived recently by Vavry?uk and P?en?ík (1997). The PP transmission coefficient presented in this paper was derived by the same approach. The coefficients are given as a sum of the coefficient for the weak contrast interface separating two nearby isotropic media and a term depending linearly on contrasts of the so-called weak anisotropy (WA) parameters (parameters specifying deviation of properties of the medium from isotropy), across the interface. While the reflection coefficient depends only on 8 of the complete set of the WA parameters describing P-wave phase velocity in weakly anisotropic media, the transmission coefficient depends on their complete set. The PP reflection coefficient depends on "shear-wave splitting parameter" γ. Tests of accuracy of the approximate formulae are presented on several models.     

Equilibrium-disequilibrium relations in the Monte Rosa Granite,Western Alps: Petrological,Rb-Sr and stable isotope data

Nine samples from the Monte Rosa Granite have been investigated by microscopic, X-ray, wet chemical, electron microprobe, stable isotope and Rb-Sr and K-Ar methods. Two mineral assemblages have been distinguished by optical methods and dated as Permian and mid-Tertiary by means of Rb-Sr age determinations. The Permian assemblage comprises quartz, orthoclase, oligoclase, biotite, and muscovite whereas the Alpine assemblage comprises quartz, microcline, albite+epidote or oligoclase, biotite, and phengite. Disequilibrium between the Permian and Alpine mineral assemblages is documented by the following facts: (i) Two texturally distinguishable generations of white K-mica are 2 M muscovite (Si=3.1–3.2) and 2 M or 3 T phengite (Si=3.3–3.4). Five muscovites show Permian Rb-Sr ages and oxygen isotope fractionations indicating temperatures between 520 and 560 ° C; however, K-Ar ages are mixed or rejuvenated. Phengite always shows mid-Tertiary Rb-Sr ages, (ii) Two biotite generations can be recognized, although textural evidence is often ambiguous. Three out of four texturally old biotites show mid-Tertiary Rb-Sr cooling ages while the oxygen isotopic fractionations point to Permian, mixed or Alpine temperatures, (iii) Comparison of radiogenic and stable isotope relations indicates that the radiogenic isotopes in the interlayer positions of the micas were mobilized during Alpine time without recrystallization, that is, without breaking Al-O or Si-O bonds. High Ti contents in young muscovites and biotites also indicate that the octahedral (and tetrahedral) sites remained undisturbed during rejuvenation. (iv) Isotopic reversals in the order of O¹⁸ enrichment between K-feldspar and albite exist. Arguments for equilibrium during Permian time are meagre because of Alpine overprinting effects. Texturally old muscovites show high temperatures and Permian Rb-Sr ages in concordancy with Rb-Sr whole rock ages. For the tectonically least affected samples, excellent concordance between quartz-muscovite and quartz-biotite Permian temperatures implies oxygen isotope equilibrium in Permian time which was undisturbed during Alpine metamorphism. Arguments for equilibrium during the mid-Tertiary metamorphism are as follows: (i) Mid-Tertiary Rb-Sr mineral isochrons of up to six minerals exist, (ii) Oxygen isotope temperatures of coexisting Alpine phengites and biotites are concordant.The major factor for the adjustment of the Permian assemblages to Alpine conditions was the degree of Alpine tectonic overprinting rather than the maximum temperatures reached during the mid-Tertiary Alpine metamorphism. The lack of exchange with externally introduced fluid phases in the samples least affected by tectonism indicates that the Monte Rosa Granite stewed in its own juices. This seems to be the major cause for the persistence of Permian ages and corresponding temperatures.     

Temperatur-Änderungen in der Erdgeschichte

This paper on “Temperature changes in earth-history” is an extension of a lecture given as an introduction to a section of equal title on the annual meeting of the Geologische Vereinigung, March 1976, in Hannover. The general development of paleoclimatological research in the last 300 years is represented on two diagrams (fig. 1–2) showing also the part of different climatic indicators. Otherwise, however, mostly new results and problems of the last years are treated (mainly papers since 1973; references of older literature are to be found in the 3^rd edition of the author's book on “Climates of the Past” = “Klima der Vorzeit”, Enke/Stuttgart 1974). This paper refers a) to some short comments on certain climatic indicators as diamictites (a similar term isSchermerhorn's “mixtite”, but “diamictite” is 6 years older and has therefore priority to “mixtite”) and “stellate nodules” (in the chapter “Mesozoic”) indicating perhaps cool climate in the Arctic. - b) Some great ice-ages are briefly discussed: Huronian (very important because of its old age); Late Proterozoic (“Eocambrian”) with many problems on account of its pretended worldwide extension. but with many uncertainities (partly pseudotillites, inconsistent paleomagnetic poles, combination of tillites with dolomites etc.); Permo-Carboniferous (many hypothesises up to 1975 try to explain the pretended “equatorial” position of tillites); Cenozoic ice-age (once “Quaternary” ice-age), with table 1 indicating some possibilities to evaluate the beginning of glaciations in Tertiary time (fig. 4). Why does glaciation start in Antarctica in the Tertiary? (Not or not only on account of drift via South Pole, but perhaps because of high relief and changes in global paleogeography). — c) Diagram of the great ice-ages in earth-history (fig. 6 b): it probably shows not all ice-ages but only the known ones indicating their maxima (i. e. times when inlandice extended to middle latitudes). This curve is probably essentially correct back to 300–400 m. y. yet especially the Precambrian time is still mostly paleoclimatic noman's-land. It is not possible to fix beginning and end of the Pre-Tertiary ice-ages exactly but at any rate the “akryogene” climates lasted longer than the “kryogene” ones (“kryogene” defined as climate with “much ice” [“pleistokryogene”], “akryogene” not as climate “without ice” but as climate with “a little ice” [“oligokryogene”]). - d) Periodicities in the temperature history: before exact dates were available (especially for Late Proterozoic and Huronian ice-ages) and before the Sahara glaciation of the Old Paleozoic was known, a periodicity of 250–300 m. y. was likely to exist. Therefore relations to the “Galactic year” were reasonable, stimulating attempts to find out plausible mechanisms for such a relation. But now, such a periodicity seems unlikely to exist (and much more one of 155 m. y., supposed byWilliams). The relative constancy of global earth temperatures over at least more than 2 billion years is more striking than their variations, though regionally the depressions may be very conspicious (in the middle, “sensitive” latitudes). Such depressions, however, are triggered by very small climatic changes on account of the existence of a hydrosphere with temperatures very favorable for a transformation of water into ice and vice versa. No other celestial body of our solar system has these optimal conditions with the consequences of occasional initiation of ice-ages. Ice ages, so to speak, are an inherited pecularity of the earth. The earth is the only “Ice-age Planet”. Under these circumstances, relatively small factors may cause ice-ages: multilateral origin of climatic changes. The most efficient parameters may be paleogeographic variations (relief etc. inclusive continental drift). Some comments are made on the radiation curves reflecting not the direct cause of glacials and interglacials but perhaps shorter climatic variations as they appear possibly in the curves of ocean temperatures (Emiliani etc.). Volcanic ashes seem not to have any farreaching influence on global temperatures; at least it is geologically impossible to support appropriate hypothesises by observations on continental volcanic sequences. The number of ash-layers in deep-sea cores may reveal sounder arguments though much more observations are needed to corroborate this supposition. — Table 2 gives a summary of the primary (planetary), secondary (multilateral) and — in special situations — tertiary “autocyclic” causes of climatic changes. Table 3 focuses on autocycles i. e. mechanisms which run. off automatically and could have caused the regular climatic variations in the Late Pleistocene with the classic glacialinterglacial sequence (not known from the older Quaternary or Pre-Tertiary ice-ages). In my opinion the most probable hypothesises on autocycles are those which were founded on wide extending subarctic continents of the northern hemisphere (qualified for the formation of large inlandice) in combination with mighty oceanic heat storage (Stokes, D. P. Adam, R. E. Newell).     

Palynology suggests hydrocarbon mobilization in Ordovician of Kasba Tadla Basin,Morocco

Palynological analysis of twelve wells shows that the metamorphic gradient of the pre-Mesozoic in the Kasba Tadla Basin of Morocco increases rapidly northwest-, southeast-, and eastward, from the center of the Basin. In the center, the Ordovician may still be releasing mobile hydrocarbons.

---

Zusammenfassung Eine palynologische Untersuchung von zwölf Bohrungen zeigt, daß der thermale Gradient sich im Premesozoikum des Kasba-Tadla-Beckens in Marokko vom Zentrum des Beckens aus nach Nordwesten, Südosten und Osten schnell vergrößert. Es ist sehr wohl möglich, daß das Ordovizium des Beckenzentrums noch flüssige und gasförmige Kohlenwasserstoffverbindungen abgibt.

---

Résumé L'analyse palynologique de 12 sondages montre que le gradient métamorphique du pré-Mésozoïque dans le Basin du Kasba Tadla, au Maroc, augmente à partir du centre du Bassin vers le nordouest, le sudest et vers l'est. Il est possible que l'Ordovicien de la partie centrale du Bassin produise encore des hydrocarbures liquides et gaseux.

---

12 , Kasba Tadla -, - . , .

---

---

The authors gratefully acknowledge support of this project through Grant GF-32510-X from the National Science Foundation, Washington, D.C., U.S.A.     

Chlorine in basalts from Iceland

Chlorine has a higher solubility in basaltic magmas than other volatiles. A theoretical degassing model predicts that less than 10% of the chlorine originally present in the magma is lost to the atmosphere during surface degassing. This prediction is born out by strong correlation between chlorine and nonvolatile elements in samples from recent volcanic eruptions in Iceland. It is concluded that the chlorine content of subaerial basaltic lavas is proportional to the chlorine content of the magmas. Assuming a roughly constant ratio between chlorine and water in the magmatic gas phase and assuming further that this ratio approximates the $\text{Cl}\text{H}{}_2\text{O}$ ratio in sea water and sediments it is possible to assign each basaltic magma a fixed amount of water. The figures thus obtained (0.3–1.2% H₂O) are identical with previously assumed water contents of basaltic magmas.The implied water contents of the melts are discussed in terms of derivation from hydrous mantle phases. It is concluded that such phases can supply only a fraction of the assumed water content, the rest is derived from an additional volatile source in the mantle. The mantle source giving rise to alkali basalts in Iceland has a lower content of volatiles than the tholeiite source.