Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.     

Spatial and Temporal Variations of Sound Speed at the PN Section

Gridded sound speed data were calculated using Del Grosso's formulation from the temperature and salinity data at the PN section in the East China Sea covering 92 cruises between February 1978 and October 2000. The vertical gradients of sound speed are mainly related to the seasonal variations, and the strong horizontal gradients are mainly related to the Kuroshio and the upwelling. The standard deviations show that great variations of sound speed exist in the upper layer and in the slope zone. Empirical orthogonal function analysis shows that contributions of surface heating and the Kuroshio to sound speed variance are almost equivalent. This revised version was published online in July 2006 with corrections to the Cover Date.     

Selenium distribution in the Rhône delta and the Gulf of Lions

Total dissolved selenium and selenium species have been measured in the Rhône river delta and the Gulf of Lions within the framework of the EROS-2000 project. The Rhône river concentration of total selenium averages 2.30 nM with important variations related to river discharge. During estuar-ine mixing, the concentrations of total dissolved selenium, selenite and selenate (calculated as the difference between total dissolved and selenite) decrease linearly with increasing salinity, without significant interconversion between selenium species. In the open Mediterranean waters of the Gulf of Lions the total dissolved selenium increases from 0.5 nM in the surface waters to 0.9 nM in the deep waters. Organic selenium has been observed in Mediterranean deep water, an observation which is different from those from the Atlantic and the Pacific Oceans. The distributions of total inorganic selenium (Σ5e), selenite and selenate are strongly related to phosphate and silicate concentrations as observed previously for the major oceans.     

Particle-bound phosphorus along an urbanized coastal plain estuary

The distribution of particle-bound phosphorus in the suspended sediment of the Delaware Estuary was examined with a sequential chemical leaching technique. The phosphorus content of particles was highest in the tidal river (140–250 μmol g⁻¹) near major anthropogenic inputs. Despite this enrichment of river particles with phosphorus, suspended particles within the salinity gradient had a phosphorus content more similar to the world's average. Sequential chemical leaches revealed that particulate phosphorus was associated with organic matter, aluminum oxides, iron oxides, and apatite in all areas of the estuary. However, ‘excess’ particle-bound phosphorus in the tidal river was associated mainly with iron oxides (27%), aluminum oxides (23%), and organic matter (50%). Within the salinity gradient, particulate phosphorus associated with iron oxides, aluminum oxides, and apatite all decreased with increasing salinity. Estuarine mixing was simulated to determine whether the observed decreases in particle-bound phosphorus pools in field samples were due to release into solution. During simulated mixing, particulate phosphorus associated with iron and aluminum oxides decreased, but no change was observed in apatite-bound phosphorus. The results of the mixing study combined with the observed particle-bound phosphorus distributions suggest that phosphate concentrations along the Delaware Estuary may be partially ‘buffered’ by aluminum and iron oxide phases.     

Dynamics of ship collisions

This paper described a procedure for simulation of the outer dynamics in ship collisions.The simulation procedure is derived using the transient equations for the horizontal motion of a ship. The hydrodynamic forces acting on the ships' hull during the collision are calculated by a strip method, where the forces acting on each section are described by means of unit response functions. These functions are determined by cosine transformation of the sectional dampings. The sectional added masses and dampings, and thereby also the sectional unit response functions, are calculated by an approximate method. The deformations of the slip structures during the collisions are modelled as non-linear springs.The resulting system of non-linear equations is solved using a numerical time-integration procedure.A number of different collision situations are simulated by means of the procedure.     

Rapid visualization of plankton abundance and taxonomic composition using the Video Plankton Recorder

Traditional methods for determining spatial distributions of planktonic taxa involve net, pump, and bottle collections followed by the tedious and time-consuming task of plankton sample analysis. Thus, plankton ecologists often require months or even years to process samples from a single study. In this paper, we present a method that allows rapid visualization of the distribution of planktonic taxa while at sea. Rapid characterization of plankton distributions is essential in the dynamic physical environment, where biological and physical patterns can change quickly. Such a “sample-and-observe” capability is necessary for mapping ephemeral features (such as patches, eddies, jets, plumes) and determining appropriate locations to conduct more localized sampling, including in situ observational studies. We describe the techniques used in imaging the plankton, analyzing the video, and visualizing the data. We present an example of at-sea data analysis conducted aboard R.V. Columbus Iselin on Georges Bank in May 1994 and visualizations of the 3-dimensional distribution of selected planktonic taxa in a 2 × 2 km × 90 m volume of seawater. A video of the image processing and visualization is included on the CD-ROM accompanying this volume and is an essential part of this paper.     

Fast static correction methods for high-frequency multichannel marine seismic reflection data: A high-resolution seismic study of channel-levee systems on the Bengal Fan

Very high-frequency marine multichannel seismic reflection data generated by small-volume air- or waterguns allow detailed, high-resolution studies of sedimentary structures of the order of one to few metres wavelength. The high-frequency content, however, requires (1) a very exact knowledge of the source and receiver positions, and (2) the development of data processing methods which take this exact geometry into account. Static corrections are crucial for the quality of very high-frequency stacked data because static shifts caused by variations of the source and streamer depths are of the order of half to one dominant wavelength, so that they can lead to destructive interference during stacking of CDP sorted traces. As common surface-consistent residual static correction methods developed for land seismic data require fixed shot and receiver locations two simple and fast techniques have been developed for marine seismic data with moving sources and receivers to correct such static shifts. The first method – called CDP static correction method – is based on a simultaneous recording of Parasound sediment echosounder and multichannel seismic reflection data. It compares the depth information derived from the first arrivals of both data sets to calculate static correction time shifts for each seismic channel relative to the Parasound water depths. The second method – called average static correction method – utilises the fact that the streamer depth is mainly controlled by bird units, which keep the streamer in a predefined depth at certain increments but do not prevent the streamer from being slightly buoyant in-between. In case of calm weather conditions these streamer bendings mainly contribute to the overall static time shifts, whereas depth variations of the source are negligible. Hence, mean static correction time shifts are calculated for each channel by averaging the depth values determined at each geophone group position for several subsequent shots. Application of both methods to data of a high-resolution seismic survey of channel-levee systems on the Bengal Fan shows that the quality of the stacked section can be improved significantly compared to stacking results achieved without preceding static corrections. The optimised records show sedimentary features in great detail, that are not visible without static corrections. Limitations only result from the sea floor topography. The CDP static correction method generally provides more coherent reflections than the average static correction method but can only be applied in areas with rather flat sea floor, where no diffraction hyperbolae occur. In contrast, the average static correction method can also be used in regions with rough morphology, but the coherency of reflections is slightly reduced compared to the results of the CDP static correction method.     

A new bathymetric model for the central Fram Strait

Based on data from R/V Polarstern multibeam sonar surveys between 1984 and 1997 high resolution bathymetry has been generated for the central Fram Strait. The area insonified covers approx. 36,500 km² between 78–80°N and 0–7.5°E allowing the creation of a Digital Terrain Model (DTM) with 100 m grid spacing. The DTM was utilized for contouring and generation of a new series of bathymetric charts (AWI Bathymetric Charts of the Fram Strait, AWI BCFS) at a scale of 1:100,000. The paper starts with a brief introduction to the regional setting of the study area comprising information on the local links between bathymetry, sea ice transport and water mass exchange. The bathymetric feature names used in this article and how they were chosen is outlined. Next, the input data and processing applied are described. Thereafter the newly created grid and contour data are put into context with existing data sets. Finally the main bathymetric features of the area are characterized and the generated data products available for public disposal are specified.