Areal versus linear evaluation of relationship between drainage basin lithology and geochemistry of stream and overbank sediments in low-order mountainous drainage basins

The comparison of two multiple regression models is based on the assumption that geochemical composition of the drainage basin alluvial sediments is derived primarily from the underlying bedrock lithology. The parent material is integrated with both stream sediment and overbank sediment geochemistry via the two essentially different approaches as regards the drainage basin geomorphological data: (1) as the relative area of influence representing a portion of the catchment basin occupied by a specific rock type and (2) as the relative “line” of influence representing a narrow zone of the underlying bedrock traversed by the perennial streams which form the active stream network. The model comparison is established on the goodness-of-fit test for both experimental designs and for the same set of data. Both experiments converge on the linear approach as the more appropriate model in evaluating the lithologic influence on the analysed sample media in small mountainous watersheds.     

Determination of the apparent copper complexing capacity of seawater by anodic stripping voltammetry

A new experimental technique using differential pulse anodic stripping voltammetry with a thin-film mercury electrode and efficient mixing of the electrolyte for the apparent copper complexing capacity of seawater is proposed. The effects of some factors such as type of electrode and cell, pH of the solution, potential of deposition, time of equilibration, and influence of a non-ionic surface active agent on the measurements are examined. Experimental results for the apparent copper complexing capacity of seawater are calculated presuming 1:1 inert complex formation. By using EDTA as a model ligand, it is shown that the proposed procedure with efficient mixing of the solution excludes any appreciable kinetic influence upon the electroanalytical results.     

Diffuse Component Spectra of Solar Active Regions at Submillimeter Wavelengths

Solar maps at 212 and 405 GHz obtained by the Solar Submillimetric Telescope (SST) show regions of enhanced brightness temperature, which coincide with the location of active regions. A statistical study of the radio emission from these active regions was performed for the first time at such high frequencies during 23 days on June and July 2002, when the atmospheric opacity was low. The brightest regions on the maps were chosen for this study, where the brightness excess observed varies from 3 to 20% above quiet Sun levels (i.e., 200–1000 K) at both wavelengths. Sizes of the regions of enhanced emission calculated at half the maximum value were estimated to be between 2′ and 7′. These sizes agree with observed sizes of active regions at other wavelengths such as Hα and ultraviolet. An important result is that the flux density spectra of all sources increase toward submillimeter frequencies, yielding flux density spectral index with an average value of 2.0. The flux density of the active region sources were complemented with that from maps at 17 and 34 GHz from the Nobeyama Radio Heliograph. The resulting spectra at all four frequencies were fit considering the flux density to be due to thermal bremsstrahlung from the active region. In the calculations, the source radius was assumed to be the mean of the measured values at 212 and 405 K. The effective temperatures of the radio emitting source, assumed homogeneous, obtained from this fit were 0.6–2.9 × 10⁴ K, for source diameters of 2′–7′.     

Water flow and solute transport model of potentially toxic elements through unsaturated zone at regional wellfield Kosnica

The objective of this work was to build a prognostic water flow model and potentially toxic elements (lead, cadmium, zinc) transport model in the unsaturated zone. Research was conducted in the catchment area of Kosnica regional wellfield, where the unsaturated zone is characterised by Fluvisol. Lower sorption capacities were determined in the first horizons for all three potentially toxic elements. Correlation coefficient of the measured and simulated values of tracer concentration is 0.58 for the AC horizon and 0.84 for the 2C/C1 horizon. Based on calibrated water flow and transport parameters, a prognostic water flow model and potentially toxic elements (lead, cadmium, zinc) transport model in the unsaturated zone was built. In case of an accidental spill of potentially toxic elements with concentrations of 1000 mg/l, the risk of contamination of the aquifer is present. Copyright © 2016 John Wiley & Sons, Ltd.     

Present and future climatologies in the phase I CREMA experiment

We provide an overall assessment of the surface air temperature and precipitation present day (1976–2005) and future (2070–2099) ensemble climatologies in the Phase I CREMA experiment. This consists of simulations performed with different configurations (physics schemes) of the ICTP regional model RegCM4 over five CORDEX domains (Africa, Mediterranean, Central America, South America, South Asia), driven by different combinations of three global climate models (GCMs) and two greenhouse gas (GHG) representative concentration pathways (RCP8.5 and RCP4.5). The biases (1976–2005) in the driving and nested model ensembles compared to observations show a high degree of spatial variability and, when comparing GCMs and RegCM4, similar magnitudes and more similarity for precipitation than for temperature. The large scale patterns of change (2070–2099 minus 1976–2005) are broadly consistent across the GCM and RegCM4 ensembles and with previous analyses of GCM projections, indicating that the GCMs selected in the CREMA experiment are representative of the more general behavior of current GCMs. The RegCM4, however, shows a lower climate sensitivity (reduced warming) than the driving GCMs, especially when using the CLM land surface scheme. While the broad patterns of precipitation change are consistent across the GCM and RegCM4 ensembles, greater differences are found at sub-regional scales over the various domains, evidently tied to the representation of local processes. This paper serves to provide a reference view of the behavior of the CREMA ensemble, while more detailed and process-based analysis of individual domains is left to companion papers of this special issue.     

Validation of Arenicola marina in field toxicity bioassays using benthic cages: biomarkers as tools for assessing sediment quality

Sediment toxicity assessments using caged organisms present advantages over using laboratory and native community studies. The use of caged Arenicola marina in sediment toxicity assessments was evaluated. Lugworms were exposed in situ to sediments from coastal and port areas in Spain for seven days, and the activities of the biotransformation enzymes ethoxyresorufin O-deethylase, dibenzylfluorescein dealkylase and glutathione S-transferase, the activities of the antioxidant enzymes glutathione reductase and glutathione peroxidase and lipid peroxidation were then analyzed as biomarkers. Biomarker results and sediment physicochemical data were integrated. Cádiz Bay (SW Spain) sediments presented metal contamination that was not linked to a biochemical response. In LPGC Port (SW Spain), Pb contamination exhibited a moderate toxic potential, while PAHs, and presumably pharmaceuticals, provoked biochemical responses that efficiently prevented lipid peroxidation. In Santander Bay (N Spain), exposure to PAHs and, presumably, pharmaceuticals induced biomarker responses, but lipid peroxidation occurred nevertheless. These results indicated that caged A. marina were effective for the assessment of sediment quality and that the selected biomarkers were sufficiently sensitive to identify chemical exposure and toxicity.