High-resolution mm interferometry and the search for massive protostellar disks: the case of Cep-A HW2

The direct detection of accretion onto massive protostars through rotating disks constitutes an important tile in the massive-star-formation-theory mosaic. This task is however observationally very challenging. A very interesting example is Cepheus A HW2. The properties of the molecular emission around this YSO seems to suggest the presence of a massive rotating disk (cf. Patel et al. in Nature 437:109, 2005). We have carried out sub-arcsec-resolution PdBI observations of high-density and shock tracers such as SO₂, SiO, CH₃CN, and CH₃OH towards the center of the outflow. A detailed analysis of the spatial distribution and of the velocity field traced by all observed species leads us to conclude that, on a ∼700 AU scale, the Cep-A “disk” is actually the result of the superposition of multiple hot-core-type objects, at least one of them ejecting an outflow at a small angle with respect to the line of sight. Together with the well-known large-scale outflow ejected by HW2, this setup makes for a very complex spatial and kinematic picture. Based on observations carried out with the IRAM Plateau de Bure Interferometer. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain).     

Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments?

Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI₅₅₀) and organic carbon (OC) content and between LOI at 950 °C (LOI₉₅₀) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI₅₅₀ and LOI₉₅₀ show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI₁₀₅) is a good qualitative proxy for the trends in gypsum content.     

Analysis of the surface of different marbles by X-ray photoelectron spectroscopy (XPS) to evaluate decay by SO2 attack

Atmospheric pollution is one of the main agents of decay in monuments and other works of art located in industrialised urban centres. SO₂ is a permanent and abundant component of air pollution and, although it does not have an immediate visual effect, after continuous exposure, it can cause irreversible damage to building materials. Marble is one of the most commonly used ornamental stones in historical monuments and its mineralogical composition makes it very susceptible to damage caused by exposure to SO₂. To measure the chemical reactions caused on marble by the action of atmosphere rich in SO₂, selected calcitic and dolomitic samples were altered by weathering accelerated test. For this, seven marble types (four calcitic and three dolomitic) were exposed to high concentration of sulphur dioxide for 24 h in a climate chamber under controlled temperature and humidity conditions (20 °C and > 90 % HR). Changes on marble surfaces caused by reactions of SO₂ with calcite and dolomite were studied using two non-destructive techniques: chromatic change by means of colorimetry and chemical analysis using X-ray photoelectron spectroscopy (XPS). The development of new mineral phases was also observed by scanning electron microscopy. Colorimetric analysis revealed a decrease in lightness and chromatic parameters suggesting that these changes were due to the development of new mineral phases in all marbles. The XPS technique, which is generally used in the analysis of metals, is relatively new in the field of stone deterioration. It enabled us to recognise the development of sulphites and sulphates on marble surfaces with high precision, after just 24 h of exposure to high SO₂ concentrations and to distinguish different decay paths for calcitic and dolomitic marbles.     

Occurrence of priority pollutants in WWTP effluents and Mediterranean coastal waters of Spain

A comprehensive study aimed at evaluating the occurrence, significance of concentrations and spatial distribution of priority pollutants (PPs) along the Comunidad Valenciana coastal waters (Spain) was carried out in order to fulfil the European Water Framework Directive (WFD). Additionally, PP concentrations were also analysed in the effluent of 28 WWTPs distributed along the studied area. In coastal waters 36 organic pollutants of the 71 analysed, including 26 PPs were detected although many of them with low frequency of occurrence. Only 13 compounds, which belong to four different classes (VOCs, organochlorinated pesticides, phthalates and tributyltin compounds (TBT)) showed a frequency of occurrence above 20% in coastal waters. In the results obtained until now, octylphenol, pentachlorobenzene, DEHP and TBT exceeded the annual average concentration (EQS-AAC), and only TBT surpassed the maximum allowable concentration (EQS-MAC). The most frequent contaminants determined in coastal waters were also present in WWTP effluents.     

Characterization of loess in central Spain: a microstructural study

The purpose of this paper is to characterize the materials developed in the middle Tajo River valley, Central Spain. These sediments are loess, the characterization of which has not been reported in the international bibliography. The sediments are related to the next geological context and their characterization is indispensable to locate the said material in the adequate environment. A few different methods have been employed in this study, such as the pipette method (for determining the grain size) and separation of the light and heavy minerals of the sand fraction by using bromoform. The mineralogical composition was determined by XRD and textural study was accomplished by SEM/EDX. The loessic materials are silt-clay or sandy-silt that are quite unstable. The mineralogical composition shows quartz, feldspar, calcite and clay minerals. Some samples show gypsum; this mineral and calcite present dissolution and stability problems. The heavy minerals starting from the sand fraction are tourmaline, zircon, garnet, staurolite, sillimanite and biotite associations. The studies carried out with SEM show that the quartz grain surfaces present etch pits typical of the wind-blown origin.     

In situ and high frequency monitoring of suspended sediment properties using a spectrophotometric sensor

It is well known that sediment properties, including sediment‐associated chemical constituents and sediment physical properties, can exhibit significant variations within and between storm runoff events. However, the number of samples included in suspended sediment studies is often limited by time‐consuming and expensive laboratory procedures after stream water sampling. This restricts high frequency sampling campaigns to a limited number of events and reduces accuracy when aiming to estimate fluxes and loads of sediment‐associated chemical constituents. In this study, we address the potential of a portable ultraviolet–visible spectrophotometer (220–730 nm) to estimate suspended sediment properties in a resource efficient way. Several field deployable spectrophotometers are currently available for in‐stream measurements of environmental variables at high temporal resolution. These instruments have primarily been developed and used to quantify solute concentrations (e.g. dissolved organic carbon and NO₃‐N), total concentrations of dissolved and particulate forms (e.g. total organic carbon) and turbidity. Here we argue that light absorbance values can be calibrated to estimate sediment properties. We present light absorbance data collected at 15‐min intervals in the Weierbach catchment (NW Luxembourg, 0.45 km²) from December 2013 to January 2015. In this proof‐of‐concept study, we performed a local calibration using suspended sediment loss‐on‐ignition (LOI) measurements as an example of suspended sediment property. We assessed the performance of several regression models that relate light absorbance measurements with the percentage weight LOI. The MM‐robust regression method presented the lowest standard error of prediction (0.48%) and was selected for calibration (adjusted r² = 0.76 between observed and predicted values). The model was then used to predict LOI during a storm runoff event in December 2014. This study demonstrates that spectrophotometers can be used to estimate suspended sediment properties at high temporal resolution and for long‐time spans in a simple, non‐destructive and affordable manner. Copyright © 2016 John Wiley & Sons, Ltd.     

Nonlinear Electric Field Diffusion in Plasmas

Approximated similarity solutions are given for the problem of electric field penetration into a semi-infinite plasma with nonlinear saturating conductivity (exponential type), using the two point quasifractional approximants method.     

Ejection and collision orbits of the spatial restricted three-body problem

We begin by describing the global flow of the spatial two body rotating problem, =0. The remainder of the work is devoted to study the ejection and collision orbits when >-0. We make use of the blow up techniques to show that for any fixed value of the Jacobian constant the set of these orbits is diffeomorphic to S²×R. Also we find some particular collision-ejection orbits.     

Late Mesozoic and Cenozoic palaeomagnetism of Australia–I. A redetermined apparent polar wander path

Summary. Palaeomagnetic measurements have been carried out on one Cretaceous and five Cenozoic sedimentary sequences of Australia; of those, one is in the Carnarvon Basin of north-western Australia, and the others are in the Otway Basin of south-eastern Australia. The new results are used together with those published previously to define a revised late Mesozoic–Cenozoic apparent polar wander path for Australia. This path differs from earlier, basalt-derived paths by the absence of a large westward excursion and zig-zag irregularities. It is characterized instead by a substantially straight Cenozoic trajectory, a sharp bend in the Late Cretaceous, and a non-uniform rate of apparent polar wander.
The early Tertiary segment of the new path lies north of the original paths, thus eliminating a discrepancy that has been noted previously between the Indian and Australian palaeomagnetic data (Luyendyk & Rennick, Peirce and Klootwyk & Peirce). A re-examination of the original data suggests that this discrepancy, as well as two others in the Australian results, may have been caused principally by incomplete time-averaging of remanence directions, because the volcanics on which the results were based had been extruded episodically.     

Observations of the Temperature and Humidity Structure Parameter Over Heterogeneous Terrain by Airborne Measurements During the LITFASS-2003 Campaign

We used numerical simulations to investigate the general relationship between urban morphology and the intensity of wind gusts in built-up areas at the pedestrian level. The simulated urban boundary layer developed over a 19.2 km (length) \(\times \) 4.8 km (width) \(\times \) 1.0 km (height) simulation domain, with 2-m resolution in all directions, to explicitly resolve the detailed shapes of buildings and the flow at the pedestrian level. This complex computation was accomplished using the lattice Boltzmann method and by implementing a large-eddy simulation model. To generalize the results, a new parameter that expresses the intensity of gusts (the gust index, \({\tilde{U}}_{ max})\) was defined as the local maximum wind speed divided by the freestream velocity. In addition, this parameter was decomposed into the mean wind-speed ratio, \({\tilde{U}} \) and turbulent gust ratio, \({\tilde{U}}^{{\prime }}\) to evaluate the qualities of gusts. These parameters were useful for quantitatively comparing the gust intensities within urban canopies at different locations or even among different experiments. In addition, the entire horizontal domain was subdivided into homogeneous square patches, in which both the simulated gust parameters and the morphological characteristics of building geometries were averaged. This procedure masked the detailed structure of individual buildings but retained the bulk characteristics of the urban morphology. At the pedestrian level, the gust index decreased with increasing building cover. Compared to \({\tilde{U}} \), the quantity \({\tilde{U}}^{{\prime }}\) notably contributed to the index throughout the range of plan area index \((\lambda _p)\) values. The dependences of all normalized wind-speed ratios transiently changed at \(\lambda _p =~0.28\). In cases where \(\lambda _p < 0.28, {\tilde{U}} \) decreased with increasing \(\lambda _p \), although \({\tilde{U}}^{{\prime }}\) was almost constant. In cases where \(\lambda _p > 0.28, {\tilde{U}}\) was almost constant and \({\tilde{U}}^{{\prime }}\) decreased with increasing \(\lambda _p \). This was explained by the change in flow regimes within the building canyon. At a higher elevation above the canopy layer, \(\lambda _p \) becomes less relevant to normalized wind-speed ratios, and instead the aerodynamic roughness length became important.