Effects of mining wastes on a seagrass ecosystem: metal accumulation and bioavailability, seagrass dynamics and associated community structure

Two different Cymodocea nodosa (Ucria) Ascherson beds growing in mining-contaminated sediments were compared with two reference beds in the Mar Menor coastal lagoon. The accumulation of Zn, Pb and Cd in different fractions of the plant, the sediment parameters that regulate the availability of metals, the seabed structure and dynamics of each seagrass bed and its associated macroinvertebrate community were studied. C. nodosa accumulates metals from the sediments and reflects their bioavailability for this seagrass. At each station, the metal content of the rhizomes was lower than that of leaves and roots. The concentration of acid-volatile sulfides does not seem to influence the availability of metals to the seagrass, possibly due to oxygen transport to underground tissues. The highest metal concentration in all the contaminated stations was found in the leaf-biofilm, due to the formation of complexes between metals and the extracellular polymeric substances that form the biofilm. All the seagrass beds were seen to be undergoing expansion, those growing in contaminated sediments accumulating great quantities of metals and showing highest photosynthetic leaf surface area and highest leaf biomass. However, these structural parameters were not seen to be responsible for the differences in the faunal composition observed between contaminated and reference beds. Moreover, the multivariate analysis identified the metal content of leaves, biofilm and sediments as important variables that may be responsible for these differences in faunal composition. In this study we have demonstrated that both the seagrass C. nodosa and the biofilm on the plant leaves may be used as environmental tools in the Mar Menor lagoon. The former is an useful indicator of sediment contamination, whereas the latter seems to be a good sentinel of water quality.     

Impact of lithology and soil properties on abandoned dryland terraces during the early stages of soil erosion by water in south‐east Spain

Soil erosion by water in abandoned dry terraces is one of the most important environmental problems in semiarid areas, enhancing biological degradation and reducing possible resources that can be obtained. However, little is known about the effects of the types of lithology and soil properties on the early stages of soil erosion. Therefore, the main aim of this research was to assess the effect of different lithologies (marls, limestones, and metamorphic—phyllites, schists, and greywackes—materials) and soil properties on the early stages of soil erosion by water in abandoned dry terraces, compared with similar terraces still in agricultural use. Soil analyses (texture, aggregate stability, and bulk density) and 22 rainfall simulations were carried out under dry conditions. During the experiments, local inclination, vegetation and stone cover, total organic matter, and antecedent soil moisture were also quantified. The results showed that the highest soil loss (41.41 g/m² in cultivated plots and 17.05 g/m² in the abandoned plots) and runoff (3.79 L/m² in the abandoned plot) occurred on marl substrata. Marls also showed the shallowest infiltration front (9 cm) and lowest infiltration rate (4.3 cm/min). Limestones and, especially, metamorphic areas, showed a lower degree of soil erosion, higher infiltration rates, and deeper infiltration fronts.     

Analysis of incorporating groundwater exchanges in hydrological models

In many catchments, the geographical demarcation does not coincide with the limits of the aquifers, so groundwater may be exchanged beyond their topographic boundaries. By studying groundwater exchanges, the natural resources of a catchment can be better assessed, and the divergences between hydrological models and measurements can be explained. The aim of this work is to reveal the importance of including groundwater exchanges in the hydrological modelling of some catchments, using a water balance model. For this purpose, a simple example is conducted. The so‐called parent model scheme is modified to only allow groundwater exchanges, and it is applied to the headwater of the Segura River Basin District, located in the southeast of Spain. This area is selected because groundwater plays an important role in surface hydrology. The results reveal that groundwater exchanges cannot be neglected in some catchments when assessing water resources because their integration in the hydrological model corrects errors in the water balance. Moreover, this paper proves that water balance models are a useful tool for estimating groundwater exchanges between catchments, which can be contrasted with more complex distributed models or isotopic tracers if there is enough information available. Copyright © 2015 John Wiley & Sons, Ltd.     

Formulation of a three‐dimensional constitutive model for unsaturated soils incorporating mechanical–water retention couplings

Wheeler, Sharma and Buisson proposed an elasto‐plastic constitutive model for unsaturated soils that couples the mechanical and water retention behaviours. The model was formulated for isotropic stress states and adopts the mean Bishop's stress and modified suction as stress state variables. This paper deals with the extension of this constitutive model to general three‐dimensional stress conditions, proposing the generalized stress–strain relationships required for the numerical integration of the constitutive model. A characteristic of the original model is the consideration of a number of elasto‐plastic mechanisms to describe the complex behaviour of unsaturated soils. This work presents the three‐dimensional formulation of these coupled irreversible mechanisms in a generalized way including anisotropic loading. The paper also compares the results from the model with published experiments performed under different loading conditions. The response of the model is very satisfactory in terms of both mechanical and water retention behaviours. Copyright © 2013 John Wiley & Sons, Ltd.     

Paleontology,sedimentology and paleoenvironment of a new fossiliferous locality of the Jurassic Cañadón Asfalto Formation,Chubut Province,Argentina

A new Late Jurassic assemblage of “conchostracans”, ostracods, bivalves and caddisfly cases from the locality “Estancia La Sin Rumbo”, Chubut Province (Patagonia, Argentina) is recorded. The fossils occur in the upper part of an outcropping 45 m thick volcaniclastic lacustrine sequence of yellowish tuffs and tuffites of the Puesto Almada Member, which is the upper member of the Cañadón Asfalto Formation with U/Pb age of 161 ± 3 Ma. The sequence represents one sedimentary cycle composed of a (lower) hemicycle of expansion and a (higher) hemicycle of contraction of the water body. The invertebrates lived in small freshwater bodies during the periods of expansion of the lake. The occurrence of a great number of small spinicaudatans, associated with mud-cracks, is evidence of dry climatic conditions and suggests several local mortality events. The spinicaudatan record of the fushunograptid–orthestheriid (component of the Eosestheriopsis dianzhongensis fauna) and the presence of Congestheriella rauhuti Gallego and Shen, suggest a Late Jurassic (Oxfordian to Tithonian) age. Caddisfly cases are recorded for the first time in the Cañadón Asfalto Basin.     

Modelling discharge through artesian springs based on a high‐resolution piezometric network

Artesian springs are localized aquifer outlets that originate when pressurized ground water is allowed to rise to the surface. Computing artesian discharge directly is often subject to practical difficulties such as restricted accessibility, abundant vegetation or slow flow rates. These circumstances call for indirect approaches to quantify flow. This paper presents a method to estimate ground water discharge through an upwelling spring by means of a three‐layer steady‐state groundwater flow model. Model inputs include on‐site measurements of vertical sediment permeability, sediment temperatures and hydraulic gradients. About 70 spring bed piezometers were used to carry out permeability tests within the spring sediments, as well as to quantify the hydraulic head at different depths below the discharge point. Sediment temperatures were measured at different depths and correlated to permeabilities in order to demonstrate the potential of temperature as a substitute for cumbersome slug tests. Results show that the spatial distribution of discharge through the spring bottom is highly heterogeneous, as sediment permeability varies by several orders of magnitude within centimetres. Sensitivity analyses imply that geostatistical interpolation is irrelevant to the results if field datasets come from a sufficiently high resolution of piezometric records. Copyright © 2013 John Wiley & Sons, Ltd.     

Determination of synthetic wind functions for estimating open water evaporation with Computational Fluid Dynamics

A computational fluid dynamics (CFD)‐based methodology is proposed to derive convective mass‐transfer coefficients (wind functions) that are required for estimating evaporation of water bodies with the mass‐transfer method. Three‐dimensional CFD was applied to model heat transfer in two water bodies: a Class‐A tank evaporimeter and an on‐farm artificial pond. The standard k–? model assuming isotropic turbulence was adopted to describe turbulent heat transport, whereas the heat and mass transfer analogy was assumed to derive the wind functions. The CFD‐derived wind functions were very similar to those empirically derived from the experimental water bodies. The evaporation rates calculated with the synthetic wind functions were in good agreement with hourly and daily evaporation measurements for the tank and pond, respectively. The proposed CFD‐approach is generalisable and cost effective, because it has low input data requirements. Besides, it provides additional capability of modelling the spatial distribution of the evaporation rate over the water surface. Although the application of CFD to water bodies evaporation modelling is still in development, it looks very promising. Copyright © 2012 John Wiley & Sons, Ltd.     

Short-term effects of the prestige oil spill on the peregrine falcon (Falco peregrinus)

We have monitored the distribution, population status, breeding success, turnover rate and diet of a Peregrine Falcon population in Bizkaia (North of Spain) since 1997. On the 13th November 2002, the tanker Prestige sunk off La Coruña (NW Spain) causing an oil spill that affected the whole of the Cantabrian Coast and the Southwest of France. The total number of birds affected by the Prestige oil spill was expected to be between 115,000 and 230,000, some of them raptors. The loss of clutches during the incubation period increased significantly and was correlated with the loss of females. Moreover, the turnover rate of the population increased from 21% to 30%. The polycyclic aromatic hydrocarbon concentrations in the eggs, collected from five nests after they were deserted, ranged from 21.20 ng/g to 461.08 ng/g, values which are high enough to cause the death of the embryos and poisoning of adult birds. The effects of pollution reached inland since some inland-breeding falcons prey on shorebirds that use rivers during their migratory flights. As the Prestige oil spill has clearly resulted in increased rates of adult mortality and reduced fertility, we suggest that the environmental authorities urgently undertake measures aimed at protecting the Peregrine Falcon in Bizkaia.