The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.     

Natural occurrence of higher thiadiamondoids and diamondoidthiols in a deep petroleum reservoir in the Mobile Bay gas field

A series of higher thiadiamondoids and diamondoidthiols, including thiatetramantanes, tetramantanethiols, thiapentamantanes, pentamantanethiols, thiahexamantanes, hexamantanethiols and thiacylcohexamantane, was discovered in a gas condensate produced from a very deep (6274 m, 20,585 ft) petroleum reservoir in the Bon Secour Bay in the Mobile Bay gas field, located offshore Alabama in the northern Gulf of Mexico, USA. This appears to be the first reported natural occurrence of these compounds. Several isomers of higher thiadiamondoids and diamondoidthiols were identified using full scan gas chromatography-mass spectrometry (GC-MS) coupled with GC-sulfur chemiluminescence detection (GC-SCD) and GC × GC-time of flight mass spectrometry (GC × GC-TOFMS). These higher thiadiamondoids and diamondoidthiols are associated with abundant lower homologs including thiaadamantanes, thiadiamantanes, thiatriamantanes and their thiol groups. The origin of these compounds in petroleum has not been reported. It is speculated that similar to lower thiadiamondoids and diamondoidthiols, higher ones are possibly formed from the sulfurization of their precursor diamondoids during TSR, a conclusion supported by the occurrence of open-cage higher diamondoidthiols and sulfur isotopic data of higher thiadiamondoids and diamondoidthiols isolated from the Mobile Bay condensate. The presence of higher thiadiamondoids and diamondoidthiols is indicative of the occurrence of TSR and can be used to predict sour gas production.     

Composition and diagenesis of neutral carbohydrates in sediments of the Baltic-North Sea transition

The distribution and composition of neutral carbohydrates in the solid phase and porewater, and their role in carbon cycling were investigated in contrasting marine sediments of the Baltic-North Sea region. Depth-invariant profiles of particulate carbohydrates (PCHO) and low PCHO yields (PCHO/organic carbon) indicated that a small inert carbohydrate fraction deposits on the sediment at the deeper stations in the northern Kattegat and Skagerrak compared to the shallower stations further South. This was supported by long-term sediment incubations, in which the PCHO concentrations remained unchanged during 480 days, revealing that neutral carbohydrates play a minor role in carbon mineralization at the deeper sites. In contrast, the reactivity of PCHO was high (first-order rate constant of 3.2 yr⁻¹) at one shallow site in the Belt Sea. Monosaccharide spectra were uniform with sediment depth and between sites with the exception of the shallowest site in the middle of Kattegat, where glucose dominated the polymers at the surface. This was likely due to benthic diatoms. Addition of fresh algae to surface sediment from the deeper sites resulted in a preferential mineralization of particulate glucose polymers. The addition of algae also resulted in an initial pulse of glucose in the porewater pools of total hydrolyzable carbohydrates (THCHO), indicating a faster hydrolysis of glucose polymers in the particulate phase than the subsequent hydrolysis and bacterial consumption of oligo- and polymers of glucose in the porewater. This study shows that some carbohydrates such as glucose polymers are selectively utilized by heterotrophic bacteria during the settling of organic particles through the water column, and a relatively inert fraction arrives to the sediments where much of it escapes mineralization and becomes permanently buried. In shallow coastal environments, where the degradation in the water column is less extensive and where benthic algae may represent a local carbohydrate source, neutral carbohydrates appear to be more important in organic matter mineralization.     

Nutrient transport in a riverine-influenced,tidal freshwater bayou in Louisiana

Transport of ammonium (NH₄ ⁺), nitrate + nitrite (NO₃ ^?), total Kjeldahl nitrogen (TKN), soluble reactive phosphate (SRP), and total suspended solids (TSS) was measured in a freshwater tidal bayou located in a marsh system near the mouth of the Atchafalaya River in Louisiana. Sampling was conducted six times over one year and was timed to assess effects of seasonal variation in river flow and mean sea level of the Gulf of Mexico on material fluxes. Net fluxes of all materials were large and ebb directed in all seasons except fall, when net transport was 2 to 3 orders-of-magnitude smaller than in any other season. These results demonstrate that riverine forcing was the primary influence on materials transport in all seasons except fall when tidal forcing was most important. The range of net fluxes (g s^?1) for each nutrient was as follows (a negative sign indicates a net export toward the Gulf): NO₃ ^?, ?0.006 to ?6.69; TKN, 0.09 to ?10.41; NH₄ ⁺, ?0.02 to ?1.36; SRP, ?0.001 to ?0.53; TSS, ?2 to ?81. Analysis of nutrient concentrations indicated the marsh/aquatic system removed NO₃ ^?, SRP, and TSS from the water column from late spring through early fall and released NH₄ ⁺ and TKN in summer. The results of this study show that net materials export per unit cross section channel area increased as riverine influence increased.     

A PROCESS OF STELLAR NUCLEOSYNTHESIS WHICH MIMICKS MASS FRACTIONATION IN P-XENON

The combination of the O-shell theory of Heymann and Dziczkaniec and the supernova theory of Woosley and Howard clearly identifies the astrophysical sites for the formation of the anomalous light Xe component in carbonaceous chondrites. These sites are the O- and Ne-shells, and possibly C-shell of a massive star. Most of the ¹²⁴Xe and ¹²⁶Xe are formed in the O-shell during hydrostatic core silicon-burning, when a seed of heavy nuclei is exposed to an effective temperature near T₉ = 2.0. ¹²⁸Xe is formed via ¹²⁸Ba in the O-shell, but the amounts appear too small to satisfy the deduced ¹²⁸Xe/¹²⁴Xe and ¹²⁸Xe/¹²⁶Xe yield ratios from the chondrites. However, substantial amounts of ¹²⁸Xe can be formed in the adjacent Ne- and C-shells during the explosion. The formation of ¹²⁸Ba in the O-shell would increase if the (γ, α) photodisintegration rate in ¹²⁸Ba is actually smaller than calculated by Woosley and Howard. Lewis et al. have proposed that the anomalous light Xe component is mass-fractionated normal Xe. It is in this sense that the process of stellar nucleosynthesis of the present paper mimicks mass-fractionation.