Polybrominated diphenyl ethers and their hydroxylated/methoxylated analogs: environmental sources, metabolic relationships, and relative toxicities

Brominated compounds are ubiquitous in the aquatic environment. The polybrominated diphenyl ether (PBDE) flame retardants are anthropogenic compounds of concern. Studies suggest that PBDEs can be biotransformed to hydroxylated brominated diphenyl ethers (OH-BDE). However, the rate of OH-BDE formation observed has been extremely small. OH-BDEs have also been identified as natural compounds produced by some marine invertebrates. Another class of compounds, the methoxylated BDEs (MeO-BDEs), has also been identified as natural compounds in the marine environment. Both the OH-BDEs and MeO-BDEs bioaccumulate in higher marine organisms. Recent studies have demonstrated that MeO-BDEs can be biotransformed to OH-BDEs and this generates greater amounts of OH-BDEs than could be generated from PBDEs. Consequently, MeO-BDEs likely represent the primary source of metabolically derived OH-BDEs. Given that for some endpoints OH-BDEs often exhibit greater toxicity compared to PBDEs, it is prudent to consider OH-BDEs as chemicals of concern, despite their seemingly "natural" origins.     

Postglacial midge community change and Holocene palaeotemperaturereconstructions near treeline, southern British Columbia (Canada)

Stratigraphic analysis of fossil chironomid head capsules wasperformed at North Crater Lake and Lake of the Woods, located at treeline (2250m) in the Ashnola region of southernmost British Columbia. Priorto 10,000 yr BP, cold conditions were indicated by the lack oftemperate taxa and the presence of cold-stenotherms. The abundance anddiversity of warm-adapted taxa (e.g., Dicrotendipes,Microtendipes, Polypedilum and Cladopelma)increased rapidly after 9500 yr BP, whereas taxa indicative ofcold conditions disappeared. Beginning prior to deposition of the Mazama ash(6730 ± 40 yr BP), several warm-adapted taxa decreasedin abundance. Mid- to late-Holocene assemblages (ca. 4500yr BP to present) indicated continued cooling as revealed by afurther reduction in diversity and abundance of warm-adapted taxa atboth lakes, and the reappearance of cold-stenotherms in Lake of theWoods. Diversity changes in the cores paralleled the inferred climatic changes.Diversity was low during the late-glacial, increased in theearly-Holocene, and declined after 5400 yr BP.To quantitatively infer past climatic changes, a newweighted yphen;averaging partial-least-squares (WA-PLS)model was developed and applied to the fossil midge data. The quantitativereconstructions revealed late-glacial mean July air temperatures rangingfrom about 8 to 10°C. Summer air temperatures were highest inthe early Holocene (13 to 17°C), gradually decreasing by about3°C through the mid- to late-Holocene.     

What we know about elemental bulk chondrule and matrix compositions: Presenting the ChondriteDB Database

Chondrules and matrix are the major components of chondritic meteorites and represent a significant evolutionary step in planet formation. The formation and evolution of chondrules and matrix and, in particular, the mechanics of chondrule formation remain the biggest unsolved challenge in meteoritics. A large number of studies of these major components not only helped to understand these in ever greater detail, but also produced a remarkably large body of data. Studying all available data has become known as ?big data? analyses and promises deep insights – in this case – to chondrule and matrix formation and relationships. Looking at all data may also allow one to better understand the mechanism of chondrule formation or, equally important, what information we might be missing to identify this process. A database of all available chondrule and matrix data further provides an overview and quick visualisation, which will not only help to solve actual problems, but also enable students and future researchers to quickly access and understand all we know about these components. We collected all available data on elemental bulk chondrule and matrix compositions in a database that we call ChondriteDB. The database also contains petrographic and petrologic information on chondrules. Currently, ChondriteDB contains about 2388 chondrule and 1064 matrix data from 70 different publications and 161 different chondrites. Future iterations of ChondriteDB will include isotope data and information on other chondrite components. Data quality is of critical importance. However, as we discuss, quality is not an objective category, but a subjective judgement. Quantifiable data acquisition categories are required that allow selecting the appropriate data from a database in the context of a given research problem. We provide a comprehensive overview on the contents of ChondriteDB. The database is available as an Excel file upon request from the senior author of this paper, or can be accessed through MetBase.     

Analysis of heavy rainfall events in North Rhine–Westphalia with radar and raingauge data

Five heavy rainfall events were investigated with radar and raingauge data. Special attention was paid to quality check and adjustment of radar data. Attenuation effects could be observed on both, C-Band and on X-Band radar. Adjustment of radar data to raingauge values turned out to be difficult in the vicinity of heavy local rain cells. Four adjustment methods were analysed and radar data from different radar stations were compared. As a further result of this project, the spatial extent of the precipitation fields was identified by adjusted radar data and compared to raingauge data. For each rainfall event, radar derived accumulated rainfall images and catchment time series were produced.     

Grain size and depositional environment as predictors of permeability in coastal marine sands

More than half of the surface sediments covering the continental shelves are sandy, which may permit substantial sub-seafloor pore water advection. Knowledge of sediment permeability is required for quantifying advection and associated solute transport, but studies of marine sediments typically report grain size analyses rather than permeability. Here data from 23 studies were examined to determine the range in permeabilities reported for sublittoral marine sands and to assess the utility of permeability–grain size relationships in this setting. In the resulting database, the permeability of small (∼30 cm) undisturbed cores collected from the sea floor all fell between 2 × 10⁻¹² and 4 × 10⁻¹⁰ m², a range where advective transport induced by wave and current action should be pervasive. The range in grain size was very similar for near-shore (<10 m water depth) and continental shelf samples (>10 m water depth), but the permeability of the continental shelf samples was consistently lower for the same median grain size. Empirical permeability–grain size relationships generated a poor fit (r² = 0.35) for the aggregate data, but separate relationships for near-shore and continental shelf samples were significantly better, r² = 0.66 and 0.77, respectively. Permeability–grain size relationships thus may be useful for sublittoral sands, but a larger database needs to be accumulated before reliable fit parameters and variability can be predicted. Thus it is recommended that permeability be routinely determined when characterizing sedimentological properties of marine sand deposits. Concurrent determinations of sediment bulk density and porosity may further improve estimates of permeability.     

Functional composition, but not richness, affected the performance of sessile suspension-feeding assemblages

The efficiency by which communities capture limiting resources may be related to the number of species or functional types competing therein. This is because species use different resources (i.e. complementarity effect) or because species-rich communities include species with extreme functional traits (positive selection effect). We conducted two manipulative studies to separate the effects of functional richness and functional identity on the feeding efficiency (i.e. filtration rate) of suspension-feeding invertebrates growing on vertical surfaces. In addition, one experiment tested whether the density of organisms influences the effect of functional diversity. Monocultures and complete mixtures of functional types were fed with a solution of microalgae of different sizes (6 μm–40 μm). Experiments conducted at two locations, Helgoland and Plymouth, showed that functional identity had far larger effects on filtration rate than richness. Mixtures did not outperform the average monoculture or the best-performing monoculture and this pattern was independent on density. The high efficiency of one of the functional types in consuming most microalgae could have minimised the resource complementarity. The loss or gain of particular species may therefore have a stronger impact on the functioning of epibenthic communities than richness per se.     

Astrophysical Jets of Blazars and Microquasars

Some recent developments in the study of relativistic jets in active galactic nuclei and microquasars are reviewed. While it has been well established for some time that extragalactic jets found in radio galaxies, quasars, and BL Lac objects are the site of ultrarelativistic particle acceleration, the recent identification of the Galactic jet source and microquasar LS~5039 as a source of very-high-energy gamma-ray emission has underlined the striking similarity between the two types of astrophysical jet sources. In this paper, I will present an overview of the dominant radiation and particle acceleration processes and observational tests to distinguish between such processes. The wide-ranging analogies between Galactic and extragalactic jets, but also their distinct differences, in particular those caused by the presence of the companion star in Galactic microquasar systems, will be exposed.     

Assessment of Discharge through a Dike Breach and Simulation of Flood Wave Propagation

This paper presents a simple and fast method to calculate flow through a dike breach. The approach was based on two-dimensional numerical simulations of idealized dike breakages at straight river-sections. As a result, computation of discharge through a breach can be achieved by use of the new developed formula (denoted as dike break formula). Furthermore, a methodology that combines one-dimensional hydrodynamic modelling, the dike break formula and a simple GIS-based method to estimate inundation areas is described. This fast and easy-to-handle tool can be utilized for near real-time forecasting or evacuation decisions. Detailed predictions were made for a number of flood and dike break scenarios at the River Rhine to prove the accuracy of the new method compared with two-dimensional numerical models.