Small-scale clusters of photospheric network bright points and their dependence on the solar cycle phase

The tendency of network bright points (NBPs) to form in their surface distribution non-random, small-scale clusters is studied by a 2-D nearest-neighbours test, based on observational data for the distance between separate NBPs. High-resolution photographs taken from long time series obtained at4308 with the 50-cm refractor of Pic du Midi Observatory are used. Three different epochs of the solar cycle were chosen. The results obtained suggest that the degree of clustering depends on the solar cycle phase. Supposing that the NBPs are good tracers of the kilogauss small-scale magnetic field, we use them to obtain information about the subphotospheric small-scale magnetic field organisation and its dependence on the solar cycle phase.     

Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2–1.9 Ga Waterberg Group, South Africa

Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.     

A comparison of chironomid biostratigraphy from Lake Vuolep Njakajaure with vegetation, lake-level, and climate changes in Abisko National Park, Sweden

Chironomid remains from the sediment of Lake Vuolep Njakajaure reflect limnological conditions resulting from changing climate and vegetation throughout the Holocene, but do not strictly follow accepted climate trends or the vegetation history based on regional pollen and macrofossil analyses. Chironomid community changes appear to be influenced by organic nutrient input from the surrounding catchment vegetation and lake hydrology, both of which are indirectly responding to some combination of climate change, hypolimnetic oxygen concentration, and changes in basin morphology. The chironomid-based quantitative mean July air-temperature reconstruction differs from other regional quantitative records; this discrepancy is likely related to limnological conditions particular to Lake Vuolep Njakajaure. Comparison of a northern Swedish temperature transfer function and one from western Canada reveals differences in the mean July air-temperature optima of several common taxa, suggesting that the existing conservative estimates of Holocene climate change in northern Sweden may be underestimated due to the limited temperature gradient captured by the Swedish training set.     

Water solubility in orthopyroxene

The solubility of water in pure enstatite was measured on samples synthesized at 1,100 °C and pressures to 100 kbar. Enstatite crystals were grown under water-saturated conditions from a stoichiometric mixture of high-purity SiO₂ and Mg(OH)₂. Water contents were calculated from polarized FTIR spectra measured on oriented single crystals. The water solubility in orthoenstatite increases with pressure to 867ᆷ ppm H₂O by weight at 75 kbar. At 100 kbar, in the stability field of high-clinoenstatite, a water solubility of 714ᆷ ppm was observed. The water solubility in enstatite at 1,100 °C can be described by the equation c_H2O=Af_H2O exp(-P(V/RT), where f_H2O is water fugacity, A=0.0204 ppm/bar and (V=12.3 cm³/mol. The infrared spectra of the hydrous enstatite crystals show a sharp, intense band at 3,363 cm^-1 and a broad, weaker band at 3,064 cm^-1. Both bands are strongly polarized parallel c. Most likely, pairs of protons attached to non-bridging oxygen atoms substitute for Mg²⁺. In order to investigate the effect of chemical impurities on water solubility in enstatite, an additional series of experiments was carried out with gels doped with Al, B, or Li as starting material. Whereas, the presence of Li and B had no detectable effect on water solubility, the addition of about 1 wt% Al₂O₃ increased water solubility in enstatite from 199 to 1,100 ppm at 1,100°C and 15 kbar. In the infrared spectra of these aluminous samples, additional bands occur in the range from 3,450 to 3,650 cm^-1. Similar bands are also observed in natural, aluminous orthopyroxenes and are most likely caused by protons coupled with Al according to the substitution of Al³⁺+H⁺ for Si⁴⁺. A series of hydrous annealing experiments on a natural, gem-quality aluminous enstatite from Tanzania yielded water solubilities generally consistent with the results from the synthetic model systems. The results presented here imply that pure enstatite has a similar storage capacity for water as olivine; however, aluminous orthopyroxenes in the mantle may dissolve much larger amounts of water comparable with the entire mass of the present hydrosphere. Moreover, the mechanism of aluminum substitution in orthopyroxenes, i.e., the distribution of Al between tetrahedral and octahedral sites, may be a potential probe of water fugacity.     

Crisis, coincidences and strategic market behaviour: the internationalization of Indonesian clothing brand-owners

Despite the fact that most Indonesian brand-owners continue to emphasize their marketing activities in the domestic market, several brand-owners have started to export clothing under their own label. This has been particularly the result of the economic crisis in the late 1990s, which affected companies serving the domestic market. Companies were trying to compensate for the loss of sales on the domestic market by redirecting their marketing activities to foreign countries. This export strategy has been driven largely by the sole aim to survive. However, in addition to these export activities, some companies have rather sophisticated, long-standing business relations to their distributors in overseas markets. This paper explores these export activities in the context of the global commodity chain framework.     

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996     

Geomorphological and pedological investigations on the glacial history of the Kali Gandaki (Nepal Himalaya)

In semi-arid orographic left tributaries of the Kali Gandaki at the northern and western flank of the Nilgiri Himal, glacio-geomorphological and pedological investigations were carried out on prehistoric moraines. Geomorphological relief analysis was derived from other literature and the own fieldwork of the author. The resulting glacial chronology was used as benchmark to explore the limits of different pedological dating methods regarding the degree of soil development. These methods are based on iron fractionation, total element contents and particle size distribution. In general the different glacial stages are mirrored correctly in the relative graduation of soil development. The ratio of well crystallised pedogenic iron-oxides to the total iron content and the ratio fine clay to total clay are most suitable, because they are almost independent from existing changes in the lithological composition. The total element based weathering indices are less suitable, because they react highly sensitive to the geology dependent shift to higher carbonate content. Most of the grain size based weathering indices are inapplicable because of the typically high textural variability within till deposits.     

Atmospheric boundary-layer structure observed during a haze event due to forest-fire smoke

During a haze event in Baltimore, U.S.A. from July 6 to 8, 2002, smoke from forest fires in the Québec region (Canada), degraded air quality and impacted upon local climate, decreasing solar radiation and air temperature. The smoke particles in and above the atmospheric boundary layer (ABL) served as a tracer and provided a unique opportunity to investigate the ABL structure, especially entrainment. Elastic backscatter lidar measurements taken during the haze event distinctly reveal the downward sweeps (or wisps) of smoke-laden air from the free atmosphere into the ABL. Visualisations of mechanisms such as dry convection, the entrainment process, detrainment, coherent entrainment structures, and mixing inside the ABL, are presented. Thermals overshooting at the ABL top are shown to create disturbances in the form of gravity waves in the free atmosphere aloft, as evidenced by a corresponding ripple structure at the bottom of the smoke layer. Lidar data, aerosol ground-based measurements and supporting meteorological data are used to link free atmosphere, mixed-layer and ground-level aerosols. During the peak period of the haze event (July 7, 2002), the correlation between time series of elastic backscatter lidar data within the mixed layer and the scattering coefficient from a nephelometer at ground level was found to be high (R=0.96 for z =324 m, and R=0.89 for z=504 m). Ground-level aerosol concentration was at a maximum about 2 h after the smoke layer intersected with the growing ABL, confirming that the wisps do not initially reach the ground.     

Diagnostic analysis of future climate scenarios applied to urban flooding in the Chicago metropolitan area

Past heavy precipitation events in the Chicago metropolitan area have caused significant flood-related economic and environmental damages. A key component in flood management policies and actions is determining flood magnitudes for specified return periods. This is a particularly difficult task in areas with a complex and changing climate and land-use, such as the Chicago metropolitan area. The standard design storm methodology based on the NOAA Atlas 14 and ISWS Bulletin 70 has been used in the past to estimate flood hydrographs with variable return periods in this region. In a changing climate, however, these publications may not be accurate. This study presents and illustrates a methodology for diagnostic analysis of future climate scenarios in the framework of urban flooding, and assesses the corresponding uncertainties. First, the design storms are calculated using data downscaled by a regional climate model (RCM) at 30-km spacing for the present and 2050s under the IPCC A1Fi (high) and B1 (low) emissions scenarios. Next, the corresponding flood discharges at six watersheds in suburban Chicago are estimated using a hydrologic event model. The resulting scenarios in flood frequency were first assessed through a set of diagnostic tests for precipitation timing and frequency. The study did not reveal any significant changes in the 2050s in the average timing of heavy storms, but their regularity decreased. The average timing did not exhibit any significant spatial variability throughout the region. The precipitation frequency analysis revealed distinct differences between the northern and southeastern subregions of the Chicago metropolitan area. The quantiles in the northern subregion averaged for 2-year, 5-year, and 10-year return periods exhibited a 20% and 16% increase in daily precipitation for scenarios B1 and A1Fi, respectively. The southeastern subregion, however, exhibited a decrease of 12% for scenario B1 and a minor increase of 3% for scenario A1Fi. The hydrologic effects of changing precipitation on the flood quantiles were illustrated using six small watersheds in the region. The relative increases or decreases in precipitation translated into even larger relative increases or decreases in flood peaks, due to the nonlinear nature of the rainfall-runoff process. Simulations using multiple climate models, for longer periods, finer spatio-temporal resolution, and larger areal coverage could be used to more accurately account for numerous uncertainties in the precipitation and flood projections.