Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Sodian stellerite from Capo Pula,Sardegna

The sodian stellerite (a zeolite) occurs as lustrous white or slightly pink, easily cleavable lamellae, filling cavities and fractures in an acid lava (andesite or rhyolite) in the cliff below S. Efisio Tower, near Capo Pula, Cagliari, Sardegna, Italy. The principal forms present are {010}, {011}, {111}. Single crystal photographs show an orthorhombic symmetry and Ammm (or Ammm) space group. An indexed X-ray diffraction powder pattern is provided. Unit cell dimensions, chemical formula, density, optical properties and thermal behaviour are given.     

Groundwater Resources In Hard Rock; Experiences from The Hvaler Study,Southeastern Norway

Investigations in a newly constructed subsea road tunnel in the Iddefjord granite at Hvaler and test-pumping of boreholes on land indicate that a topographic or geophysical anomaly is no guarantee of a substantially transmissive fracture zone. Many prominent fracture zones appear to have depressed transmissivity due to secondary swelling-clay mineral infillings. No current geophysical technique can adequately distinguish these zones from transmissive ones. Given that siting of boreholes on the basis of geology alone can be unreliable, hydrogeologists should concentrate on quantifying the chances of a successful boring, and optimizing those chances by sensible location, favourable borehole orientation and use of artificial enhancement techniques.     

A Model of Magmatic Crystallization

A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined minerals—magnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions.     

Metadolerite age relationships in the Dalradian of northwest Donegal,Ireland and their orogenic significance

The structural relationships of several intrusive sheets belonging to the extensive metadolerite suite of the Appin (lower) Dalradian rocks of the Creeslough area, northwest Donegal, Ireland have been examined. It is concluded that, relative to the regional chronology of deformation of the enclosing metasediments, sheet emplacement has occurred: pre-D2; syn-D2; between D2 and D3; and syn-D3. The height of activity came in the post-D2, pre-D3 interval and coincided with the peak of regional metamorphism in the area. These relationships in Donegal are compared with those of the pretectonic basic rocks of the southwest Highlands and models are discussed.     

Peculiarities of Dynamic Slip Nucleation in a Thin Granular Layer

Izvestiya, Physics of the Solid Earth - Abstract—Granular media determine the dynamics of many natural systems including faults in the Earth’s crust. The paper addresses the laboratory...     

Saturn's electrostatic discharges: Could lightning be the cause?

It is proposed that Saturn's electrostatic discharges (SED) might be generated in the planet's equatorial atmosphere, perhaps as lightning from a storm system. The 10^h10^m periodicity of the signal envelope duplicates that of Saturn's equatorial jet. The rings shield the atmosphere from solar EUV photons, and thereby substantially reduce the local ionospheric cutoff frequency to allow low-frequency SED to leak out. Many of the unusual properties of SED could be explained in terms of changes in the storm system, the relative spacecraft position in the beaming pattern of the source, local refraction of the signal by the highly disturbed ionosphere, and the influence of the ring particles on the highest frequency component of SED. A comparison of SED with planetary lightning on other planets shows that the two are similar in general character and some time behavior; the power output of SED may be higher than most planetary lightnings but that is unclear because of uncertainties in the measurements and variations in the signal's spectrum. Our simple discussion suggests that lightning could be a viable source for SED and that exotic ring mechanisms are not necessarily required.     

Expansion of the principal functions of Keplerian motion using complex variables

A special system of canonical variables is considered. An algorithm for expanding the principal functions of Keplerian motion in new elements is presented. The advantage of the proposed system is a relatively small number of terms in the classical expansions of the unperturbed two-body problem. A method for expanding the time derivatives of the rectangular coordinates is proposed. Some estimates of the number of terms in the presented expansions have been obtained through numerical experiments.