Petrogenesis of basalt–trachyte lavas from Olmoti Crater, Tanzania

Olmoti Crater is part of the Plio-Pleistocene Ngorongoro Volcanic Highland (NVH) in northern Tanzania to the south of Gregory Rift. The Gregory Rift is part of the eastern branch of the East African Rift System (EARS) that stretches some 4000 km from the Read Sea and Gulf of Aden in the north to the Zambezi River in Mozambique. Here, we (1) characterize the chemistry and mineral compositions of lavas from Olmoti Crater, (2) determine the age and duration of Olmoti volcanic activity through ⁴⁰Ar/³⁹Ar dating of Olmoti Crater wall lavas and (3) determine the genesis of Olmoti lavas and the relationship to other NVH and EARS volcanics and (4) their correlation with volcanics in the Olduvai and Laetoli stratigraphic sequences.Olmoti lavas collected from the lower part of the exposed crater wall section (OLS) range from basalt to trachyandesite whereas the upper part of the section (OUS) is trachytic. Petrography and major and trace element data reflect a very low degree partial melt origin for the Olmoti lavas, presumably of peridotite, followed by extensive fractionation. The ⁸⁷Sr/⁸⁶Sr data overlap whereas Nd and Pb isotope data are distinct between OLS and OUS samples. Interpretation of the isotope data suggests mixing of enriched mantle (EM I) with high-μ-like reservoirs, consistent with the model of Bell and Blenkinsop [Bell, K., Blenkinsop, J., 1987. Nd and Sr isotopic compositions of East African carbonatites: implications for mantle heterogeneity. Geology 5, 99–102] for East African carbonatite lavas. The isotope ratios are within the range of values defined by Oceanic Island Basalt (OIB) globally and moderate normalized Tb/Yb ratios (2.3–1.6) in these lavas suggest melting in the lithospheric mantle consistent with other studies in the region.⁴⁰Ar/³⁹Ar incremental-heating analyses of matrix and anorthoclase separates from Olmoti OLS and OUS lavas indicate that volcanic activity was short in duration, lasting 200 kyr from 2.01 ± 0.03 Ma to 1.80 ± 0.01 Ma. The age of Olmoti activity overlaps with ages reported for Ngorongoro Caldera, implying contemporaneous activity of multiple NVH volcanic centers during part of the eruption interval.Olmoti is considered the source for the bulk of interbedded volcanics and volcaniclastic deposits that comprise much of the upper Bed I section of nearby Olduvai Gorge, and part of the Laetoli sequence, both known for their well preserved fossils and archaeological remains. Age and chemical data reported here are compatible with those derived from tephra and lava interbedded in Bed I at Olduvai Gorge and from the Olpiro Beds at Laetoli.     

Climate drying and associated forest decline in the lowlands of northern Guatemala during the late Holocene

Palynological studies document forest disappearance during the late Holocene in the tropical Maya lowlands of northern Guatemala. The question remains as to whether this vegetation change was driven exclusively by anthropogenic deforestation, as previously suggested, or whether it was partly attributable to climate changes. We report multiple palaeoclimate and palaeoenvironment proxies (pollen, geochemical, sedimentological) from sediment cores collected in Lake Petén Itzá, northern Guatemala. Our data indicate that the earliest phase of late Holocene tropical forest reduction in this area started at ∼ 4500 cal yr BP, simultaneous with the onset of a circum-Caribbean drying trend that lasted for ∼ 1500 yr. This forest decline preceded the appearance of anthropogenically associated Zea mays pollen. We conclude that vegetation changes in Petén during the period from ∼ 4500 to ∼ 3000 cal yr BP were largely a consequence of dry climate conditions. Furthermore, palaeoclimate data from low latitudes in North Africa point to teleconnective linkages of this drying trend on both sides of the Atlantic Ocean.     

Geochronology of the Precambrian crust in the Mozambique belt in NE Mozambique, and implications for Gondwana assembly

Zircon and monazite U–Pb data document the geochronology of the felsic crust in the Mozambique Belt in NE Mozambique. Immediately E of Lake Niassa and NW of the Karoo-aged Maniamba Graben, the Ponta Messuli Complex preserves Paleoproterozoic gneisses with granulite-facies metamorphism dated at 1950 ± 15 Ma, and intruded by granite at 1056 ± 11 Ma. This complex has only weak evidence for a Pan-African metamorphism. Between the Maniamba Graben and the WSW–ENE-trending Lurio (shear) Belt, the Unango and Marrupa Complexes consist mainly of felsic orthogneisses dated between 1062 ± 13 and 946 ± 11 Ma, and interlayered with minor paragneisses. In these complexes, an amphibolite- to granulite-facies metamorphism is dated at 953 ± 8 Ma and a nepheline syenite pluton is dated at 799 ± 8 Ma. Pan-African deformation and high-grade metamorphism are more intense and penetrative southwards, towards the Lurio Belt. Amphibolite-facies metamorphism is dated at 555 ± 11 Ma in the Marrupa Complex and amphibolite- to granulite-facies metamorphism between 569 ± 9 and 527 ± 8 Ma in the Unango Complex. Post-collisional felsic plutonism, dated between 549 ± 13 and 486 ± 27 Ma, is uncommon in the Marrupa Complex but common in the Unango Complex. To the south of the Lurio Belt, the Nampula Complex consists of felsic orthogneisses which gave ages ranging from 1123 ± 9 to 1042 ± 9 Ma, interlayered with paragneisses. The Nampula Complex underwent amphibolite-facies metamorphism in the period between 543 ± 23 to 493 ± 8 Ma, and was intruded by voluminous post-collisional granitoid plutons between 511 ± 12 and 508 ± 3 Ma. In a larger context, the Ponta Messuli Complex is regarded as part of the Palaeoproterozoic, Usagaran, Congo-Tanzania Craton foreland of the Pan-African orogen. The Unango, Marrupa and Nampula Complexes were probably formed in an active margin setting during the Mesoproterozoic. The Unango and Marrupa Complexes were assembled on the margin of the Congo-Tanzania Craton during the Irumidian orogeny (ca. 1020–950 Ma), together with terranes in the Southern Irumide Belt. The distinctly older Nampula Complex was more probably linked to the Maud Belt of Antarctica, and peripheral to the Kalahari Craton during the Neoproterozoic. During the Pan-African orogeny, the Marrupa Complex was overlain by NW-directed nappes of the Cabo Delgado Nappe Complex before peak metamorphism at ca. 555 Ma. The nappes include evidence for early Pan-African orogenic events older than 610 Ma, typical for the Eastern Granulites in Tanzania. Crustal thickening at 555 ± 11 Ma is coeval with high-pressure granulite-facies metamorphism along the Lurio Belt at 557 ± 16 Ma. Crustal thickening in NE Mozambique is part of the main Pan-African, Kuunga, orogeny peaking between 570 and 530 Ma, during which the Congo-Tanzania, Kalahari, East Antarctica and India Cratons welded to form Gondwana. Voluminous post-collisional magmatism and metamorphism younger than 530 Ma in the Lurio Belt and the Nampula Complex are taken as evidence of gravitational collapse of the extensive orogenic domain south of the Lurio Belt after ca. 530 Ma. The Lurio Belt may represent a Pan-African suture zone between the Kalahari and Congo-Tanzania Craton.     

Asbestos in lake and reservoir waters of Staten Island,New York: Source,concentration, mineralogy,and size distribution

There is strong evidence indicating that the six commonly recognized varieties of asbestos are cancer-producing agents Epidemiological and experimental data indicate that, although response to inhalation exposure is most marked, exposure by ingestion probably also entails a risk of excess tumor incidence. The toxicity of mineral fibers can be related to fiber dimensions, mineralogy, chemistry, and surface-active properties. In the Silver Lake Reservoir in Staten Island, New York, where chrysotile from serpentinite bedrock exposures is a potential source of contamination, chrysotile asbestos levels of 15 to 86 million fibers per liter (MFL) were measured, with an average of 53 MFL Much lower levels (average 0 3 MFL) were observed in small lakes and ponds with clayey bottoms on the Staten Island Serpentinite.     

Solute and geothermal flux monitoring using electrical conductivity in the Madison,Firehole, and Gibbon Rivers,Yellowstone National Park

The thermal output from the Yellowstone magma chamber can be estimated from the Cl flux in the major rivers in Yellowstone National Park; and by utilizing continuous discharge and electrical conductivity measurements the Cl flux can be calculated. The relationship between electrical conductivity and concentrations of Cl and other geothermal solutes (Na, SO₄, F, HCO₃, SiO₂, K, Li, B, and As) was quantified at monitoring sites along the Madison, Gibbon, and Firehole Rivers, which receive discharge from some of the largest and most active geothermal areas in Yellowstone. Except for some trace elements, most solutes behave conservatively and the ratios between geothermal solute concentrations are constant in the Madison, Gibbon, and Firehole Rivers. Hence, dissolved concentrations of Cl, Na, SO₄, F, HCO₃, SiO₂, K, Li, Ca, B and As correlate well with conductivity (R² > 0.9 for most solutes) and most exhibit linear trends. The 2011 flux for Cl, SO₄, F and HCO₃ determined using automated conductivity sensors and discharge data from nearby USGS gaging stations is in good agreement with those of previous years (1983–1994 and 1997–2008) at each of the monitoring sites. Continuous conductivity monitoring provides a cost- and labor-effective alternative to existing protocols whereby flux is estimated through manual collection of numerous water samples and subsequent chemical analysis. Electrical conductivity data also yield insights into a variety of topics of research interest at Yellowstone and elsewhere: (1) Geyser eruptions are easily identified and the solute flux quantified with conductivity data. (2) Short-term heavy rain events can produce conductivity anomalies due to dissolution of efflorescent salts that are temporarily trapped in and around geyser basins during low-flow periods. During a major rain event in October 2010, 180,000 kg of additional solute was measured in the Madison River. (3) The output of thermal water from the Gibbon River appears to have increased by about 0.2%/a in recent years, while the output of thermal water for the Firehole River shows a decrease of about 10% from 1983 to 2011. Confirmation of these trends will require continuing Cl flux monitoring over the coming decades.     

In the footsteps of Alexander the Great: searching for the origins of ancient zooplankton on the wild steppe of Central Asia

Rising above the modern town of Nurata, in Navoiy Province, eastern Uzbekistan is the ancient fortress of Alexander the Great, built as part of Alexander's campaigns to subjugate the Persian‐speaking Sogdian peoples that lived in this province of the Persian Empire in the 4th Century bc . Alexander passed this way in 327 bc , marching his ancient army through this beautiful but desolate landscape, and conquering all before him. His fortress was built in a strategic place at the boundary between fertile agricultural lands and a dry and uncompromising vastness of steppe that lies to the east. From Nurata, about one hour drive by car along a road that cuts eastwards across the desert, is the sleepy town of Jo'sh. In the mountains beyond Jo'sh sits the hamlet of Kanda, a few mud‐brick houses nestling at the head of a small valley where a spring emerges miraculously from a bone‐dry landscape. Hereabouts are telltale signs of ancient marine deposits yielding graptolites from rocks of the Silurian system. And in these rocks are the fossils of tiny arthropods that mark a fundamental shift in the marine arthropod zooplankton 425 million years ago. It is these fossils that we have chased halfway across the world to the steppe of Central Asia.     

Mesoscale Structure of Trade Wind Convection over Puerto Rico: Composite Observations and Numerical Simulation

We examine the mesoscale structure of the atmospheric boundary layer (ABL), low-level circulation, and trade wind convection over the sub-tropical island of Puerto Rico in mid-summer. Shallow afternoon thunderstorms are frequently seen over the western plains of the island. Observational data include automatic weather station measurements, radiosonde profiles, infrared satellite images, and mesoscale reanalysis data with a focus on the summer of 2006. Satellite microwave radar data (TRMM and CloudSat) indicate that island clouds typically extend just above the −20°C level during afternoon hours with reflectivity values reaching 50 dBz. A singular value decomposition of 3-hourly high resolution satellite rainfall maps reveals an island mode. From this a composite is constructed for a group of ten cases. With a Froude number ≈1 the trade winds pass over the mountains and standing vortices and gravity waves are trapped in the meandering wake. The Weather and Research Forecasting (WRF) model at 1-km resolution with 51 vertical layers is used to simulate the short-lived thunderstorms for two cases: 27 June and 20 July 2006. The model correctly locates the convective cells that develop between 1400 and 1700 LST. The shallow afternoon thunderstorms are triggered by surface heat fluxes, confluent sea breezes and a mountain wake. Recommendations for enhanced observations are given.     

Solar activity levels in 2100

Mark A Clilverd, Ellen Clarke, Henry Rishbeth, Toby D G Clark and Thomas Ulich look forward to a little less solar activity in 2100, using direct and proxy records of past solar and geomagnetic activity.     

A Method To Detect Viable Helicobacter pylori Bacteria in Groundwater

The inability to detect the presence of viable Helicobacter pylori bacteria in environmental waters has hindered the public health community in assessing the role water may play in the transmission of this pathogen. This work describes a cultural enrichment method coupled with an H. pylori‐specific PCR to identify these bacteria in water. While far from perfected at the present time, this represents an exciting new approach to studying the significance of water as a transmission mechanism for H. pylori. Evidence is presented that indicates culturable H. pylori bacteria were found using this enrichment/PCR method in a local groundwater source.     

Accumulation of organochlorines and brominated flame retardants in estuarine and marine food chains: field measurements and model calculations

Food chain accumulation of organochlorines and brominated flame retardants in estuarine and marine environments is compared to model estimations and fresh water field data. The food chain consists of herbivores, detritivores and primary and secondary carnivores i.e. fish, fish-eating birds and marine mammals. Accumulation of polychlorinated biphenyls is predicted well by OMEGA for herbi-detritivores and primary and secondary carnivorous fish. Ratios are similar to those found for fresh water species. Accumulation ratios for fish-eating birds and mammals are overestimated by the model, which is attributed partly to biotransformation of meta-para unsubstituted congeners. Additionally, birds may feed in other less polluted areas. For brominated diphenylethers (BDE) accumulation patterns are highly species and congener specific. Accumulation depends on both K(ow) and metabolization capacities. BDE47 is the predominant congener in lower trophic levels. For marine birds and mammals accumulation ratios of BDE99 and 100 are similar to or higher than ratios of persistent PCBs.