Microbial mercury cycling in sediments of the San Francisco Bay-Delta

Microbial mercury (Hg) methylation and methylmercury (MeHg) degradation processes were examined using radiolabled model Hg compounds in San Francisco Bay-Delta surface sediments during three seasonal periods: late winter, spring, and fall. Strong seasonal and spatial differences were evident for both processes. MeHg production rates were positively correlated with microbial sulfate reduction rates during late winter only. MeHg production potential was also greatest during this period and decreased during spring and fall. This temporal trend was related both to an increase in gross MeHg degradation, driven by increasing temperature, and to a build-up in pore water sulfide and solid phase reduced sulfur driven by increased sulfate reduction during the warmer seasons. MeHg production decreased sharply with depth at two of three sites, both of which exhibited a corresponding increase in reduced sulfur compounds with depth. One site that was comparatively oxidized and alkaline exhibited little propensity for net MeHg production. These results support the hypothesis that net MeHg production is greatest when and where gross MeHg degradation rates are low and dissolved and solid phase reduced sulfur concentrations are low.     

Combining Sample and Census Data in Small Area Estimates: Iterative Proportional Fitting with Standard Software*

The combination of detailed sample data with less detailed but fully enumerated marginal subtotals is the focus of a wide range of research. In this article we advocate careful modeling of sample data, followed by Iterative Proportional Fitting (IPF). The modeling aims to estimate accurately the interaction or odds ratios of complex tables, which is information not contained in the marginal subtotals. IPF ensures consistency with the subtotals. We advance this work in three practical ways. First, we show that detailed small‐area estimates of both counts and proportional distributions usually gain accuracy by combining data for larger areas containing the small areas, and we illustrate the multilevel framework to achieve these estimates. Second, we find that a general classification or socioeconomic typology of the small areas is even more associated with the within‐area interactions than is membership of the larger area. Third, we show how the Statistical Package for the Social Sciences (SPSS) can be used for IPF in any number of dimensions and with any structure of constraining marginal subtotals. Throughout, we use an example taken from the 1991 U.K. Census. These data allow us to evaluate various methods combining 100 percent tabulations and the Samples of Anonymised Records.     

Morphologic and stratigraphic evolution of muddy ebb-tidal deltas along a subsiding coast: Barataria Bay, Mississippi River delta

The Barataria barrier coast formed between two major distributaries of the Mississippi River delta: the Plaquemines deltaic headland to the east and the Lafourche deltaic headland to the west. Rapid relative sea‐level rise (1·03 cm year^?1) and other erosional processes within Barataria Bay have led to substantial increases in the area of open water (> 775 km² since 1956) and the attendant bay tidal prism. Historically, the increase in tidal discharge at inlets has produced larger channel cross‐sections and prograding ebb‐tidal deltas. For example, the ebb delta at Barataria Pass has built seaward > 2·2 km since the 1880s. Shoreline erosion and an increasing bay tidal prism also facilitated the formation of new inlets. Four major lithofacies characterize the Barataria coast ebb‐tidal deltas and associated sedimentary environments. These include a proximal delta facies composed of massive to laminated, fine grey‐brown to pale yellow sand and a distal delta facies consisting of thinly laminated, grey to pale yellow sand and silty sand with mud layers. The higher energy proximal delta deposits contain a greater percentage of sand (75–100%) compared with the distal delta sediments (60–80%). Associated sedimentary units include a nearshore facies consisting of horizontally laminated, fine to very fine grey sand with mud layers and an offshore facies that is composed of grey to dark grey, laminated sandy silt to silty clay. All facies coarsen upwards except the offshore facies, which fines upwards. An evolutionary model is presented for the stratigraphic development of the ebb‐tidal deltas in a regime of increasing tidal energy resulting from coastal land loss and tidal prism growth. Ebb‐tidal delta facies prograde over nearshore sediments, which interfinger with offshore facies. The seaward decrease in tidal current velocity of the ebb discharge produces a gradational contact between proximal and distal tidal delta facies. As the tidal discharge increases and the inlet grows in dimensions, the proximal and distal tidal delta facies prograde seawards. Owing to the relatively low gradient of the inner continental shelf, the ebb‐tidal delta lithosome is presently no more than 5 m thick and is generally only 2–3 m in thickness. The ebb delta sediment is sourced from deepening of the inlet and the associated channels and from the longshore sediment transport system. The final stage in the model envisages erosion and segmentation of the barrier chain, leading to a decrease in tidal discharge through the former major inlets. This process ultimately results in fine‐grained sedimentation seaward of the inlets and the encasement of the ebb‐tidal delta lithosome in mud. The ebb‐tidal deltas along the Barataria coast are distinguished from most other ebb deltas along sand‐rich coasts by their muddy content and lack of large‐scale stratification produced by channel cut‐and‐fills and bar migration.     

Walrus (Odobenus rosmarus) predation on adult thick-billed murres (Uria lomvia) at Coats Island, Nunavut, Canada

Although the diet of walrus ( Odobenus rosmarus ) is considered varied, records of walrus consuming marine birds are rare in the published literature. In 2001 and 2002 we observed walrus foraging on adult thick-billed murres ( Uria lomvia ) at Coats Island in Nunavut, Canada. Approximately 46% of the attacks on murres were successful, and as many as 67 murres may have been killed in one day in August 2002. All soft parts of the murres were sucked out, with carcasses of only bones, feathers and skin left floating on the water. The extent to which predation on seabirds by walrus occurs across the eastern Arctic is unknown, but it could represent an important source of mortality for murres at some breeding colonies.     

A distribution‐free statistical method for the spatial characterization of dune granulometry: an example from the Strzelecki Desert,South Australia

Distribution‐free statistical methods of comparative data analysis have identi?ed subtle granulometric differences attributed to the evolution of barchan form at Gurra‐Gurra waterhole. Geomorphic locations on the barchan dunes display statistically signi?cant grain‐size differences that assist in the interpretation of aeolian processes. In summer, very ?ne sands mantle the dunescape and are the fraction that most affects the parameters of sorting and skewness. The sur?cial sedimentological character is one of subtle contrasts between the processes of grain winnowing and intergranular protection. The second and third moment measures are parameters that best demonstrate the spatial granulometric differences. Dune‐forming processes at Gurra‐Gurra have produced dune sands that have a very narrow range of grain size, which, in turn, re?ects textural and mineralogical maturity, and hence an extensive transport history. The statistical techniques employed in this study can also be used for the comparison of temporal (seasonal) sedimentological change, and for the granulometric analysis and association of process for dunes of different morpho‐types. Copyright © 2004 John Wiley & Sons, Ltd.     

A Hybrid Multi-Agent/Spatial Interaction Model System for Petrol Price Setting

This paper examines the use of multi‐agent simulations (MAS) to model the petrol market. The development of a purely agent based model for petrol prices is presented. Failings within this model are discussed and an alternative strategy for controlling the price of each petrol station based on population of customers is considered. Individual level modelling of customers is too computationally intensive; therefore a spatial interaction model was used to estimate the sales and linked to the agent system to create a hybrid model. To evaluate how effective this hybrid model was, a comparison was made with an existing data set of real petrol prices collected over a two month period. This was achieved both statistically and visually with the use of a Geographical Information System (GIS). Experimentation revealed that the hybrid model outperformed the agent model. Investigation into the behaviour and sensitivity of the system (for example, how prices diffuse spatially) was undertaken by means of idealised simulations.     

Contrasting flow pathways within tropical forest slopes of Ultisol soils

There are very few experimental studies identifying hydrological pathways within rain forest slopes. Such knowledge is, however, necessary to understand why forest disturbance affects rainfall–riverflow response and nutrient migration. This study examines flow pathways within lowland rain forest slopes comprising Udults of the Ultisol soil order. Experimentation was conducted on four SE Asian hillslope units (each 5 × 5 m in plan) in the Bukit Timah catchment (Singapore Island), and in the W8S5 catchment (Sabah, Borneo Island). The flow pathways were identified by artificial tracer experiments. We evaluated how well hydrometric calculations based on tensiometry and permeametry measurements predicted the tracer patterns. The tracer work indicated much faster subsurface flows at Bukit Timah than W8S5 for the storms studied. Some explanation of the greater subsurface waterflows at Bukit Timah in comparison to W8S5 is afforded by the less steep moisture release curves which maintain hydraulic conductivity as the soil dries. Vertical flow of the tracer through the upper 1 m of soil predominated (>90 per cent of percolation) in the Bukit Timah slopes. In some contrast, a major component (approximately 60 per cent) of the tracer percolation was directed laterally within the W8S5 slopes. The flow vectors calculated using the hydrometric methods did, however, grossly under‐estimate the degree of lateral deflection of waterflow generated at W8S5 and to a lesser extent over‐estimated it at Bukit Timah. In part, these errors may relate to the inability of traditional hydrometric techniques to fully characterize the effect of the large and small ‘natural soil pipes’ present within both catchments. In conclusion, the study indicates that marked variations in flow vectors exist within the Udult great group of SE Asian soils and hydrometric calculations may be poor predictors of these dominant pathways. Copyright © 2005 John Wiley & Sons, Ltd.