Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

---

Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

---

---

With 5 Figures

---

Deceased     

Directions and possibilities of mathematical geology

This paper considers the present state of mathematical geology. Three directions are recognized: applied, theoretical, and mathematical. Applied mathematical geology includes formal use of mathematics to solve problems and computer processing of data. Success is achieved by a correspondence of mathematical methods used to the nature of geological data. This correspondence can be demonstrated by purely mathematical means. Theoretical mathematical geology uses mathematics as a language of geology; however, a number of methodological problems must be solved: formalization of initial geological concepts and creation of a strict conceptual basis, substantiation of initial principles of mathematical simulation, creation of theoretical geological models, problems of elementary and coincidence in geology, and methodological substantiations of possibilities of any mathematical model to approximate geological models. The essense and significance of these problems are considered. The main task of mathematical geology is to prove its correspondence to the nature of the geological objects studied, geological data obtained, and geological problems solvable. Finally, the main problems of mathematical geology are not so much mathematical as geological and methodological.     

The Stress–Strain State of Recent Structures in the Northeastern Sector of the Russian Arctic Region

Doklady Earth Sciences - Complex research to determine the stress–strain state of the Earth’s crust and the types of seismotectonic destruction for the northeastern sector of the...     

On the reoccurrence of site specific response

The period and amplitude variations of local peaks in the Fourier amplitude spectra of free-field strong ground motion recorded at five stations in San Fernando Valley of metropolitan Los Angeles, California, are described, searching for peaks that reoccur during different earthquakes. The data suggest that some local peaks reoccur (about 50% of the time), during shaking by small local earthquakes (peak ground velocities, v_max<10–20 cm/s). During large strong motion amplitudes (v_max>20 cm/s), these peaks are shifted towards longer periods (by nonlinear response of soils) or disappear. The data also suggest that densification and settlement of soil, minutes and hours following the strong shaking may contribute towards fluctuations in the effective stiffness of the shallow surface layers.     

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.     

Benthic foraminifers in upper Quaternary sediments of the southern Bering Sea: Distribution and paleoceanographic interpretations

Composition and distribution of benthic foraminifers, being coupled with isotopic-geochemical data on Upper Pleistocene and Holocene sediments from the southern Bering Sea (Core GC-11; 53°31′ N, 178°51′E, water depth 3060 m), demonstrate variations in bottom water properties during the last 54 kyr. Their abundance increased to some extent during short periods corresponding to warm Dansgaard-Oeshger interstadials 14, 12, 8, and 2 of marine isotopic stages (MIS) 3 and 2. The first and second deglaciation phases separated by the Younger Dryas cooling episode are marked by significant abundance peaks of benthic foraminifers (an order magnitude higher than in the glacial period), although their share in community of benthic and planktonic foraminifers taken together decreases. Species typical of stable high-productivity areas gain the dominant position. A significant proportion of agglutinated species in the Holocene sediments is indicative of Ca ions deficiency that accelerates dissolution of carbonate tests up to their disappearance approximately 2.5–3 ka ago.     

Organic matter of the North Atlantic

The areas that we studied in the North Atlantic (53 and 60°N) and in the Labrador Sea in the summer were characterized by a wide variability of the concentrations of dissolved and particulate organic matter and its elemental composition both in the surface and in the deep waters. The concentrations of dissolved and particulate C_org varied within 69–360 μM and 0.7–25.6 μM, respectively; the N_org and P_org contents varied within 1.4–22.2 μM and 0.02–0.86 μM, respectively. The maximal concentrations were registered in the photic layer and in the zones of mixing between the waters of different genesis. The particulate matter contribution to the total organic matter (OM) content varied from 0.5 to 15.4%. The waters of the photic layer contained more particulate C_org than those of the near-bottom layer. The values of the C/N molar ratios from the surface to the bottom over the entire aquatic area surveyed varied 5-to 6-fold; at that, the values of the C/P molar ratios varied more than tenfold. In the most productive waters, the values of the C/N ratios were close to the Redfield ratios (6–10). The values of the C/P molar ratios varied from 160 in the photic layer to 4831 in the deep waters. The pronounced non-uniformity in the spatial distribution of the OM and its elemental composition is caused not only by the penetration of the waters of different origins but also by the changes in the microplankton metabolism under mixing of these waters.     

Spectral analysis of the “Koshava” wind

Summary “Koshava” is a gusty wind of changeable intensity, blowing from a south-easterly direction, over Serbia, Romania and Bulgaria. It is caused by the interaction between the synoptic circulation and the orography of the Carpathian and the Balkan mountains. This paper analyzes wind data measured at the Belgrade-Observatory during the longest period of consecutive days of “Koshava” which occurred from 14 January to 13 February 1972. Mean hourly wind speed data has been examined using spectral analysis. The power spectra are calculated using autocorrelation spectral analysis, the multi-taper method and wavelet transform. The maximum of which is about 122 h (5 days) corresponds to the time span of synoptic processes.     

Response of detrital zircon and monazite,and their U–Pb isotopic systems,to regional metamorphism and host‐rock partial melting,Cooma Complex,southeastern Australia

Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ～12°C/10⁶y from ～730 to ～170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton.