Heavy metals in mangrove sediments of the central Arabian Gulf shoreline,Saudi Arabia

To assess heavy metals in mangrove swamps of Sehat and Tarut coastal areas along the Arabian Gulf, 18 sediment samples were collected for Al, V, Cr, Mn, Cu, Zn, Cd, Pb, Hg, Sr, As, Fe, Co, and Ni analysis. The results indicated that the distribution of some metals was largely controlled by anthropogenic inputs, while others were of terrigenous origin and most strongly associated with distribution of aluminum and total organic carbon in sediments. Mangrove sediments were extremely severe enriched with Sr (EF?=?67.59) and very severe enriched with V, Hg, Cd, Cu, As (EF?=?44.28, 37.45, 35.77, 25.97, and 11.53, respectively). Average values of Sr, V, Hg, Cd, Cu, Ni, As, and Cr were mostly higher than the ones recorded from the Mediterranean Sea, the Red Sea, the Gulf of Aqaba, the Caspian Sea, the Arabian and Oman gulfs, coast of Tanzania, sediment quality guidelines, and the background shale and the earth crust. Landfilling due to coastal infrastructure development around mangrove forests, oil spills and petrochemical and desalination effluents from Al-Jubail industrial city to the north were the anthropogenic activities that further enhanced heavy metals in the studied mangrove sediments.     

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.     

Heavy metal exposure from co-processing of hazardous wastes for cement production and associated human risk assessment

This study was carried out to determine the concentration of heavy metals (Cd, Ni, Pb, Cr, Ni and Zn) in ordinary Portland cement (OPC) produced from the co-processing with hazardous waste in comparison with OPC produced using natural raw materials. The results showed that the concentration of heavy metals in cement produced from natural raw material was in the order of Zn > Pb > Cr > Ni > Cu > Cd. Zn and Cd were the highest and the lowest concentrations, respectively, in cements produced from the co-processing activity. The difference between heavy metals concentrations in OPC produced with and without co-processing was found to be statistically significant. The concentration of heavy metals in the cement produced is generally factory dependent. The human risk assessment associated with the heavy metals for non-carcinogenic and carcinogenic risks has been evaluated. The calculated hazard index (HI) and total lifetime cancer risks (LCR) were lower than the acceptable threshold reference values, HI < 1 and LCR < 1 × 10^?4, respectively. Thus, it is anticipated that there is no potential of non-carcinogenic and carcinogenic risks for both adult and children. However, the findings indicated that there is a need for regulatory monitoring. The exposure pathway for both non-carcinogenic and carcinogenic risks are both in the order of ingestion > dermal > inhalation.     

Wetland Loss Patterns and Inundation-Productivity Relationships Prognosticate Widespread Salt Marsh Loss for Southern New England

Tidal salt marsh is a key defense against, yet is especially vulnerable to, the effects of accelerated sea level rise. To determine whether salt marshes in southern New England will be stable given increasing inundation over the coming decades, we examined current loss patterns, inundation-productivity feedbacks, and sustaining processes. A multi-decadal analysis of salt marsh aerial extent using historic imagery and maps revealed that salt marsh vegetation loss is both widespread and accelerating, with vegetation loss rates over the past four decades summing to 17.3 %. Landward retreat of the marsh edge, widening and headward expansion of tidal channel networks, loss of marsh islands, and the development and enlargement of interior depressions found on the marsh platform contributed to vegetation loss. Inundation due to sea level rise is strongly suggested as a primary driver: vegetation loss rates were significantly negatively correlated with marsh elevation (r ²?=?0.96; p?=?0.0038), with marshes situated below mean high water (MHW) experiencing greater declines than marshes sitting well above MHW. Growth experiments with Spartina alterniflora, the Atlantic salt marsh ecosystem dominant, across a range of elevations and inundation regimes further established that greater inundation decreases belowground biomass production of S. alterniflora and, thus, negatively impacts organic matter accumulation. These results suggest that southern New England salt marshes are already experiencing deterioration and fragmentation in response to sea level rise and may not be stable as tidal flooding increases in the future.     

Mapping landslide susceptibility with frequency ratio,statistical index,and weights of evidence models: a case study in northern Iran

The main objective of this study is to investigate potential application of frequency ratio (FR), weights of evidence (WoE), and statistical index (SI) models for landslide susceptibility mapping in a part of Mazandaran Province, Iran. First, a landslide inventory map was constructed from various sources. The landslide inventory map was then randomly divided in a ratio of 70/30 for training and validation of the models, respectively. Second, 13 landslide conditioning factors including slope degree, slope aspect, altitude, plan curvature, stream power index, topographic wetness index, sediment transport index, topographic roughness index, lithology, distance from streams, faults, roads, and land use type were prepared, and the relationships between these factors and the landslide inventory map were extracted by using the mentioned models. Subsequently, the multi-class weighted factors were used to generate landslide susceptibility maps. Finally, the susceptibility maps were verified and compared using several methods including receiver operating characteristic curve with the areas under the curve (AUC), landslide density, and spatially agreed area analyses. The success rate curve showed that the AUC for FR, WoE, and SI models was 81.51, 79.43, and 81.27, respectively. The prediction rate curve demonstrated that the AUC achieved by the three models was 80.44, 77.94, and 79.55, respectively. Although the sensitivity analysis using the FR model revealed that the modeling process was sensitive to input factors, the accuracy results suggest that the three models used in this study can be effective approaches for landslide susceptibility mapping in Mazandaran Province, and the resultant susceptibility maps are trustworthy for hazard mitigation strategies.     

Assessment of H<Subscript>2</Subscript>S emission hazards into tunnels: the Nosoud tunnel case study from Iran

The presence of a gassy ground condition is an important problem in tunneling. In this study, the effects of groundwater H₂S and CH₄ emissions are investigated and characterized together with the factors that created these conditions in Nosoud tunnel in Iran. Through the geological investigations, the presence of these gasses was not detected prior to the construction of the tunnel. Groundwater sampling indicated that about 1 L of H₂S is released per 100 L of the water inflow into the Nosoud tunnel under normal conditions. However, the volume of the released gas was varying with the changes in the groundwater discharge rate. Thus, estimation of groundwater inflow into the tunnel is necessary for predicting the volume of gas emission. Based on the experience of the Nosoud tunnel excavations, there are several geological and hydrogeological factors that must be considered as the indicators of gas emissions during tunneling. Considering the importance of ground water gas emission into the tunnels located in gassy conditions, the present work was conducted to predict the H₂S seepage before the excavation using geological and hydrogeological indicators.     

A new Jurassic cow shark (Chondrichthyes,Hexanchiformes) with comments on Jurassic hexanchiform systematics

A new taxon, ?Crassodontidanus gen. nov. of Hexanchiformes (cow sharks) from the Jurassic of Germany is described. It is characterized by peculiar teeth combining apomorphic (serrated mesial cutting edge of the main cusp) and plesiomorphic features (deep root with convex mesial and distal margins in labial and lingual views; protruding lingual root bulge). This character combination readily distinguishes members of the new taxon from all other known extant (Heptranchias, Hexanchus, Notorynchus) and extinct (?Gladioserratus, ?Notidanodon, ?Notidanoides, ?Pachyhexanchus, ?Paraheptranchias, ?Weltonia) hexanchiforms. Currently, two species, ?C. serratus (type species; Late Jurassic, Late Kimmeridgian of Nusplingen, South Germany) and ?C. wiedenrothi (Early Jurassic, Early Pliensbachian of Gretenberg (Hanover), North Germany) are assigned to this taxon. ?Crassodontidanus gen. nov. is member of ?Crassonotidae fam. nov. and sister to ?Notidanoides Maisey, 1986 and ?Pachyhexanchus Cappetta, 1990. We consider ?Notidanus amalthei Oppel, 1854 from the Pliensbachian of South Germany, ?Notidanus insignis Seguenza, 1887 from the Oxfordian of Sicily (Italy) and ?Notidanus wagneri Agassiz, 1843 from the Early Tithonian of Solnhofen (South Germany) nomina dubia and nomina nuda, respectively. The family ?Crassonotidae comprises plesiomorphic hexanchiforms ranging from the Sinemurian (Early Jurassic) to the Hauterivian (Early Cretaceous).     

Trace metal assessment in soils in a small city and its rural surroundings,Pensacola, FL,USA

This study assesses the origin and pollution of trace metals in surface soils in a region with contrasting land uses (urban vs. rural). Principal component analysis (PCA) reveals that Cr and Ni are predominantly of geogenic origin. These two trace metals are also the only ones with statistically significant correlations with soil particle size and organic matter content. Copper, Pb and Zn, and possibly Hg, are of anthropogenic origin, but their concentrations rarely reach levels described as strongly polluted by pollution indexes. The concentrations of these anthropogenic trace metals are statistically not different in urban and rural areas, except for Pb that is higher in the urban area. This general lack of a difference between the two land uses indicates that the influence of this small urban area on trace metal concentrations in soils is minor. Lead and Zn have the most, but still a modest number, of strongly polluted sites, mainly in an industrial part of the city. GIS analysis shows that, based on the pollution load index (PLI), overall concentrations of trace metals also reach their highest levels in that industrial area. These observations indicate that the influence of industry on trace metal pollution in soil exceeds that of other urban activities in the region. Local background concentrations were found to be very different from general crustal background concentrations. This demonstrates the importance of the careful selection of a background type in studies like this.     

Strip Transect Sampling to Estimate Object Abundance in Homogeneous and Non-homogeneous Poisson Fields: a Simulation Study of the Effects of Changing Transect Width and Number

This paper investigates the use of strip transect sampling to estimate object abundance when the underlying spatial distribution is assumed to be Poisson. A design-based rather than model-based approach to estimation is investigated through computer simulation, with both homogeneous and non-homogeneous fields representing individual realizations of spatial point processes being considered. Of particular interest are the effects of changing the number of transects and transect width (or alternatively, coverage percent or fraction) on the quality of the estimate. A specific application to the characterization of unexploded ordnance (UXO) in the subsurface at former military firing ranges is discussed. The results may be extended to the investigation of outcrop characteristics as well as subsurface geological features.     

Ra’s Abdah of the north Eastern Desert of Egypt: the role of granitic dykes in the formation of radioactive mineralization,evidenced by zircon morphology and chemistry

Syenogranitic dykes in the north of Egypt’s Eastern Desert are of geological and economic interest because of the presence of magmatic and supergene enrichment of radioactive mineralization. Zircon crystal morphology within the syenogranitic dykes allows precise definition of sub-alkaline series granites and crystallized at mean temperature of about 637 °C. The growth pattern of the zircons suggest magmatic and hydrothermal origins of radioactive mineralization. Hydrothermal processes are responsible for the formation of significant zircon overgrowth; high U-zircon margins might have occurred contemporaneously with the emplacement of syenogranitic dykes which show anomalous uranium (eU) and thorium (eTh) contents of up to 1386 and 7330 ppm, respectively. Zircon chemistry revealed a relative increase of Hf consistent with decreasing Zr content, suggesting the replacement of Zr by Hf during hydrothermal activity. Visible uranium mineralization is present and recognized by the presence of uranophane and autunite.