Changes in Nutrient Biogeochemistry in Response to the Regression of Zostera noltii Meadows in the Arcachon Bay (France)

From 1989 to 2007, a severe decline in Zostera noltii meadows was reported in the Arcachon Bay, with an accelerated regression after 2005. We investigated the inter-annual variability of the biogeochemistry of the sediment in an area affected by seagrass decline. In late summer and in winter of the years 2006, 2010, and 2011, sediment cores were collected at low tide on vegetated and adjacent non-vegetated sediments located in the eastern part of the Arcachon Bay. The geochemical analyses of sediment solid-phase organic carbon, reactive P and Fe, and the pore water concentrations of Fe²⁺, DIP, and NH₄ ⁺ are presented. The changes in the chemistry of sediment and pore water between 2006 and 2010 are interpreted as a consequence of the decrease in the Z. noltii biomass between 2006 and 2010. The absence of significant seasonal variations in biomass throughout the growth period (March–September) in 2011 is most likely related to the regression of Z. noltii meadow that strongly affects the study area. In contrast to the healthy meadow in 2006, the declining meadow favored the dissolution of sedimentary particulate phosphorus in winter. In late summer, the low biomass of seagrass resulted in a net release of ammonium in the pore water of the upper 20 cm of sediment. This study clearly shows that seagrass decay may enhance nutrient release in sediments, resulting in a significant supply of phosphorus to the water column of a magnitude comparable to annual inputs to the lagoon from the rivers and the tidal pump.     

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.     

Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents: a hypothesis

Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150°C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other – brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor.     

Late Pleistocene–Holocene environmental and climatic history of a freshwater paramo ecosystem in the northern Andes

This study presents the first multi-proxy palaeoenvironmental and palaeoclimatic history for northern South America based on the palaeolimnological reconstruction of a pond located in a dry paramo at 3570 masl. During the Last Glacial Maximum (LGM), the study area was under glacial conditions, then during global events Heinrich Stadial 1 (HS1), Bølling–Allerød (BA), and the Younger Dryas (YD), the pond expanded, accumulation rates and proxies for erosion reached the highest values, indicative of humid conditions, with maxima in humidity during the BA and YD. Dry conditions and pond desiccation occurred in the Greenlandian–Northgrippian and by 6010 cal a bp the area was transformed into the mire of today. Comparisons with records from other sites in South America indicate that changes in humidity are most likely controlled by the Intertropical Convergence Zone, mainly during the glacial and postglacial, and by changes in the Pacific Ocean, more pronounced after the YD.     

High-resolution sea ice in long-term global ocean GCM integrations

The resolution of the sea-ice component of a coarse-resolution global ocean general circulation model (GCM) has been enhanced to about 22 km in the Southern Ocean. The ocean GCM is designed for long-term integrations suitable for investigations of the deep-ocean equilibrium response to changes in southern hemisphere high-latitude processes. The space and time scales of the high-resolution sea-ice component are commensurate with those of the resolution of satellite passive-microwave sea-ice data. This provides the opportunity for a rigorous evaluation of simulated sea-ice characteristics. It is found that the satellite-derived continuous high ice concentration of the interior winter ice pack can only be captured when vertical oceanic mixing is modified in a way that less local, intermittent convection occurs. Furthermore, the width and the variability of the coastal polynyas around the Antarctic continent and its ice shelves are best captured when some form of ice-shelf melting is accounted for. The width of the wintertime ice edge is reasonably reproduced, while its variability remains underestimated, closely following the coarse-grid pattern of the ocean model due to its high dependence on ocean temperature. Additional variability besides daily winds, e.g. in form of idealized tidal currents, improves the temporal and spatial ice-edge variability, while leads in the interior ice pack become more abundant, more in line with the fine-scale satellite-derived texture. The coast- or ice-shelf line is described on the fine grid based on satellite passive-microwave data. This method requires parts of a coarse coastal ocean grid cell to be covered by an inert layer of “fast ice” or “ice shelf”. Reasonable long-term global deep-ocean properties can only be achieved when these areas are not inert, i.e. are exposed to heat flux and ice growth, or when the vertical mixing parameterization allows for excessive open-ocean convection. The model area exposed to cold high-latitude atmospheric conditions thus being most decisive for a realistic representation of the long-term deep-ocean properties, suggests that high-latitude coastlines are definitely in need of being represented at high resolution, including ice sheets and their effects on the heat and freshwater flux for the ocean.     

A three-dimensional numerical groundwater flow model to assess the feasibility of managed aquifer recharge in the Tamne River basin of Ghana

Hydrogeology Journal - Increasing population growth and global climatic changes threaten water security in semiarid regions such as Northern Ghana. The Tamnean Plutonic Suite aquifer is the main...     

Issues associated with the distinction between climatic and tectonic controls on Permian alluvial fan deposits from the Kotzen and Barnim Basins (North German Basin)

Facies analysis focussing on coarse-grained sediments has been carried out on more than 2500 m of drill cores from seven wells from southern margins of the North German Basin (NGB). The NGB forms a central element of the Southern Permian Basin (SPB). The wells exposed conglomerates and sandstones of the Rotliegend Grüneberg and Parchim Formations deposited in the Kotzen Basin and the Barnim Basin.17 lithofacies types have been grouped into six lithofacies associations. The studied successions are dominated by fluid gravity flow deposits (hyperconcentrated flows and stream flows) of alluvial fan and alluvial plain systems. Maximum particle size/bed thickness plots (MPS/BTh) support the interpretation as fluid gravity flow deposits. The MPS and BTh data have also been used to differentiate coarsening–thickening and fining–thinning trends of the fan systems.The dominance of water-rich mass flow processes together with sedimentary structures such as dewatering structures and outwashed tops suggests the presence of wet-type fans and plains under semi-humid to semi-arid seasonal climates in the central SPB. The investigated sediments show variation in clast composition subsequent to deep erosion processes on basin margins and changes of source areas. Synsedimentary normal faults and clastic dykes have been interpreted as indicators of tectonic activity of grabens itself and its frames. On a larger scale, then evolution from a half-graben to a graben is apparent for the Tuchen Sub-basin at least. The progradational/retrogradational cycles of the studied alluvial fan systems document combined local tectonic movements and influences of climatic changes. However, our data did not allow for a clear distinction between climatic and tectonic signals. Furthermore, a one-to-one correlation of fan cycles with depositional trends in the NGB basin centre would appear to be oversimplistic.