First alkaline magmatism during Iberia–Newfoundland rifting

The age and origin of alkaline rocks emplaced into the sediments of the rift‐related continental Lusitanian basin were investigated to constrain earliest magmatic activity occurring prior to oceanic plate formation between Iberia and Newfoundland. The U–Pb titanite ages are 146.5 ± 1.6 (2σSTERR), 145.3 ± 1.4 and 142.3 ± 1.0 Ma, and initial Pb isotopic ratios of feldspars lie at 18.418–18.978 for ²⁰⁶Pb/²⁰⁴Pb, at 15.594–15.925 for ²⁰⁷Pb/²⁰⁴Pb and at 37.105–39.216 for ²⁰⁸Pb/²⁰⁴Pb. Initial ⁸⁷Sr/⁸⁶Sr ratios measured in the same feldspar fractions lie at 0.705409–0.706462. This episode of magmatic activity lasting for at least 4.2 ± 2.6 Myr most likely marks a phase of maximum lithospheric thinning during which zones of weakness were created to allow deep magmas to reach the surface. Such zones are preferentially re‐activated Palaeozoic faults of the Iberian plate. The isotope data suggest that the dominant volume of alkaline magmas was generated by partial melting of the metasomatized subcontinental Iberian mantle.     

The influence of climate,hydrology and permafrost on Holocene peat accumulation at 3500 m on the eastern Qinghai–Tibetan Plateau

Peatland of the eastern Qinghai–Tibetan Plateau lies at the convergence of the East Asian and Indian monsoon systems in eastern Asia. To understand the evolution of this peatland and its potential to provide new insights into the Holocene evolution of the East Asian monsoon a 6 m peat core was collected from the undisturbed central part of a peat deposit near Hongyuan. The age-depth profile was determined using 16 ¹⁴C-AMS age dates, the peat analysed for a range of environmental variables including carbon, nitrogen and hydrogen concentration, bulk density, δ¹³C and the associated spring water analysed for hydrogen and oxygen isotopes. The age-depth profile of the recovered peat sequence covers the period from 9.6 to 0.3 kyr BP and is linear indicating that the conditions governing productivity and decay varied little over the Holocene. Using changes in carbon density, organic carbon content and its δ¹³C, cold dry periods of permafrost characterised by low density and impeded surface drainage were identified. The low δ¹⁸O and δD values of the spring water emanating around the peat deposit, down to ?13.8 and ?102‰ (VSMOW), respectively, with an inverse relationship between electrical conductivity and isotopic composition indicate precipitation under colder and drier conditions relative to the present day. In view of the current annual mean air temperature of 1 °C this suggests conditions in the past have been conducive to permafrost. Inferred periods of permafrost correspond to independently recognised cold periods in other Holocene records from across China at 8.6, 8.2–7.8, 5.6–4.2, 3.1 and 1.8–1.5 kyr BP. The transition to a cold dry climate appears to be more rapid than the subsequent recovery and cold dry periods at Hongyuan are of longer duration than equivalent cold dry periods over central and eastern China. Light–dark banding peat on a scale of 15–30 years from 9.6 to 5.5 kyr BP may indicate a strong influence of decadal oscillations possibly the Pacific Decadal Oscillation and a potential link between near simultaneous climatic changes in the northwest Pacific, ENSO, movement of the Intertropical Convergence Zone and the East Asian Monsoon.     

REDD herrings or REDD menace: Response to Beymer-Farris and Bassett

Norwegian funded REDD+ projects in Tanzania have attracted a lot of attention, as has the wider REDD+ policy that aims to reduce deforestation and degradation and enhance carbon storage in forests of the developing countries. One of these REDD+ projects, managed by WWF Tanzania, was criticised in a scientific paper published in GEC, and consequently in the global media, for being linked to attempted evictions of communities living in the Rufiji delta mangroves by the Government of Tanzania, allegedly to make the area ‘ready for REDD’. In this response, we show how this eviction event in Rufiji mangroves has a history stretching back over 100 years, has nothing to do with REDD+ or any policy changes by government, and is not in any way linked to the work of any WWF project in Tanzania. We also outline some of the broader challenges faced by REDD+ in Tanzania.     

Cathodoluminescence microanalysis of silica and amorphized quartz

Cathodoluminescence (CL) techniques are used to investigate the defect structures of pure synthetic silicon dioxide (SiO₂) polymorphs. Pure, synthetic Types I, II, III and IV amorphous SiO₂ polymorphs, pure, synthetic crystal α-SiO₂ and pure, synthetic amorphized crystal α-SiO₂ have been investigated and their characteristic defects have been determined and compared. The CL emission from pure SiO₂ polymorphs is generally related to local point defects in the tetrahedrally coordinated SiO₂ host lattice. A range of CL emissions associated with non bridging oxygen defects, oxygen deficient defects and the radiative recombination of self trapped excitons are observed from both the pure synthetic crystal and amorphous SiO₂ polymorphs. In addition CL emissions associated with residual concentrations of Aluminium impurities are also observed from α-SiO₂ (quartz) and Type I and II a-SiO₂ (fused quartz). Localised amorphous micro-volumes may exist within natural α-SiO₂ due to the presence of a high concentration of pre-existing or induced defects. Amorphization of α-SiO₂ diminishes the difference between the defect structures and associated CL from α-SiO₂ and a-SiO₂. Thus CL investigation of the defect structure of a-SiO₂ polymorphs provides useful insight into the microstructure of amorphized α-SiO₂.     

Modeling hot spring chemistries with applications to martian silica formation

Many recent studies have implicated hydrothermal systems as the origin of martian minerals across a wide range of martian sites. Particular support for hydrothermal systems include silica (SiO₂) deposits, in some cases >90% silica, in the Gusev Crater region, especially in the Columbia Hills and at Home Plate. We have developed a model called CHEMCHAU that can be used up to 100 °C to simulate hot springs associated with hydrothermal systems. The model was partially derived from FREZCHEM, which is a colder temperature model parameterized for broad ranges of temperature (<−70 to 25 °C), pressure (1-1000 bars), and chemical composition. We demonstrate the validity of Pitzer parameters, volumetric parameters, and equilibrium constants in the CHEMCHAU model for the Na-K-Mg-Ca-H-Cl-ClO₄-SO₄-OH-HCO₃-CO₃-CO₂-O₂-CH₄-Si-H₂O system up to 100 °C and apply the model to hot springs and silica deposits.A theoretical simulation of silica and calcite equilibrium shows how calcite is least soluble with high pH and high temperatures, while silica behaves oppositely. Such influences imply that differences in temperature and pH on Mars could lead to very distinct mineral assemblages. Using measured solution chemistries of Yellowstone hot springs and Icelandic hot springs, we simulate salts formed during the evaporation of two low pH cases (high and low temperatures) and a high temperature, alkaline (high pH) sodic water. Simulation of an acid-sulfate case leads to precipitation of Fe and Al minerals along with silica. Consistency with martian mineral assemblages suggests that hot, acidic sulfate solutions are plausibility progenitors of minerals in the past on Mars. In the alkaline pH (8.45) simulation, formation of silica at high temperatures (355 K) led to precipitation of anhydrous minerals (CaSO₄, Na₂SO₄) that was also the case for the high temperature (353 K) low pH case where anhydrous minerals (NaCl, CaSO₄) also precipitated. Thus we predict that secondary minerals associated with massive silica deposits are plausible indicators on Mars of precipitation environments and aqueous chemistry. Theoretical model calculations are in reasonable agreement with independent experimental silica concentrations, which strengthens the validity of the new CHEMCHAU model.     

Low signal-to-noise event detection based on waveform stacking and cross-correlation: application to a stimulation experiment

We study the microseismicity (M _L ?<?2) in the region of Landau, SW Germany. Here, due to thick sediments (~3?km) and high cultural seismic noise, the signal-to-noise ratio is in general very low for microearthquakes. To gain new insights into the occurrence of very small seismic events, we apply a three-step detection approach and are able to identify 207 microseismic events (?1?<?M _L ?<?~1) with signal-to-noise ratios smaller than 3. Recordings from a temporary broadband network are used with station distances of approximately 10?km. First, we apply a short-term to long-term average detection algorithm for data reduction. The detection algorithm is affected severely by transient noise signals. Therefore, the most promising detections, selected by coinciding triggers and high-amplitude measures, are reviewed manually. Thirteen seismic events are identified in this way. Finally, we conduct a cross-correlation analysis. As master template, we use the stacked waveforms of five manually detected seismic events with a repeating waveform. This search reveals additional 194 events with a cross-correlation coefficient exceeding 0.65 which ensures a stable identification. Our analysis shows that the repeating events occurred during the stimulation of a geothermal reservoir within a source region of only about 0.5?km³. Natural background seismicity exceeding our detection level of M _L ?~?0.7 is not found in the region of Landau by our analysis.     

Resolution of impact‐related microstructures in lunar zircon: A shock‐deformation mechanism map

Abstract– The microstructures of lunar zircon grains from breccia samples 72215, 73215, 73235, and 76295 collected during the Apollo 17 mission have been characterized via optical microscopy, cathodoluminescence imaging, and electron backscatter diffraction mapping. These zircon grains preserve deformation microstructures that show a wide range in style and complexity. Planar deformation features (PDFs) are documented in lunar zircon for the first time, and occur along {001}, {110}, and {112}, typically with 0.1–25 μm spacing. The widest PDFs associated with {112} contain microtwin lamellae with 65°/<110> misorientation relationships. Deformation bands parallel to {100} planes and irregular low‐angle (<10°) boundaries most commonly have <001> misorientation axes. This geometry is consistent with a dislocation glide system with <100>{010} during dislocation creep. Nonplanar fractures, recrystallized domains with sharp, irregular interfaces, and localized annealing textures along fractures are also observed. No occurrences of reidite were detected. Shock‐deformation microstructures in zircon are explained in terms of elastic anisotropy of zircon. PDFs form along a limited number of specific {hkl} planes that are perpendicular to directions of high Young’s modulus, suggesting that PDFs are likely to be planes of longitudinal lattice damage. Twinned {112} PDFs also contain directions of high shear modulus. A conceptual model is proposed for the development of different deformation microstructures during an impact event. This “shock‐deformation mechanism map” is used to explain the relative timing, conditions, and complexity relationships between impact‐related deformation microstructures in zircon.     

New igneous zircon Pb/Pb and metamorphic Rb/Sr ages in the Yaounde Group (Cameroon, Central Africa): implications for the Central African fold belt evolution close to the Congo Craton

Three meta-igneous bodies from the Yaounde Group have been analyzed for their petrography, geochemistry, and ²⁰⁷Pb/²⁰⁶Pb zircon ages. According to their geochemical patterns, they represent meta-diorites. The meta-plutonites yielded identical zircon ages with a mean of 624?±?2?Ma interpreted as their intrusion age. This age is in agreement with previously published zircon ages of meta-diorites from the Yaounde Group. The meta-diorites derived mainly from crustal rocks with minor contribution from mantle material. The ⁸⁷Rb/⁸⁶Sr isochron ages of one meta-diorite sample and three meta-sedimentary host rocks are significantly younger than the obtained intrusion age. Therefore, they are not related to igneous processes. ⁸⁷Rb/⁸⁶Sr isochron ages differ from sample to sample (599?±?3, 572?±?4, 554?±?5, 540?±?5?Ma) yielding the oldest Neoproterozoic age (~600?Ma) for a paragneiss sample at a more northern location. The youngest Rb/Sr isochron age (~540?Ma) was obtained for a mica schist sample at a more southern location closer to the border of the Congo Craton. The ⁸⁷Rb/⁸⁶Sr whole rock-biotite ages are interpreted as cooling ages related to transpressional processes during exhumation. Therefore, several discrete metamorphic events related to the exhumation of the Yaounde Group were dated. It could be shown by Rb/Sr dating for the first time that these late tectonic processes occurred earlier at more distant northern locations of the Yaounde Group and lasted at least until early Cambrian (~540?Ma) more closely to the border of the Congo Craton.     

Coral skeletal delta(15)N reveals isotopic traces of an agricultural revolution

This study introduces a new method of tracing the history of nutrient loading in coastal oceans via delta(15)N analysis of organic nitrogen preserved in the skeleton of the massive Porites coral. Four coral cores were collected in Bali, Indonesia, from reefs exposed to high levels of fertilizers in agricultural run-off, from lagoonal corals impacted by sewage, and from a reef located 30 km offshore. Skeletal delta(15)N in the agriculturally exposed coral declined from 10.7+/-0.4 per thousand in 1970-1971, when synthetic fertilizers (-0.8 per thousand+/-0.2 per thousand) were introduced to Bali, to a depleted "anthropogenic" baseline of 3.5 per thousand+/-0.4% in the mid-1990s. delta(15)N values were negatively correlated with rainfall, suggesting that marine delta(15)N lowers during flood-bourn influxes of waste fertilizers. Reef cores exposed to untreated sewage in terrestrial discharge were enriched (7.8 and 7.3+/-0.4 per thousand), while the offshore core reflected background oceanic signals (6.2+/-0.4 per thousand). delta(15)N, N concentration, and C:N systematics indicate that the N isotopic composition of skeletal organic matter was generally well preserved over 30 years. We suggest that skeletal organic delta(15)N can serve as a recorder of past nitrogen sources. In Bali, this tracer suggests that the intensification of Western style agricultural practices since 1970 are contributing to the degradation of coastal coral reefs.