High-pressure behaviour along the jadeite NaAlSi2O6–aegirine NaFeSi2O6 solid solution up to 10 GPa

The volume variation as a function of pressure along the jadeite–aegirine solid solution was determined at room temperature up to pressures between 6.5 and 9.7 GPa by single-crystal X-ray diffraction. The unit-cell volumes collected at room pressure for the different compositions indicate a slight deviation from linearity along the join. The pressure–volume data have been fitted using a third-order Birch-Murnaghan equation of state (BM3-EoS). The bulk modulus, K _T0, varies from 134.0(7) GPa for pure jadeite to 116.1(5) GPa for pure aegirine. Its evolution with composition along the join is not linear and can be described by the following second order polynomial:

Stratigraphic and geochemical study of the organic-rich black shales in the Tarcău Nappe of the Moldavidian Domain (Carpathian Chain,Romania)

An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians), coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring within a deep, periodically isolated and tectonically controlled basin.     

Construction of three-phase data to model multiphase flow in porous media: Comparing an optimization approach to the finite element approach

Multiphase flow modelling is a major issue in the assessment of groundwater pollution. Three-phase flows are commonly governed by mathematical models that associate a pressure equation with two saturation equations. These equations involve a number of secondary variables that reflect the fluid behaviour in a porous medium. To improve the computational efficiency of multiphase flow simulators, several simplified reformulations of three-phase flow equations have been proposed. However, they require the construction of new secondary variables adapted to the reformulated flow equations. In this article, two different approaches are compared to quantify these variables. A numerical example is given for a typical fine sand.     

Installation of a vertical slurry wall around an Italian quarry lake: complications arising and simulation of the effects on groundwater flow

Slurry walls are non-structural barriers that are constructed underground to impede groundwater flow or manage groundwater control problems. The study area is in the Piemonte plain (Italy), close to the River Po. Quarrying works carried out below the piezometric surface created two big quarry lakes. The local groundwater system is characterized by a lower semi-confined aquifer, which is overlain by a semi-permeable bed of clayey peat (aquitard) and an upper unconfined aquifer. Locally, the peat fades away and the granulometry of this horizon becomes silty sandy. A planned enlargement of the quarry will increase the size and depth of the quarry lakes. So the aquitard bed between the two aquifers will be damaged, creating a mixing rate of groundwater. Such a procedure would not be compatible with the presence of two municipal wells upstream from the quarries. Consequently, the installation of a vertical diaphragm (slurry wall) is recommended to separate the aquifers and to act as a filter for the groundwater flowing from the unconfined to the semi-confined aquifer. To predict the consequences caused by the installation of the vertical diaphragm separating the unconfined aquifer and the semi-confined one, a specifically adjusted finite-difference model was used. The model showed a maximum rising of the water table equal to 12 cm, just upstream of the diaphragm and for a distance of about 100 m, and a maximum lowering of 2 cm just downstream of the diaphragm. However, the slurry wall would not cause any change in the piezometric head in the area where there are municipal wells and, hence, will not have any negative effect on the functionality of the municipal wells. Moreover, the migration of water from the unconfined aquifer through the vertical diaphragm will stimulate a series of attenuation and auto-depuration processes of eventual contaminants. These processes are due to the higher crossing time that the groundwater flow takes to go through the vertical barrier (t _a = 96.5 days, whereas for the horizontal semi-permeable layer t _a = 9.6 days). So, the vertical diaphragm can be a resolutive element, representing a mediation and separation factor between the unconfined and the semi-confined aquifers along the border of the quarrying areas, and a protective barrier for the water quality of the quarry lake and the semi-confined aquifer.     

Deep tunnel fronts in cohesive soils under undrained conditions: a displacement-based approach for the design of fibreglass reinforcements

The fronts of tunnels excavated under particularly difficult ground conditions by employing conventional tunnelling methods are commonly supported: the stabilization is usually achieved either by improving the mechanical properties of the soil (injections, jet grouting, soil freezing, etc.) or by introducing linear inclusions. This last technique, consisting in the introduction of pipes (usually made of fibreglass reinforced polymers) in the front, is particularly popular since it is very simple to adapt the reinforcement geometry, length and number to the different conditions encountered during the excavation. The design of this reinforcement technique is nowadays based on very simplified approaches: on either empirical formula or the limit equilibrium method. In a previous paper, the authors numerically studied the mechanical response of unreinforced fronts in cohesive soils and defined a non-dimensional front characteristic curve. In this paper, the authors intend to take into consideration the role of reinforcements by following the same approach. A procedure allowing the definition of the reinforced non-dimensional front characteristic curve, once the reinforcement pattern is assigned, is introduced. The practical use of this curve is described.

     

Crustal attenuation in the Southern Andean retroarc (38°–39°30′ S) determined from tectonic and gravimetric studies: The Lonco-Luán asthenospheric anomaly

The western retroarc of the Southern Andes between 38° and 40° S is formed by a NNW-elongated ridge not associated with stacked thrust sheets. On the contrary, during the last 4–3 Ma this ridge was affected by extensional deformation, regional uplift and related folding on a very broad scale. Receiver function analysis shows that the drainage divide area and adjacent retroarc lie over an attenuated crust. Expected crustal thickness at these latitudes is around 38 km, whereas in this part of the retroarc the thickness is less than 32 km. The causes for such attenuation have been linked to a moderate steepening of the subducted Nazca plate beneath the South American plate, which is suggested by a westward shift and narrowing of the magmatic arc during the last 4 to 5 Ma. Gravimetric studies show that the upper plate did not react homogeneously to slab steepening, but ancient sutures and lithospheric discontinuities deeply buried under Mesozoic to Cenozoic sequences in the retroarc were locally reactivated. These processes resulted in an asthenospheric anomaly that correlates at the surface with the area of Pliocene to Quaternary doming, widespread extension and three radial troughs. Two of the troughs have accommodated substantial amounts of extension, but the third was probably aborted at an early stage. Moreover, the presence of an anomalous concentration of calderas and large volcanic centers over the proposed asthenospheric anomaly, and their age distribution, may indicate minor migration of the asthenospheric anomaly between 4 and 2 Ma through the western South American plate.     

Mechanical interpretation of dry granular masses impacting on rigid obstacles

Acta Geotechnica - The evaluation of impact forces exerted by flowing granular masses on rigid obstacles is of fundamental importance for the assessment of the associated risk and for the design of...