Characterization of the manganese oxide produced by pseudomonas putida strain MnB1

Manganese oxides form typically in natural aqueous environments via Mn(II) oxidation catalyzed by microorganisms, primarily bacteria, but little is known about the structure of the incipient solid-phase products. The Mn oxide produced by a Pseudomonas species representative of soils and freshwaters was characterized as to composition, average Mn oxidation number, and N₂ specific surface area. Electron microscopy, X-ray diffraction, and X-ray absorption near edge structure spectroscopy were applied to complement the physicochemical data with morphological and structural information. A series of synthetic Mn oxides also was analyzed by the same methods to gain better comparative understanding of the structure of the biogenic oxide. The latter was found to be a poorly crystalline layer type Mn(IV) oxide with hexagonal symmetry, significant negative structural charge arising from cation vacancies, and a relatively small number of randomly stacked octahedral sheets per particle. Its properties were comparable to those of δ-MnO₂ (vernadite) and a poorly crystalline hexagonal birnessite (“acid birnessite”) synthesized by reduction of permanganate with HCl, but they were very different from those of crystalline triclinic birnessite. Overall, the structure and composition of the Mn oxide produced by P. putida were similar to what has been reported for other freshly precipitated Mn oxides in natural weathering environments, yielding further support to the predominance of biological oxidation as the pathway for Mn oxide formation. Despite variations in the degree of sheet stacking and Mn(III) content, all poorly crystalline oxides studied showed hexagonal symmetry. Thus, there is a need to distinguish layer type Mn oxides with structures similar to those of natural birnessites from the synthetic triclinic variety. We propose designating the unit cell symmetry as an addition to the current nomenclature for these minerals.     

Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.     

Search for Phobos and Deimos gas/dust tori using in situ observations from Mars Global Surveyor MAG/ER

More than 490 elliptical aerobraking and science phasing orbits made by Mars Global Surveyor (MGS) in 1997 and 1998 provide unprecedented coverage of the solar wind in the vicinity of the orbits of the martian moons Phobos and Deimos. We have performed a comprehensive survey of magnetic field perturbations in the solar wind to search for possible signatures of solar wind interaction with dust or gas escaping from the moons. A total of 1246 solar wind disturbance events were identified and their distribution was examined relative to Phobos, the Phobos orbit, and the Deimos orbit. We find that the spatial distribution of solar wind perturbations does not increase near or downstream of Phobos, Phobos’ orbit, or Deimos’ orbit, which would have been expected if there is significant outgassing or dust escape from the martian moons. Of the 1246 magnetic field perturbation events found in the MGS data set, 11 events were found within 2000 km of the Phobos orbit, while three events were found within 2000 km of the Deimos orbit. These events were analyzed in detail and found to likely have other causes than outgassing/dust escape from the martian moons. Thus we conclude that the amount of gas/dust escaping the martian moons is not significant enough to induce detectable magnetic field perturbations in the solar wind. In essence we have not found any clear evidence in the MGS magnetic field data for outgassing or dust escape from the martian moons.     

Seasonal Diet Shifts and Overlap Between Two Sympatric Catfishes in an Estuarine Nursery

This study describes the seasonal feeding habits of different size classes of Cathorops spixii and Cathorops agassizii along an estuarine ecocline and the food overlap when different size classes occur together. These species were essentially zoobenthivorous, feeding mainly on Polychaeta Nereis sp., Copepoda Pseudodiaptomus acutus, Ostracoda Asterope sp., Gastropoda: Littorinidae, and Bivalvia Mytilus sp. and Anomalocardia brasiliana. However, during their life cycle and between different habitats and seasons, their trophic guild can change to zooplanktivore. The competition for resources was observed among C. spixii and C. agassizii, but was significantly reduced due to the seasonal diference in habitat use by different ontogenetic phases in the main channel of the estuary. The food niche separation was strongly influenced by environmental fluctuations, principally of salinity, resulting from rainfall and river inflow. High abundance of some preys, such as P. acutus (all estuary), Asterope sp. (upper and middle estuary), and Littorinidae (upper and lower estuary), could influence the significant diet overlap, principally during the rainy season, and call for more detailed studies of the benthic community structure. Moreover, dietary overlap was observed mainly between smaller sizes (intraspecific and/or interspecific) or between corresponding ontogenetic phases (interspecific), suggesting some differentiation in the diet in relation to the size class. Differences in prey type and size between the different ontogenetic phases of these ariids, principally among juveniles and adults, could be related to the size of the mouth, since adults are able to successfully capture larger preys or larger quantities of particular items.     

Regional climate change experiments over southern South America. I: present climate

We present an analysis of a regional simulation of present-day climate (1981–1990) over southern South America. The regional model MM5 was nested within time-slice global atmospheric model experiments conducted by the HadAM3H model. We evaluate the capability of the model in simulating the observed climate with emphasis on low-level circulation patterns and surface variables, such as precipitation and surface air mean, maximum and minimum temperatures. The regional model performance was evaluated in terms of seasonal means, seasonal cycles, interannual variability and extreme events. Overall, the regional model is able to capture the main features of the observed mean surface climate over South America, its seasonal evolution and the regional detail due to topographic forcing. The observed regional patterns of surface air temperatures (mean, maxima and minima) are well reproduced. Biases are mostly within 3°C, temperature being overestimated over central Argentina and underestimated in mountainous regions during all seasons. Biases in northeastern Argentina and southeastern Brazil are positive during austral spring season and negative in other seasons. In general, maximum temperatures are better represented than minimum temperatures. Warm bias is larger during austral summer for maximum temperature and during austral winter for minimum temperature, mainly over central Argentina. The broad spatial pattern of precipitation and its seasonal evolution are well captured; however, the regional model overestimates the precipitation over the Andes region in all seasons and in southern Brazil during summer. Precipitation amounts are underestimated over the La Plata basin from fall to spring. Extremes of precipitation are better reproduced by the regional model compared with the driving model. Interannual variability is well reproduced too, but strongly regulated by boundary conditions, particularly during summer months. Overall, taking into account the quality of the simulation, we can conclude that the regional model is capable in reproducing the main regional patterns and seasonal cycle of surface variables. The present reference simulation constitutes the basis to examine the climate change simulations resulting from the A2 and B2 forcing scenarios which are being reported in a separate study.     

Monte Verde,South-Central Chile: Stratigraphy,climate change,and human settlement

Two sedimentary units are recognized by means of stratigraphic and sedimentological analyses at Monte Verde, a late Pleistocene archeological site with stone tools and well-preserved wood artifacts and botanical remains, that lies southwest of Lago Llanquihue and north of the Golfo de Reloncavi in the southern end of the Chilean Central graben. the geological evidence shows that at no time after 33,000 yr B.P., and perhaps since the first Llanquihue advance (before 56,000 yr B.P.), was the Monte Verde area covered by ice. Influences of two glacial advances at 20,000 and 15,000-14,500 yr B.P. are recognized at the site; effects of the Varas Interstade, however, are not identified. Rapid climatic change took place after the end of the Llanquihue Glaciation. It was shortly interrupted by a cool, wet period around 10,000 yr B.P., after which a well-documented Hypsithermal (8270-4750 yr B.P.) accompanied by pyroclastic vulcanism followed. The evidence indicates that around 13,000 yr B.P. 1) the site occupants settled on the sandy point bars and beaches of the old creek channel and 2) the area was habitated during cool and wet conditions similar to those that prevail in the area today. Evidence for reconstruction of the paleo-environment and climate of the terminal Pleistocene and the preliminary implications of these findings for understanding the human occupation at Monte Verde are discussed.     

Ottant'anni di Osservazioni Meteorologiche a Moncalieri (Torino)

Riassunto Si espongono ed illustrano i valori medi dei principali elementi meteorologici osservati a Moncalieri senza alcuna interruzione nell'ottantennio 1865–1945 e durante il quarantennio 1907–1946 per il vento. L'analisi delle medie quinquennali ed annuali pone in luce qualche caratteristica della variazione secolare dei medesimi fattori.

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Zusammenfassung Die Mittelwerte der wichtigsten meteorologischen Elemente die in Moncalieri ohne Unterbrechung gesammelt worden sind, werden angegeben und zwar für den Zeitraum 1865–1945, ausgenommen für den Wind, deren Beobachtungen auf die Periode 1907–1946 sich beziehen. Die Gänge der fünfjährigen und jährlichen Mitteln zeigen einige Eigentümlichkeiten der sekularen Variation für denselben Elemente, die herausgehoben werden.

     

Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at