Comparative study of digestion methods EPA 3050B (HNO₃--H₂O₂--HCl) and ISO 11466.3 (aqua regia) for Cu, Ni and Pb contamination assessment in marine sediments

Knowing the metal extraction capacity of a digestion method is crucial for a better environmental interpretation of metal concentrations determined in sediments. One of the main problems at the present is the lack of harmonization of information obtained by two of the most popular sediment partial digestion methods: ISO 11466.3 (aqua regia) and EPA 3050B (HNO?--H?O?--HCl). In the present work, the amount of Cu, Ni and Pb leached by using both methods was compared with the total content of those elements in marine sediments collected, as an example, from the Cienfuegos Bay, Cuba. Similar amounts of Cu were extracted by both methods; while leaching of Ni and Pb were different. Generally, the EPA method extracted more Ni than the ISO method. In contrast, Pb was extracted in a larger amount by the ISO method. Some explanations are given for the observed results. X-ray Diffraction, X-ray Fluorescence, Particle Induced X-ray Emission Spectrometry and Energy Dispersive X-ray coupled to Scanning Electron Microscopy were employed for this purpose. On the other hand, none of the methods studied extracted simultaneously the fraction of all the metals, probably provided by human activity (Theoretical Anthropogenic Fraction) in both sediments studied. The use of ISO 11466.3 or EPA 3050B is recommended since the analytical performance parameters of both, in combination with Flame Atomic Absorption Spectrometry, are adequate. For a better environmental interpretation of the analytical results, information on the extraction efficiency of the selected method for specific elements and sediments under study should also be provided, together with the determined concentrations.     

Accretion of Grenvillian terranes to the southwestern border of the R��o de la Plata craton, western Argentina

A comprehensive review of the geological, geochronological, and isotopic features of the Mesoproterozoic Grenvillian terranes attached to the southwest of the Río de la Plata craton in Early Paleozoic times is presented in this paper. They are grouped into the northern (sierras de Umango, Maz and del Espinal and surroundings), central (Sierra de Pie de Palo, southern Precordillera and Frontal Cordillera), and southern (San Rafael and Las Matras Blocks) segments. The Mesoproterozoic basement consists mainly of arc related, intermediate to acidic and mafic?Cultramafic rocks of 1,244?C1,027?Ma, with juvenile, Laurentian affinity. Exception to it is the Maz Group, with a protracted history and reworked character. They are affected by 846?C570?Ma, extensional magmatism in the northern and central segments, which represents the Neoproterozoic breakup of the Rodinia supercontinent. Successive passive margin sedimentation is registered in Late Neoproterozoic (~640?C580?Ma) and Cambro-Ordovician (~550?C470?Ma) times. The southern segment is noted for the younger sedimentation alone, and for showing the exclusive primary unconformable relationship between the Mesoproterozoic basement and Early Ordovician cover. The effects of Early Paleozoic Famatinian orogeny, associated with the collisions of Cuyania and Chilenia terranes, are recorded as main phase (480?C450?Ma), late phase (440?C420?Ma), and Chanic phase (400?C360?Ma). Among them, the tectonothermal climax is the Ordovician main phase, to which klippe and nappe structures typical of collisional orogens are related in the northern and central segments. Preliminary data allow us to suggest a set of paired metamorphic belts, with an outboard high-P/T belt, and an inboard Barrowian P/T belt.     

Recent and active tectonics of the external zone of the Northern Apennines (Italy)

We present a comprehensive study of the recent and active tectonics of the external part of the Northern Apennines (Italy) by using morphotectonic, geological–structural, and stratigraphic analysis, compared with the current seismicity of the region. This analysis suggests that the external part of the Northern Apennines is characterised by presence of three major systems of Quaternary compressive structures corresponding to (1) the Apenninic watershed, (2) the Apennines–Po Plain margin (pede-Apenninic thrust front), and (3) the Emilia, Ferrara, and Adriatic Fold systems buried below the Po Plain. Geological data and interpreted seismic sections indicate a roughly N–S Quaternary deformation direction, with rates <2.5 mm/year. The shortening decreased since the Pliocene, when our data indicate compression in a NNW–SSE direction and rates up to 7 mm/year. The trend and kinematics of the structures affecting the Apennines–Po Plain margin and the Po Plain subsoil fit well the pattern of the current seismicity of the area, as well as recent GPS and geodetic levelling data, pointing to a current activity of these thrust systems controlled by an overall compressive stress field. Close to the Apenninic watershed, earthquake focal mechanisms indicate that shallow extension is associated to deep compression. The extensional events may be related to a secondary extensional stress field developing on the hangingwall of the thrust system affecting the Apenninic watershed; alternatively, this thrust system may have been recently deactivated and overprinted by active normal faulting. Deeper compressive events are related to the activity of both a major basement thrust that connects at surface with the pede-Apenninic thrust front and a major Moho structure.     

Thermal and irradiation history of lunar meteorite Dhofar 280

Dhofar 280 recorded a complex history on the Moon revealed by high‐resolution ⁴⁰Ar‐³⁹Ar dating. Thermal resetting occurred less than 1 Ga ago, and the rock was exposed to several impact events before and afterwards. The cosmic ray exposure (CRE) age spectrum indicates a 400 ± 40 Ma CRE on the lunar surface. A unique feature of this lunar sample is a partial loss of cosmogenic ³⁸Ar, resulting in a (low‐temperature) CRE age plateau of about 1 Ma. This was likely caused by the same recent impact event that reset the (low‐temperature) ⁴⁰Ar‐³⁹Ar age spectrum and preceded the short transit phase to Earth of ≤1 Ma. Dhofar 280 may be derived from KREEP‐rich lunar frontside terrains, possibly associated with the Copernicus crater or with a recent impact event on the deposits of the South Pole–Aitken basin. Although Dhofar 280 is paired with Dhofar 081, their irradiation and thermal histories on the Moon were different. An important trapped Ar component in Dhofar 280 is “orphan” Ar with a low ⁴⁰Ar/³⁶Ar ratio. It is apparently a mixture of two components, one endmember with ⁴⁰Ar/³⁶Ar = 17.5 ± 0.2 and a second less well‐constrained endmember with ⁴⁰Ar/³⁶Ar ≤10. The presence of two endmembers of trapped Ar, their compositions, and the breccia ages seem to be incompatible with a previously suggested correlation between age or antiquity and the (⁴⁰Ar/³⁶Ar)_trapped ratio (Eugster et al. 2001; Joy et al. 2011a). Alternatively, “orphan” Ar of this impact melt breccia may have an impact origin.     

Sensitivity of LAGEOS to changes in Earth's (2, 2) gravity coefficients

In recent years it has become of geophysical interest to detect a possible time variation of the low-degree coefficients of the Earth's gravity field, in particular the (2, 2) tesseral harmonic. We investigate the possibility of detecting such a phenomenon via analysis of the tracking data from LAGEOS, the passive geodynamics satellite tracked by laser stations on the ground. For this purpose the main problems are caused: (i) for short orbital arcs, by the irregular distribution in time of the tracking data, and by the dynamical effects of oceanic tides, which cannot be easily separated from the effects of geopotential changes; (ii) for long orbital arcs, by the difficulty of reliably predicting the variable drag-like force that is causing a slow semimajor axis decay. We estimate that a relative accuracy of the order of 10^–4 in the (2, 2) coefficients can be reached provided that a larger number of higher technology laser stations is available, and that better modelling is possible of the drag-like force. Both these conditions seem quite unrealistic at present. If a relative accuracy better than 10^–4 has to be reached, an effective separation of the tidal perturbations is also needed, since they give rise to perturbations with a similar signature.     

Endogenous and nonimpact origin of the Arkenu circular structures (al‐Kufrah basin—SE Libya)

Abstract– The twin Arkenu circular structures (ACS), located in the al‐Kufrah basin in southeastern Libya, were previously considered as double impact craters (the “Arkenu craters”). The ACS consist of a NE (Arkenu 1) and a SW structure (Arkenu 2), with approximate diameters of about 10 km. They are characterized by two shallow depressions surrounded by concentric circular ridges and silica‐impregnated sedimentary dikes cut by local faults. Our field, petrographic, and textural observations exclude that the ACS have an impact origin. In fact, we did not observe any evidence of shock metamorphism, such as planar deformation features in the quartz grains of the collected samples, and the previously reported “shatter cones” are wind‐erosion features in sandstones (ventifacts). Conversely, the ACS should be regarded as a “paired” intrusion of porphyritic stocks of syenitic composition that inject the Nubia Formation and form a rather simple and eroded ring dike complex. Stock emplacement was followed by hydrothermal activity that involved the deposition of massive magnetite–hematite horizons (typical of iron oxide copper‐gold deposits). Their origin was nearly coeval with the development of silicified dikes in the surroundings. Plugs of tephritic‐phonolitic rocks and lamprophyres (monchiquites) inject the Nubian sandstone along conjugate fracture zones, trending NNW–SSE and NE–SW, that crosscut the structural axis of the basin.     

An integrated approach to environmental quality assessment in a coastal setting in Campania (Southern Italy)

The coastal region of Southern Italy’s Caserta province, known as the Litorale Domitio (Domitia coast) has been subjected to increasing pressure from unsustainably fast economic and urban growth in the last century, that resulted in a induced serious land degradation. To obtain a comprehensive picture of the ecological status of the Domitia coastal zone (Campania, Southern Italy), a holistic methodology has been applied. Sedimentological, geochemical, and biological analyses of the surface sediments and water samples were performed along the submerged beach. The data were integrated using a geographical information system, together with information on past and present land use and human activities along the coast and in inland regions. Heavy metal concentrations in sediments plus As and Se (Cd, Co, Cr, Cu, Hg, Ni, Pb, V, Zn) and their enrichment factors, which are important for identifying polluted areas in countries like Italy (where environmental legislation has not yet established intervention limits), indicate excesses Cd, Cr, Pb, and V of probable anthropogenic origin. A microbiological contamination of marine waters has been detected by the Regional Environmental Protection Agency of Campania. The Bacteriological Quality Index map shows that bathing areas must be classified as “contaminated” and “highly contaminated”. High levels of chemical and biological contamination are particularly common in both bathing seawater and sediments along the coastal zone south of the Volturno River, where the existing wastewater treatment plant is not properly working, to date. Factory farming, which is widespread in the area, is likely to be an additional important source of contamination. In accordance with these conclusions, analyses of the benthic diatom community revealed dominance of eutrophic species.     

Predictive assessment of the asbestos content in the Western Italian Alps: an essential tool for an effective approach to risk analysis and management in tunneling operations and muck reuse

The modern approach to the design and management of tunnel excavation, and muck reuse, can be influenced to a great extent by the possible presence of rock formations containing asbestos minerals. This situation creates problems concerning the protection of the workers’ health and the expectable environmental criticalities, while a drastic re-consideration of the muck destination is necessary. Since, in the case of carcinogens, corrective action following exposure or dispersion is not acceptable, detailed knowledge of the characteristics of the material to be excavated is all the more essential. Only on this basis it is possible to design the tunneling operations in a prevention through design approach, so that the tunnel driving techniques, fittings and technologies, and special equipment and modus operandi, can grant, where necessary, minimized risk conditions, and make a correct decision on whether, how and when these measures must be fully activated, since such an approach involves a remarkable impact on costs and work organization. In the Western Alps a detailed identification and quantification of the asbestos content in rocks is a difficult task, due to the fact that the asbestos in the host rocks, mainly serpentinite, shows a highly variable distribution, typical of ophiolitic belts throughout the world, as it is mostly associated with joints and shear zones. The possibilities of a predictive assessment of the asbestos content in the formations to be excavated are here discussed, with special reference to the reliability of the achievable results.     

On the estimation of the maximum depth of investigation of transient electromagnetic soundings: the case of the Vizcaino transect,Mexico

We test an approach proposed in the literature for estimating the maximum depth of investigation (MDI) of in-loop transient electromagnetic soundings (TEM) with data from the Vizcaino transect, a profile of 38 TEM soundings crossing the Baja California peninsula. The validity of this approach is confirmed by comparing the MDI with the deepest interface of 16 stratified models. In these soundings, all located over the Vizcaino basin, the measured data are not affected by induced polarization. The models indicate the presence of a dipping conductor interpreted as a zone of seawater intrusion with a large lateral extension of over 70 km. The remaining 22 soundings, located over igneous and metamorphic rocks, show reversals in the voltage polarity, indicating the presence of induced polarization effects. The layered Cole-Cole models for these soundings suggest a significant decrease in the MDI. This is confirmed by analyzing the depth behavior of the subsurface current densities. We further analyze the noise level of a data set comprising close to 2000 late-time voltages of about 400 TEM sites acquired in northwestern Mexico. No difference was found between the stationary noise levels of winter and summer, presumably because near thunderstorms are practically absent in this part of Mexico.