Mineral systems and the thermodynamics of selenites and selenates in the oxidation zone of sulfide ores – a review

Mineralogy and Petrology - Contemporary mineralogy and geochemistry are concerned with understanding and deciphering processes that occur near the surface of the Earth. These processes are...     

A mathematical model for steady‐state regolith production at constant erosion rate

It has been hypothesized that many soil profiles reach a steady‐state thickness. In this work, such profiles were simulated using a one‐dimensional model of reaction with advective and diffusive solute transport. A model ‘rock’ is considered, consisting of albite that weathers to kaolinite in the presence of chemically inert quartz. The model yields three different steady‐state regimes of weathering. At the lowest erosion rates, a local‐equilibrium regime is established where albite is completely depleted in the weathering zone. This regime is equivalent to the transport‐limited regime described in the literature. With an increase in erosion rate, transition and kinetic regimes are established. In the transition regime, both albite and kaolinite are present in the weathering zone, but albite does not persist to the soil–air interface. In the weathering‐limited regime, here called the kinetic regime, albite persists to the soil–air interface. The steady‐state thickness of regolith decreases with increasing erosion rate in the local equilibrium and transition regimes, but in the kinetic regime, this thickness is independent of erosion rate. Analytical expressions derived from the model are used to show that regolith production rates decrease exponentially with regolith thickness. The steady‐state regolith thickness increases with the Darcy velocity of the pore fluid, and in the local equilibrium regime may vary markedly with small variations in this velocity and erosion rate. In the weathering‐limited regime, the temperature dependences for chemical weathering rates are related to the activation energy for the rate constant for mineral reaction and to the ΔH of dissolution, while for local equilibrium regimes they are related to the ΔH only. The model illustrates how geochemical and geomorphological observations are related for a simple compositional system. The insights provided will be useful in interpreting natural regolith profiles. Copyright © 2010 John Wiley & Sons, Ltd.     

Automated Segmentation of Resistivity Image Logs Using Wavelet Transform

We describe a wavelet-transform-based method for automated segmentation of resistivity image logs that takes into account the apparent dip in the data and addresses the problem of discriminating lithofacies boundaries from noise and intrafacies variations. Our method can be applied to borehole measurements in general, but might have an advantage when applied to resistivity image logs as it addresses explicitly the large variability in facies segments recorded with a high-resolution multiple-sensor tool. We have developed an algorithm based on this method that might outperform other existing segmentation methods in the cases of low to moderate dip. We made a detailed comparison of the segmentation from our method with the one done by a geologist to delineate different lithofacies blocks in a well drilled in a deepwater depositional environment. Our results show considerable success rates in reproducing the geologically defined lithofacies boundaries, and the generality of our procedure suggests it could also be applied to other depositional environments.     

Reliable Procedure for Molecular Analysis of Airborne Microflora in Three Indoor Environments: An Office and Two Different Museum Contexts

Biological aerosols from air constitute a significant source of exposure to microorganisms in public places. Airborne microorganisms are involved in the development of certain respiratory symptoms, allergies, or infections among users and occupants. Various sampling instruments have commonly been used in aerobiology to collect bacteria and fungi suspended in the air. The objective of this study was to develop a reliable procedure for sampling in indoor public environments presenting different levels of occupancy, airborne bacteria and fungi to be subjected to molecular analysis (bacteria and fungi quantitative PCR, capillary electrophoresis single strand conformation polymorphism fingerprinting). Four different sampling devices were tested in situ in an office building (open‐plan type) and the sampling strategy chosen was tested in two museum contexts. In accordance with the drawbacks involved to our study (quantitative and qualitative aspects, cost, and overcrowding), cyclone device appeared to be most suitable. The results underline the effectiveness of this high‐volume aerosol sampling device for both qualitative and quantitative molecular analysis. Four in situ sampling collections were carried out in 1 day in the Louvre Museum to study quantitative and qualitative variations of airborne bacterial and fungal diversity. The quantitative results revealed a similar order of magnitude for the numbers of both bacteria and fungi. In the Louvre Museum, the samples yielded between 3.7 × 10⁴ and 4.1 × 10⁴ genome equivalent (GE) bacteria/m³ air and between 5.0 × 10⁴ and 5.9 × 10⁴ GE fungi/m³ air and in the Decorative Arts Museum between, 2.1 × 10⁴ and 2.5 × 10⁴ GE bacteria/m³ air and between 1.4 × 10⁴ and 1.7 × 10⁴ GE fungi/m³ air. The results also indicate that the dominant bacterial community displayed a stable structure over a short period of time whereas dominant eukaryotic airborne community appeared more variable.     

The Problem of Double Longitudes on Glavač’s Map

Abstract

Exploring large volumes of geospatial data is difficult. This paper presents an approach that combines visual and computational analysis to make this process easier. This approach is based on the effective application of computational algorithms, such as the Self-Organizing Map (SOM). These are used to uncover the structure, patterns, relationships and trends in the data, and for the creation of abstractions where conventional methods may be limited. In addition, graphical representations are applied to portray extracted patterns in a visual form that allows for better understanding of the derived structures and possible geographical processes, and should facilitate knowledge construction.     

Curie Point Depth Estimates and Correlation with Subduction in Mexico

We investigate the regional thermal structure of the crust in Mexico using Curie Point Depth (CPD) estimates. The top and bottom of the magnetized crust were calculated using the power-density spectra of the total magnetic field from the freely available ??Magnetic Anomaly Map of North America??. We applied this method to estimate the regional crustal thermal structure in overlapping square windows of 2°?×?2°. The CPD estimates range between 10 and 40?km and show several regions of relatively shallow and deep magnetic sources, with a general inverse correlation with measured heat flow. A deep CPD region (20?C30?km) is located in the fore-arc area where the subducting Cocos plate has a flat-slab geometry. This deep region is bound to the NW and SE by shallow CPD areas beneath the states of Michoacan (CPD?=?12?C16?km) and Oaxaca (CPD?=?~16?km), respectively. There is a good spatial correlation between this deep CPD area and two main fracture zones located on the incoming Cocos plate (Orozco and O??Gorman fracture zones), suggesting that subduction plays an important role in setting apart different CPD provinces along the Mexican coast. Another deep CPD (16?C32?km) area corresponds to the region where the Rivera plate subducts beneath Jalisco block. The Trans-Mexican Volcanic Belt is characterized by a decrease in Curie depths from west (16?C20?km) to east (10?C12?km). Finally, several deep CPD areas are situated in the back-arc region where old Mesozoic terrains are present. Our results suggest that the main control on the crust??s regional thermal structure in the fore-arc and volcanic arc regions is due to the subduction of the Cocos and Rivera plates beneath Mexico.     

From back-analysis to run-out prediction: a case study in the Western Italian Alps

Rock avalanches are complex phenomena that occur with a low frequency but which have a high destructive potential. As a consequence, the people who are responsible for the management of a territory are more and more interested in predicting the possible evolutions of well-known potential events. Tackling the above problems from a quantitative point of view, the RASH3D code, based on continuum mechanics concepts, has been here used to predict the evolution of a potential rock avalanche in the Western Italian Alps. A calibration-based approach, in which rheological parameters are constrained by systematic adjustment during trial-and-error back-analysis of past events similar to the landslide under investigation, is proposed to set rheological parameter values to be used for prediction purposes. The back-analysis of a 2?10⁶ m³ rock avalanche located in the Divedro Valley, close to the area of the potential event, has then been analysed using both a frictional and a Voellmy rheology. The characteristics of the slope and the dynamics of the event have made the frictional rheology more suitable to come to the correct simulation of the historical case. The back-analysis results have contributed not only in the selection of the rheological parameter values but also in the choice of the type of rheological law to use in the carried out forward-analyses.     

Trace-element study and age dating of zircon from chromitites of the Bushveld Complex (South Africa)

The layered Bushveld Complex hosts a number of chromitite layers, which were found to contain significant amounts of zircon grains compared with adjacent silicate rocks. Cathodoluminescent-dark, partially metamict cores and transparent rims of composite zircon grains were analyzed for trace elements with SIMS and LA-ICPMS techniques. The cores are enriched in REE, Y, Th and U and are characterized by distinctly flatter REE patterns in contrast to those of the rims and transparent homogenous crystals. Zircon from the different stratigraphic units has specific Th/U ratios, the highest of which (1.5–4) occurs in a Merensky Reef zircon core. The Ti content of Bushveld zircon ranges from 12 to 52 ppm correlating to a crystallization temperature range of 760–930 °C. The geochemical characteristics of the first zircon generation are consistent with its high-temperature crystallization as the first major U, Th and REE acceptor from a highly-evolved residue of the high-Mg basalt magma, whereas the rims and coreless crystals have crystallized from percolating intercumulus liquid of new influx of the same magma. U-Pb SHRIMP dating of zircon cores and rims does not reveal a distinguishable difference between their ages indicating the absence of inherited zircon. Concordia ages of 2,051?±?9 Ma (2σ, MSWD?=?0.1) and 2,056?±?5 Ma (2σ, MSWD?=?0.05) for zircons from the Merensky Reef and the Upper Platreef located equally near the top of the Critical Zone are in agreement with published ages for the Merensky Reef. Zircon from the deeper-seated Lower Group, Middle Group and Lower Platreef chromitites yields younger concordia ages that may reflect prolonged late-stage volatile activity.