Problems of Oxfordian and Kimmeridgian stratigraphy in northern Central Siberia (Nordvik Peninsula section)

The Oxfordian–Lower Hauterivian section of the Nordvik Peninsula (northern Central Siberia) is a reference for developing zonal scales for various fossil groups and improving the Boreal zonal standard. In the middle 1950s–late 1980s, it was studied extensively by geologists, stratigraphers, lithologists, and experts on various fossil groups. These studies yielded rich fossil and microfossil collections and a set of parallel zonal scales for various faunal groups. Recently, a new detailed ammonite zonation of the Oxfordian and Kimmeridgian units of this section has been proposed. These results contradict the previous biostratigraphic data on ammonites, foraminifers, and palynomorphs. In the present paper, all the biostratigraphic data on the Oxfordian and Kimmeridgian units of the Nordvik Peninsula (Cape Urdyuk-Khaya) and northern Central Siberia undergo a comprehensive analysis and comparison with those on the Boreal Realm. The ammonite-constrained stratigraphic position of the lower Upper Jurassic in the Cape Urdyuk-Khaya section is interpreted as Upper Oxfordian or Middle Oxfordian. In our view, this difference in the understanding is due to the misidentification of some Oxfordian ammonite forms. The zones based on other fossil groups (foraminifers, dinocysts) which were distinguished in the Upper Oxfordian and Kimmeridgian sections of the Nordvik Peninsula are well traceable circumarctically. Their stratigraphic position in various regions of the Northern Hemisphere is constrained by ammonites and bivalves. However, if we use the last alternative ammonite zonation of this section part, hardly explicable contradictions will appear in interregional foraminiferal and dinocyst correlations.     

The impact of dolomite and plagioclase weathering on the chemistry of shallow groundwaters circulating in a granodiorite-dominated catchment of the Sila Massif (Calabria,Southern Italy)

This work is aimed at investigating the weathering processes of the granodiorites cropping out in a small catchment of the Sila Massif. The mineral constituents in this granodiorite are plagioclase, often zoned with a Ca-rich core and a Na-rich rim, quartz, chlorite, K-feldspar, white mica and epidote. During this study, dolomite was discovered in local stream sediments, as separate monomineralic grains, probably resulting from erosion of veins cutting the crystalline rocks. Prevailing dissolution of foreign dolomite and a Ca-rich plagioclase is suggested by the Ca–Mg–HCO₃ chemical composition of local groundwaters and stream waters, which is rather unexpected for waters interacting with granitoid rocks. These qualitative observations are quantitatively confirmed by reaction path modelling of the weathering processes occurring in the study area, which was carried out using the EQ3/6 software package, version 8.0, and the Double Solid Reactant Method. Indeed, it was possible to ascertain that the release of both major dissolved constituents and several trace elements (Ba, Co, Cr, Fe, Mn, Ni, Pb, Sr, V and Zn), from rocks to waters, is chiefly controlled by the dissolution of foreign dolomite and the Ca-rich core of zoned plagioclases.     

Characterization of the proteinaceous matter in marine aerosols

Marine aerosols play a dominant role in the transfer of oceanic material to the atmosphere. Most marine aerosol originates when air bubbles burst at the sea surface ejecting material from the sea surface microlayer and bubble surface layers into the air. Concentrations of chemical compounds in these surface layers often differ from their concentrations in bulk water. We examined the enrichment of aerosols with proteinaceous matter and attempted to characterize the physical nature and sources of this matter. We measured concentrations of dissolved free (DFAA), dissolved combined (DCAA), and particulate (PAA) amino acids, transparent stainable particles (TSP), and bacteria and virus-like particles as carriers of protein, in natural and simulated aerosols. We also evaluated D/L ratios certain amino acids in all amino acid fractions.DFAA and DCAA enriched the aerosols we sampled by 1.2–20 times compared to bulk seawater; PAA enrichment was usually higher (up to 50-fold). Aerosols contained particles typical of seawater, e.g., microorganisms, organic debris, inorganic particles with adsorbed organic matter, but also a large number of semitransparent gel-like particles, which all contained amino acids. Some of these particles were probably scavenged from bulk water, but new particles produced as bubbles burst at the surface comprised at least 10% of total proteinaceous matter in the aerosol. D/L ratios of certain amino acid suggested that the particles were most likely made from dissolved polymers secreted by phytoplankton that were concentrated on bubble surfaces and in the microlayer. Examination with Alcian Blue (a dye that targets carbohydrates) and Coomassie Blue (a dye that targets proteins) showed that most TSP in the aerosols contained both proteins and polysaccharides. Microorganisms enriched the aerosols by up to two orders of magnitude, but contributed less than 4% to the total protein pool.     

Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3·3H2O,Fe2(SeO3)3·5H2O) and the water content in the natural ferric selenite mandarinoite

Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe₂(SeO₃)₃·(6-x)H₂O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected.     

Évolution pression–température des amphibolites de la zone axiale au cours du métamorphisme hercynien des Pyrénées orientales

Thin levels of amphibolites from the Canigou, Albères and Cap de Creus massifs have been studied in order to investigate their pressure and temperature evolution during time. P and T values have been calculated using the amphibole–plagioclase–quartz thermo-barometer. Si, Al, Mg and Fe of zoned amphiboles have been analysed from core to rim by microprobe. By combining the results obtained from several (or different) crystals, P–T–t paths have been determined using the amphibole-plagioclase-quartz equilibriums. In the Canigou Massif, the amphibolites have recorded anti-clockwise P–T–t paths around a peak of metamorphism located at about 650?°C–6.1 kbar, whereas in the Albères Massif, the calculated P–T–t paths of amphibolites near the paragneisses are retrograde only, from 600?°C–5 kbar to 450?°C–2.5 kbar, but one cummingtonite-bearing amphibolite has also recorded an anti-clockwise evolution around 650?°C–4.5 kbar. The retrograde P–T–t paths recorded for amphibolites from the ‘Cap de Creus’ Massif are retrograde only, from 650?°C–6 kbar and 400?°C–1 kbar. To cite this article: C. Triboulet et al., C. R. Geoscience 337 (2005).     

Paleontological and magnetostratigraphic data on Upper Cretaceous deposits from borehole no. 8 (Russkaya Polyana District, Southwestern Siberia)

This work presents results of complex research (palynological, macro- and microfaunistic, and paleomagnetic) of Upper Cretaceous deposits, opened by borehole no. 8 in the Russkaya Polyana District (the southern margin of the Omsk Depression, Southwestern Siberia). The paleontological data obtained allowed us to establish the age of deposits. Based on dinocysts, nannoplankton and spore-pollen complexes, the section of borehole no. 8 has been divided into Pokur, Kuznetsovo, Ipatovo, Slavgorod, and Gan’kino Formations. This work gives data on the composition of zonal palynomorphs, nannoplankton, and microfaunistic complexes. Based on the complex data obtained, the magnetostratigraphic section of Upper Cretaceous deposits has been developed. The section consists of three magnetozones: normal and two reversed polarity magnetozones. The Pokur, Kuznetsovo and Ipatovo Formation (Cenomanian-Santonian) belong to the long normal polarity magnetozone; the Slavgorod and Gan’kino Formations (Campanian-Maastrichtian), separated by a stratigraphic break, belong to reversed polarity magnetozones. The magnetostratigraphic section has been correlated with the general magnetostratigraphic and magnetochronological time scales.     

Interannual variability of the zooplankton on the shelf of the northeastern Black Sea in the autumn period

The variability of the mesozooplankton stock in the shelf pelagic communities was studied in the late summer and autumn of 2006–2008. The plankton community’s structure and distribution were described for the shoreward transect (Gelendzhik city vicinity). The indirect and direct effect of the ctenophores Mnemiopsis leidyi and Beroe ovata on the mesozooplankton community was studied. The long-term changes in the meso- and macroplankton communities of the Black Sea were analyzed for the period of 2001–2008. The effects of the climatic factors, the water mass circulation, and the factors’ interplay on the mesozooplankton dynamics were assessed. Despite the wide range of the environmental conditions, the stock biomass of Mnemiopsis leidyi appeared to be quite stable within the studied period.     

Distribution of trace metals in anchialine caves of Adriatic Sea,Croatia

This study presents results of the first comprehensive research on ecotoxic trace metals (Cd, Pb, Cu and Zn) in aquatic anchialine ecosystems. Data show the influence of hydrological and geological characteristics on trace metals in highly stratified anchialine water columns.