The East Caledonian Current: A Case Example for the Intercomparison between AltiKa and In Situ Measurements in a Boundary Current

This paper presents an assessment of SARAL/AltiKa satellite altimeter for the monitoring of a tropical western boundary current in the south-western Pacific Ocean: the East Caledonian Current. We compare surface geostrophic current estimates obtained from two versions of AltiKa along-track sea level height (AVISO 1 Hz and PEACHI 40 Hz) with two kinds of dedicated in situ datasets harvested along the satellite ground tracks: one deep-ocean current-meter mooring deployed in the core of the boundary current and five glider transects. It is concluded that the AltiKa-derived current successfully captures the velocity of the boundary current, with a standard error of 11 cm/s with respect to the in situ data. It also appears important to reference AltiKa sea level anomaly to the latest mean dynamic topography available in our area. Doing so, Ka-band altimetry provides a satisfactory representation of the western boundary current. Thereby, it usefully contributes to observing its variability in such a remote and under-observed ocean region. However, the rather long repeat period of SARAL (35 days) in comparison to the high frequency variability seen in the flow velocity of the boundary current calls for a combined use of SARAL with the other satellite altimetry missions.     

Kirishites,a new type of natural high-carbon compounds

On the right-hand bank of the Volkhov River, in the natural area of tektite-like glasses (Volkhovites), fragments of shungites and slags with bunches of hairlike dark brownish enclosures were found. The filament thickness ranged from 20 to 100 μm, and separate “hairlines” were 3 cm in length. The composition of shungites and “hairlines” was found to be identical, which allowed us to consider the latter as aposhungite carbon formations. The high-carbon hairline structures associated with volkhovites are called kirishites. Kirishites are a new type of high-carbon structures that formed simultaneously with volkhovites in the case of explosion-type delivery of carbon slag and shungite fragments to the daylight surface during Holocene explosive activity. Under sharply reductive conditions, the slags partially melted, the melts were segregated, and carbonaceous-silicate and carbonaceous-ferriferous glasses formed with subsequent decompression-explosive liberation of carbon-supersaturated structures, which were extruded from shungite and slag fragments in the form of a resinoid mass. The “hairlines” were found to be zonal in structure: the central axial zones are composed of high-nitrogen hydrocarbon compounds, and peripheral regions are essentially carbonaceous with a high content of organic-mineral compounds and numerous microanomalies of petrogenic, volatile, rare, and ore elements. Infrared spectroscopy identified in kirishites proteinlike compounds, diagnosed in absorption bands (in cm⁻¹) 600–720 (Amid V), 1200–1300 (Amid III), 1480–1590 (Amid II), 1600–1700 (Amid I), 3000–3800 (vibrations in NH₂ and II groups). Gas chromatography, with the possibility of differentiation of left- and right-handed forms, revealed a broad spectrum of amino acids in kirishites, with their total content found to be the absolutely highest record for natural bitumens, an order of magnitude higher than the largest amino acid concentrations ever revealed in fibrous high-structured kerite crystals from Volyn pegmatites and in Transbaikalia phyto fulgurates. Like in phytofulgurites and fibrous kerites, in kirishites the amino acids are abiogenic, and they are predominately left-handed in configuration, contrary to the commonly accepted view about the exclusively biological nature of left-handed amino acids and their natural abiological thermofusion. Kirishites can be considered as models of prebiotic systems, predecessors of the simplest living organisms. This process could be favored by extreme conditions with rapid variations of temperature and pressure. Further study of kirishites and construction of a kirishite formation model will also be useful for development of the conception of endogenous ore-naphtobiogenesis.     

Extended time weather forecasts contributes to agricultural productivity estimates

Weather conditions in critical periods of the vegetative crop development influence crop productivity, thus being a basic parameter for crop forecast. Reliable extended period weather forecasts may contribute to improve the estimation of agricultural productivity. The production of soybean plays an important role in the Brazilian economy, because this country is ranked among the largest producers of soybeans in the world. This culture can be significantly affected by water conditions, depending on the intensity of water deficit. This work explores the role of extended period weather forecasts for estimating soybean productivity in the southern part of Brazil, Passo Fundo, and Londrina (State of Rio Grande do Sul and Paraná, respectively) in the 2005/2006 harvest. The goal was to investigate the possible contribution of precipitation forecasts as a substitute for the use of climatological data on crop forecasts. The results suggest that the use of meteorological forecasts generate more reliable productivity estimates during the growth period than those generated only through climatological information.     

Volkhovite: A new type of tektite-like glass

Volkhovites are tektite-like glasses of mafic and ultramafic composition discovered in the fluvioglacial drift of the Valdai glaciation (10–60 ka ago) along the right bank of the Volkhov River (59°27′ N, 32°01′ E). Volkhovite particles are small in size (0.1–3.0 mm) and irregular in shape, with various microtektite aerodynamics (globular, droplike, and dumbbell-like forms). They are perfectly preserved, and, thus, postglacial in age. Sporadic volkhovite grains (up to 20 items per 1 kg of loam) were detected over an area 1.0 × 1.5 km². Some samples from local spots 20 × 30 m² in size are anomalously enriched, up to 1700 volkhovite grains per 1 kg of loam. Tiny Ti-Fe, Fe, and Cu-Au spherules, particles of quenched glass and cinder, and fragments of the Precambrian and Paleozoic rocks are spatially associated with volkhovites. The suggested cryptomagmatic model assumes that the glass and cinder are pre-Holocene in age, whereas volkhovites were formed in the post-glacial time as a result of the outburst of the slag-stone-melt-mud-gas mixture that ascended from the asthenosphere to the surface. Drops of the melt solidified in the air instantaneously to form tectite-like glasses, and the tuffisite-like agglomerate mixed with the fluvioglacial drift.     

Determination of Selenium Concentration in Sixty Five Reference Materials for Geochemical Analysis by GFAAS after Separation with Thiol Cotton

Selenium has been determined in sixty five geological reference materials of different origins by graphite furnace atomic absorption spectrometry. Samples were decomposed with a mixture of nitric and hydrofluoric acids. Selenium was reduced to Se^IV with hydrochloric acid, and then fixed and separated from the matrix on thiol cotton. After digestion of the thiol cotton in hot nitric acid, the Se concentration was measured using palladium and magnesium nitrates as a matrix modifier. The limit of determination was 0.02 μg g⁻¹, the precision of the results (relative standard deviation of 3 to 8 replicates) varied from 2.6 to 17.7% with an average of 7.9% in the range 0.02-42.7 μg g⁻¹ and was similar to the value obtained for synthetic samples. Our results are in good agreement with available literature values.     

Recent dynamics of subarctic dunes as determined by tree-ring analysis of white spruce, Hudson Bay, Québec

The radial-growth patterns of white spruce were studied on a number of trees growing in subarctic dunes along the eastern coast of Hudson Bay to calculate the rates of accumulation, erosion, and migration of cold-climate sand dunes. The average rate of sand accumulation in sheltered dunes (forest sites) was 2.5 to 3.3 cm/yr, which is two to three times lower than in highly exposed dunes with a rate of sedimentation of 7.65 cm/yr. The average erosion rate was 1.4–1.7 cm/yr, about two times lower than the accumulation rate. The migration rate of sheltered dunes was 18 to 30 cm/yr, three to five times lower than for an exposed dune which advanced at a speed of 74 cm/yr. This migration rate established for highly exposed dunes in the Subarctic with tree-ring methods is about 10 times lower than that established for a barchan in the Sahara with other methods.     

Determination of Mercury in One Hundred and Sixteen Geological and Environmental Reference Materials Using a Direct Mercury Analyser

The mercury content of 116 reference materials (RMs) from ten international organisations was determined in this study, which focused on variability within and between batches of RMs. Direct mercury analysis (DMA) was applied to RMs having Hg contents between 1 and 6300 ng g^?1 and provided good precision and accuracy. Accuracy was demonstrated by the agreement of our results with certified values, while replicates were made to establish the precision. Low within‐batch variability was noted, with precision from 0.1 to 23% (n = 3–5) apparently depending on Hg content and homogeneity, whereas systematic offsets were detected among several batches. Thanks to the analysis of different batches; the homogeneity or heterogeneity of several RMs was shown, and thus, suitable RMs for quality control for Hg determinations could be recommended.