Thermochemistry and melting properties of basalt

The heat capacities of the liquid, glassy and crystalline phases of an alkali basalt have been determined from relative enthalpies measured between 400 and 1,800 K. Values given by available models of calculation generally agree to within 2% of these results. As derived from the new data and the enthalpy of vitrification measured at 973 K by oxide-melt drop solution calorimetry for the same sample, the enthalpy of fusion of this basalt increases from 15.4 kJ/mol at 1,000 K to 33.6 kJ/mol at 1,800 K. Comparisons between the enthalpies of fusion of basalt and model compositions confirm the small magnitude of the enthalpy of mixing between the molten mineral components of the liquids. Minor variations in the chemical composition have only a small effect in the heat capacity and the enthalpy of melting of basalt. The enthalpies of formation at 298 K from the oxides of the crystallized and glass phases of this alkali basalt are −112.2 and −98.5 kJ/mol, respectively, for a gram formula weight based on one mole of oxide components.     

Astronomical time scale for the Middle Oxfordian to Late Kimmeridgian in the Swiss and French Jura Mountains

Detailed investigation of facies and sedimentary structures reveals that, during the Middle Oxfordian to Late Kimmeridgian, the shallow carbonate platform of the Swiss and French Jura Mountains recorded high-frequency sea-level fluctuations quite faithfully. The cyclostratigraphic analysis within the established biostratigraphic and sequence-chronostratigraphic framework implies that the resulting hierarchically stacked depositional sequences formed in tune with the orbital cycles of precession (20 kyr) and eccentricity (100 and 400 kyr). The astronomical time scale presented here is based on the correlation of 19 platform sections and 4 hemipelagic sections from south-eastern France where good biostratigraphic control is available. The cyclostratigraphic interpretation suggests that the interval between sequence boundaries Ox4 and Kim1 (early Middle Oxfordian to earliest Kimmeridgian) lasted 3.2 myr and that the Kimmeridgian sensu gallico has a duration of 3.2 to 3.3 myr. The astronomical time scale proposed here is compared to time scales established by other authors in other regions and the discrepancies are discussed. Despite these discrepancies, there is a potential to estimate the durations of ammonite zones and depositional sequences more precisely and to better evaluate the rates of sedimentary, ecological and diagenetic processes. Editorial handling: Hanspeter Funk, Helmut Weissert, Stefan Bucher     

Garnet reequilibration and growth in the eclogite facies and geodynamical evolution near peak metamorphic conditions

Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe²⁺Mg⁻¹ exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a _H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe²⁺ and Mg. While these kinetic factors confine garnet reequilibration to Fe²⁺Mg⁻¹ exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates.     

Tethyan-to-boreal correlation in the Kimmeridgian using high-resolution sequence stratigraphy (Vocontian Basin,Swiss Jura,Boulonnais, Dorset)

Ammonite biostratigraphy plays a central role in the definition of Jurassic stratigraphy. Nevertheless, the strong provincialism of European ammonite species during the Kimmeridgian is a long-standing problem in correlation attempts between the boreal and Tethyan faunal realms. Moreover, the sequence-stratigraphic interpretations for northern and southern Europe given in the Jurassic chronostratigraphic chart of Hardenbol et al. in SEPM Publ. 60 (chart) (1998) are different. The present study aims to resolve this correlation problem in order to better understand the connections between the boreal and the Tethyan realms during the Kimmeridgian. A sedimentological and high-resolution sequence-stratigraphic interpretation is presented for two unpublished sections (Cras d’Hermont and Roche de Mars) in the northern Swiss Jura, where recently discovered ammonites display both boreal and Tethyan influences. Then, these sections are correlated with the same time interval in the central Swiss Jura and Vocontian Basin, which belong to the Tethyan realm. Lastly, a long-distance transect is constructed between the Vocontian Basin, Swiss Jura, northern France, and southern England, the last two areas being part of the sub-boreal realm. The main results of this work are that: (1) third-order depositional sequences, and also higher-frequency sequences, can be correlated from the Tethyan to the boreal realm; (2) the sequence-stratigraphic interpretation given by Hardenbol et al. in SEPM Publ 60 (chart) (1998) for northern Europe seems to be accurate and agrees with the sequence-stratigraphic framework established in the Swiss Jura; (3) the Late Kimmeridgian of the Swiss Jura displays boreal influences; (4) integrated high-resolution sequence-stratigraphic and cyclostratigraphic studies are a valuable approach for bridging the correlation gap between northern and southern Europe.     

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.     

A simplified approach for vulnerability assessment in moderate-to-low seismic hazard regions: application to Grenoble (France)

Due to the moderate seismic risks in France, the building vulnerability assessment methods developed for high seismic risk countries could not easily be used here because of their cost and the low-risk perception among the public and officials. A light vulnerability assessment method is proposed and tested in Grenoble (France), based on classes and scores provided in the GNDT method but simplified in terms of visual screening and number of structural parameters used. Compared to the RiskUE method, the damage obtained by our approach shows that 90% of buildings have residuals smaller than 0.2, i.e. one grade of the EMS98 damage scale. A large scale survey is devised and conducted among the inhabitants of Grenoble in order to collect the main structural parameters. By comparing the results from the survey to the historical urbanization of Grenoble and to expert surveys performed in two urban districts, the information useful for the light method of vulnerability assessment can be rapidly collected by non-experts reducing substantially the estimate cost. The average damage is then computed using the GNDT formula considering the probable intensities which could be observed in Grenoble (VII and VIII). The average damage reaches 0.4 in the oldest part of Grenoble mainly made of masonry buildings and 0.2 in reinforced concrete suburbs where reinforced concrete predominates. The results are a relative vulnerability assessment that provides useful initial information for the urban zones of Grenoble where the vulnerability is higher. This method can be used to classify the seismic vulnerability in wide seismic-prone regions to a fair degree of accuracy and at low cost.     

2D magnetic resonance tomography applied to karstic conduit imaging

Karstic conduits play a crucial role for water supply in many parts of the world. However, the imaging of such targets is generally a difficult task for most geophysical methods. Magnetic Resonance Sounding (MRS) is a geophysical method designed for imaging of water bearing structures. Initially, MRS was developed for characterizing horizontally stratified aquifers. However, when applying a 1D MRS measuring setup to the imaging of 2D–3D targets, the size of which may be much smaller than the loop, the accuracy and the lateral resolution may not be sufficient. We have studied the possibility of simultaneously processing several MRS aligned along a profile to perform a Magnetic Resonance Tomography (MRT). This work emphasizes the gain of resolution for 2D–3D imagery of MRT versus the interpolation of 1D inversion results of MRS along the same profile. Numerical modelling results show that the MRT response is sensitive to the size and location of the 2D target in the subsurface. Sensitivity studies reveal that by using the coincident transmitting/receiving (TX/RX) setup and shifting the loop around the anomaly area, the depth, section and position of a single karstic conduit with a size smaller than the MRS loop size can be resolved. The accuracy of the results depends on the noise level and signal level, the latter parameter being linked to the depth and volume of the karstic conduit and the water content in the limestone matrix. It was shown that when applying MRT to the localization of 2D anomalies such as karstic conduits, the inclination of the geomagnetic field, the orientation of the MRT profile and the angle of crossover of the conduit by the MRT profile must be taken into account. Otherwise additional errors in interpretation should be expected. A 2D inversion scheme was developed and tested. Both numerical and experimental results confirm the efficiency of the developed approach.     

Ground motion characterization and seismic hazard assessment in Spain: context,problems and recent developments

This article points out some particular features conditioning seismic hazard assessments (SHA) in Spain, a region with low–moderate seismicity. Although sized earthquakes occurred in the past, as evidenced by historical documents and neotectonic studies, no large events occurred during the last decades. The absence of strong motion records corresponding to earthquakes with magnitude larger than 5.5 is an important obstacle for the development of ground motion models constrained by local data, with the consequent difficulty in SHA studies. In this paper, some recent developments aiming at providing solutions to these difficulties are presented. Specifically, a strong motion databank containing a massive collection of accelerograms and response spectra from different configurations source-path-site corresponding to earthquakes all over the world is introduced, together with software utilities for its management. A first application of this databank is the development of specific ground motion models for Spain and for the Mediterranean region that predict peak ground accelerations as a function of several definitions of magnitude, distance and soil class. The predictive power of these ground motion models is tested by contrasting their estimates with recently recorded ground motions. The comparison between our ground-motion models with others proposed in the literature for other areas reveals a regular overestimation of the expected ground motions at Spanish sites by the non-local models. Consequently, SHA studies based in external models may overestimate the predicted hazard at the Iberian sites. In the last part of the paper a method for checking whether the response spectra proposed in the Spanish Building Code (NCSE-02) are consistent with actual accelerometric data from recent low magnitude earthquakes is applied. The spectral shapes of the Spanish Building Code NCSE-02 are compared with the response spectral shapes deduced from the available accelerograms by normalising the response spectra with the recorded PGA. It is appreciated that the NCSE-02 spectral shapes are exceeded by a large number of actual spectral shapes for short periods (around 0.2 s), a result to be taken into account in further revisions of the NCSE-02 code. The issues tackled in this work constitute not only an improvement for ground-motion characterisation in Spain, but also provide guidelines of general interest for potential applications in other regions with similar seismicity.