Chemical speciation of polycyclic aromatic hydrocarbons in sediments: Partitioning and extraction of humic substances

The primary objective of this study was to examine the chemical speciation of polycyclic aromatic hydrocarbons (PAHs) found in sediments endowed with different characteristics. To achieve this purpose and because the nature of the sediments influences the distribution of PAHs, we have analyzed four different types of sediments. To study the role of organic matter in the sequestration of PAHs, we fractionated humic substances into humic acids and humin-mineral fractions. After their separation and purification, the humic components were examined for their sorptive reactivity by extracting them with organic solvents; these extracts were subsequently subjected to GC/MS analysis. Our results show that PAHs are distributed between labile and sequestered fractions in sediments. A slower uptake of PAHs occurs when the sequestered fraction is formed, and this process can be prolonged and may be influenced by the characteristics if the sediment. Our study suggests that organic contaminants are available in muddy sediments for a longer period of time than in sandy sediments.     

Analysis of the reliability of a statistical oil spill response model

A statistical oil spill response model is developed and validated by means of actual oil slick observations reported during the Prestige accident and trajectories of drifter buoys. The model is based on the analysis of a database of hypothetical oil spill scenarios simulated by means of a Lagrangian transport model. To carry out the simulations, a re-analysis database consisting of 44-year hindcast dataset of wind and waves and climatologic daily mean surface currents is used. The number of scenarios required to obtain statistically reliable results is investigated, finding that 200 scenarios provide an optimal balance between the accuracy of the results and the computational effort. The reliability of the model was analyzed by comparing the actual data with the numerical results. The agreement found between actual and numerical data shows that the developed statistical oil spill model is a valuable tool to support spill response planning.     

Discrimination of Nuclear Explosions against Civilian Sources Based on Atmospheric Xenon Isotopic Activity Ratios

A global monitoring system for atmospheric xenon radioactivity is being established as part of the International Monitoring System that will verify compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT) once the treaty has entered into force. This paper studies isotopic activity ratios to support the interpretation of observed atmospheric concentrations of ¹³⁵Xe, ^133mXe, ¹³³Xe and ^131mXe. The goal is to distinguish nuclear explosion sources from civilian releases. Simulations of nuclear explosions and reactors, empirical data for both test and reactor releases as well as observations by measurement stations of the International Noble Gas Experiment (INGE) are used to provide a proof of concept for the isotopic ratio based method for source discrimination.     

Zero-stress,cylindrical wave functions around a circular underground tunnel in a flat,elastic half-space: Incident P-waves

The zero-stress boundary conditions at the surface of the half-space in the presence of surface and sub-surface cavities for in-plane, incident cylindrical P- and SV-waves have always posed challenging problems. The outgoing cylindrical P- and SV-waves can be represented by Hankel functions of radial distance coupled with the sine and cosine functions of angle. Together, at the half-space surface the P- and SV-wave functions are not orthogonal over the semi-infinite radial distance from 0 to infinity. Thus, to simultaneously satisfy the zero in-plane, normal, and shear stresses, an approximation of the geometry is often made. This paper presents an analytical formulation of the boundary-valued problem, where the Hankel wave functions are expressed in integral form, changing the representation from cylindrical to rectangular coordinates, so that the zero-stress boundary conditions at the half-space surface can be applied in a more straightforward way.     

New Methods for Modeling Laterolog Resistivity Corrections

The paper presents methods for laterolog response modeling. In Coulomb’s charges method, Laplace’s equation is solved for the electric field distribution in rock medium with internal boundaries between different resistivity layers. There, the boundary problem is reduced to Fred-holm integral equation of the second kind. The second method uses a finite element array to model apparent resistivity from laterolog. The task is treated as DC problem and the Laplace equation is solved numerically. The presented methods were applied to borehole data covering a typical stratigraphie section of the Fore-Sudetic Monocline in southwestern Poland. Apparent resistivity was calculated using the Coulomb’s charges method and alternatively modeled using a finite element method which gave similar results. Then, a series of linear corrections for borehole, shoulder bed, and filtration effects for apparent resistivity obtained by the Coulomb’s charges method demonstrated the feasibility of calculating true resistivity of virgin and invaded zones. The proposed methods provide a flexible solution in modeling which can be adapted to other logs.