Grain-size end-members and environmentally sensitive grain-size components: A comparative study in the mud shelf depocenters off southern Brazil

The current study aims to do a comparative analysis of the results obtained with two End-Member(EM)grain-size modeling techniques(AnalySize and BasEMMA)and the Environmental Sensitive Grain-Size(ESGS)modeling for sediment samples collected in the mudbelts of the southern Brazilian shelf.The methods were compared using grain-size data from the south Brazilian shelf,and the results are discussed here.It is the first time that the concept of ESGS,in its present form,is utilized outside China.The results show that despite its relative ease of use,the ESGS is not fully comparable to the EM analyses,and only two grain-size ESGS classes were recognized as analogous to EMs.The comparison of the AnalySize and BasEMMA procedures also revealed significant differences between the techniques.A comparative analysis between the two EM techniques revealed advantages in the BasEMMA,especially in the better correlation of the end-members with the original grain size distribution.The analysis of the geographical distribution of the EM abundances allowed point sources of sandy populations to be recognized as well as the contribution of the Rio de la Plata as a source of silty sediments to be inferred.     

Exposure of the clam Tapes philippinarum to 4-nonylphenol: changes in anti-oxidant enzyme activities and re-burrowing capability

The effects of 4-nonylphenol on anti-oxidant enzyme (superoxide dismutase and catalase) activity in both gills and digestive gland and re-burrowing capability of the clam Tapes philippinarum were investigated after 7 days' exposure to various sublethal concentrations of nonylphenol (NP). NP caused a significant decrease in superoxide dismutase activity in both tissues from the lowest concentration tested, whereas no significant alteration with respect to controls was observed in catalase activity. NP effects on re-burrowing of clams were evaluated in two experiments. In the first, clams exposed to the highest NP concentrations showed a marked delay in re-burrowing 48 h after the end of exposure. Modifications in normal burrowing behaviour were also observed, suggesting that NP acts via narcosis and/or neurotoxic mechanisms. In the second experiment, the elapsed time for 50% of the exposed clams to re-burrow into the sediment (RT(50)) was also calculated in a 24-h re-burrowing response test. At the highest NP concentrations, it was not possible to estimate RT(50) values, as the percentage of clams showing complete burial was less than 50%. The present study demonstrates that NP causes oxidative stress by inhibiting superoxide dismutase activity and greatly affects the re-burrowing capability of T. philippinarum, even at environmentally realistic concentrations.     

Assessing characteristics of Mediterranean explosive cyclones for different data resolution

A comparison of two objective climatologies of explosive cyclones in the Mediterranean region is performed. The results are derived from two different mean sea-level pressure reanalysis data resolutions, but from the same assimilation model, in order to quantify the pure impact of higher resolution on the identification and characteristics of explosive cyclones, when the assimilation model is the same. The explosive cyclones were identified with the aid of the Melbourne University automatic cyclone finding and tracking scheme over a 40-year period, using the 6-hourly analyses of ERA-40 mean sea-level pressure (MSLP) on: (a) 2.5?×?2.5 and (b) 1?×?1 latitude–longitude grid. The comparison of the two datasets revealed the significant role of the increase in spatial resolution of MSLP data on the identification and tracking process, and the number of the explosive cyclones in the high-resolution dataset is almost four times greater than the respective one in the lower resolution dataset. However, the comparison of explosive cyclone characteristics, including spatial and temporal variations of explosive deepening, revealed differences in the geographical distribution of the location of the maximum explosive deepening and average explosive cyclone Laplacian of the central pressure. These differences are due to the identification in the higher resolution set of smaller scale and secondary explosives along the strongly baroclinic northern Mediterranean boundaries, south of the Alps and the Pyrenees. Explosive deepening appears a bias to the daytime period from 12 to 18 Coordinated Universal Time (UTC) for both datasets, which is more prominent in the LR dataset. Statistically significant difference of pressure tendency between the two datasets appear for the daytime period from 06 to 12 UTC, accounting for better representation of orographic forcing in the HR dataset.     

Comparison of metal accumulation between 'Artificial Mussel' and natural mussels (Mytilus galloprovincialis) in marine environments

The passive sampler called 'Artificial Mussel' (AM) developed by Wu et al. (2007) can provide a time-integrated estimate of metal concentrations in the marine environment, and offers a potential device to assess and compare metal concentration in different marine environments worldwide. The aim of this study was to compare metal accumulation on AM and natural mussel Mytilus galloprovincialis at three sites with different metal loads along the Portuguese coast for four months. M. galloprovincialis were placed in cages alongside AMs at each site. Samples were collected monthly and Cd, Cr, Cu, Pb, and Zn concentrations in whole soft tissues and AMs compared. For both Cu and Cd, the results were similar between AMs and natural mussels. Higher concentrations of Zn were observed in natural mussels, whereas the inverse was shown for Pb (about 10-fold higher). Our results showed that AMs are promising tools for assessing metal concentrations in marine environments.     

Do seasonal changes in habitat features influence aquatic macroinvertebrate assemblages in perennial versus temporary Mediterranean streams?

In this study we examined the importance of seasonal changes in habitat features and aquatic macroinvertebrate responses in temporary and perennial streams from two different catchments in the Western Mediterranean region in Spain. Macroinvertebrate sampling was spatially intensive to account for the relative frequency of meso- (i.e., riffles and pools) and micro-habitats (i.e., different mineral and organic-based substrata) at each site. Samples were collected at two distinctly different phases of the hydrograph: (1) during the flowing period, when pool-riffle sequences were well-established, and (2) during the dry phase, when only isolated pools were expected to occur in the temporary streams. During the dry season, both a reduction in the available total habitat and in microhabitat diversity in all sites studied was observed. As a result, taxon richness decreased in all streams, but more dramatically at temporary stream sites and particularly so in the infrequently remaining discontinuous riffles. Macroinvertebrate assemblages differed among catchments (i.e., geographical identity) and sites (perennial vs. temporary). Invertebrate differences were also strong within and among meso- and micro-habitats, particularly mineral and organic microhabitat patches, and differences were due to both loss of taxa from some habitats and some taxa exhibiting certain habitat affinities.     

Peculiar earthquake damage on a reinforced concrete building in San Gregorio (L��Aquila, Italy): site effects or building defects?

In San Gregorio (L’Aquila, Italy) a three-story, reinforced concrete (RC) building had the first floor collapsed following the earthquake of April 6, 2009. The remaining two stories fell with a displacement in the horizontal projection of about 70 cm. This unusual behaviour is made more puzzling by the fact that buildings located at a short distance and with similar features had little or no damage reported. To understand the causes of the collapse we performed strong motion recordings, microtremor measurements, a detailed geological survey, a high-resolution geo-electrical tomography, a borehole with a down-hole test. On the building we performed a geometrical survey and laboratory tests on concrete cores. The acceleration and noise recordings have shown a high amplification with uphill-downhill direction. The geological survey has revealed the presence of co-seismic fractures on stiff soils. Geo-electrical tomography has shown an unexpected, strong discontinuity just below the building. Taking advantage of excavations in adjacent lots, we have highlighted rare cataclastic decimetric bands with a very low resistance material incorporated in well-stratified calcarenites. The same soft material has been founded in the borehole down to 17 m from ground level, showing a shear wave velocity that starts at 250 m/s, increases with depth and has an abrupt transition in calcarenites at 1,150 m/s. The surface geophysical measurements in the vicinity of the site have not shown similar situations, with flat HVSR curves as expected for a rock outcrop, except for a lateral extension of the soft zone. The analysis on the quality of the building materials has yielded values higher than average for the age and type of construction, and no special design or construction deficiencies have been observed. A strong, peculiar site effect thus appears to be the most likely cause of the damage observed.     

Pesticide Pollution in Surface‐ and Groundwater by Paddy Rice Cultivation: A Case Study from Northern Vietnam

This study was designed to examine the environmental exposure of surface‐ and groundwater pollution in remote mountainous regions of northern Vietnam. In 2008, we monitored the loss of four commonly applied pesticides (imidacloprid, fenitrothion, fenobucarb, dichlorvos) from paddy rice farming systems to a receiving stream on the watershed scale and quantified groundwater pollution. For the entire monitoring period, runoff loss of pesticides from the watershed was estimated to range between 0.4% (dichlorvos) and 16% (fenitrothion) of the total applied mass. These losses were correlated well with the octanol–water partition coefficient and water solubility of pesticides (r² = 0.78–0.99). In the groundwater collected from eight wells, all target pesticides were frequently detected. Maximum measured concentrations were 0.47, 0.22, 0.17, and 0.07 µg L^?1 for fenitrothion, imidacloprid, fenobucarb, and dichlorvos, respectively. Our results strongly indicate that under the current management practice pesticide use in paddy fields poses a serious environmental problem in mountainous regions of northern Vietnam.     

Synchrotron-based X-ray study of iron oxide transformations in terraces from the Tinto-Odiel river system: Influence on arsenic mobility

Simultaneous analysis of micro-X-ray diffraction (μ-XRD) and micro-X-ray fluorescence (μ-XRF) based on synchrotron light sources, and electron microprobe (EMP) analyses, were performed on iron terrace samples taken from Tinto-Odiel river system from the Iberian Pyrite Belt (IBP, SW Iberian Peninsula). Iron terraces are formed during the oxidation and precipitation of dissolved iron along the riverbeds impacted by acid mine drainage (AMD). This paper includes the study of actively-forming current terraces and fossil terraces isolated from the stream courses due to the river migration over time. The results of the study of current terrace samples from AMD-affected streams of two IPB abandoned mines (Tinto Santa Rosa and Cueva de la Mora) showed that fresh precipitates at the surface are composed primarily of metastable schwertmannite, which is gradually transformed at depth over short-time scales into goethite. Sediments of ancient terraces are composed mainly of goethite, which most likely originated from the re-crystallization of a precursor schwertmannite. However, at century-time scale, goethite partially re-crystallizes to hematite due to diagenetic processes. The transformation rate of goethite into hematite is negatively correlated with grain size and the crystallinity of goethite. Moreover, this transformation is accompanied by an increase in grain size and a decrease in surface area of hematite, and a concomitant decrease in arsenic trapped in the solid. This increase in the arsenic mobility during the diagenetic maturation should be considered in the development of conceptual and analytical models describing long-term fate, transport and bioavailability of arsenic in environmental systems.     

Vessel biofouling as an inadvertent vector of benthic invertebrates occurring in Brazil

This article reviews the literature involving benthic invertebrates that are cited in association with hull fouling, reporting the species that occur on the Brazilian coast and evaluating the importance of this vector for the introduction of nonindigenous and cryptogenic invertebrates in Brazil. It discusses some of the strategies that were used by the species that allowed for their overseas transport and made it easier to cross natural barriers that otherwise would have been obstacles to their dispersion. The compiled data list 343 species (65% nonindigenous and 35% cryptogenic), mainly from the northwestern Atlantic Ocean. The traveling fauna, composed mostly of cosmopolitan species (70.3%), is primarily euryhaline and marine stenohaline, with sessile and sedentary habits. After delineating the shipborne species’ ecological profiles and traveling strategies and evaluating their overlapping vectors, we concluded that hull vessels were the main vector of introduction to the Brazilian coast for 89.8% of the compiled species.