Illite authigenesis in sandstones of the Guaritas Allogroup (Early Paleozoic): Implications for the depositional age,stratigraphy and evolution of the Camaquã Basin (Southern Brazil)

Several analytical studies performed on alluvial-eolian sandstones of the Early Paleozoic Guaritas Allogroup (Camaquã Basin, southern Brazil) indicate illite to be abundant, showing different morphologies as authigenic grain rims and pore-bridging filaments. Authigenic illite separates of variable grain sizes from distinct stratigraphic intervals of the Guaritas Allogroup yielded ⁴⁰K–⁴⁰Ar ages from 521.7 ± 10.3 to 473.7 ± 9.4 Ma. These ages, interpreted to record the timing of illite authigenesis, are coincident with the age of emplacement of the Rodeio Velho andesites (470 ± 19 Ma). Moreover, field structures suggest interaction between hot, andesite lava flows and wet, poorly consolidated sediments of the Pedra Pintada Alloformation (lower strata of the Guaritas Allogroup). This set of data indicates that the Rodeio Velho volcanism could have been responsible for a widespread remobilization of interstitial fluids and consequent authigenic illite precipitation in the sandstones of the Guaritas Allogroup.     

Modelling the effects of changes in rainfall event characteristics on TSS loads in urban runoff

The effect of changes in rainfall event characteristics on urban stormwater quality, which was described by total suspended solids (TSS), was studied by means of computer simulations conducted with the Storm Water Management Model for a climate change scenario for northern Sweden. The simulation results showed that TSS event loads depended mainly on rainfall depth and intensity, but not on antecedent conditions. Storms with low‐to‐intermediate depths and intensities showed the highest sensitivity to changes in rainfall input, both for percentage and absolute changes in TSS wash‐off loads, which was explained by the contribution of pervious areas and supply limitations. This has significant implications for stormwater management, because those relatively frequent events generally carry a high percentage of the annual pollutant load. Copyright © 2013 John Wiley & Sons, Ltd.     

State-of-the-art overview of the Loess Palaeolithic of Poland

In Poland, loess mainly occurs in the southern part of the country, in the Polish Uplands, and on the northern foreland of the Sudetes and the Carpathians. Most of these sediments come from the time of the last glaciation–the Vistulian (Weichselian) glaciation. Thin covers of loess from the penultimate glaciation have been preserved in Upper Silesia. Only a few sites from the Middle Palaeolithic remain in the loess. In the eastern part of Poland loess creates profiles several metres high. Discoveries in this zone represent the cultural sequence from the transition from the Middle to Upper Palaeolithic. We know more traces of various cultures from the Upper Palaeolithic exist. The study attempts to synchronise profiles from selected archaeological open-air sites, outlines of the history of research on loess sites, and attempts to explain terminological and conceptual issues. The issue of loess in the cave site profiles will not be discussed in the article.     

Benchmarking sustainability in cities: The role of indicators and future scenarios

Scenarios are a useful tool to help think about and visualise the future and, as such, are utilised by many policymakers and practitioners. Future scenarios have not been used to explore the urban context in much depth, yet have the potential to provide valuable insights into the robustness of decisions being made today in the name of sustainability. As part of a major research project entitled Urban Futures, a toolkit has been developed in the UK to facilitate the use of scenarios in any urban context and at any scale relevant to that context. The toolkit comprises two key components, namely, (i) a series of indicators comprising both generic and topic area-specific indicators (e.g., air quality, biodiversity, density, water) that measure sustainability performance and (ii) a list of characteristics (i.e., 1–2-sentence statements about a feature, issue or small set of issues) that describe four future scenarios. In combination, these two components enable us to measure the performance of any given sustainability indicator, and establish the relative sensitivity or vulnerability of that indicator to the different future scenarios. An important aspect of the methodology underpinning the toolkit is that it is flexible enough to incorporate new scenarios, characteristics and indicators, thereby allowing the long-term performance of our urban environments to be considered in the broadest possible sense.     

Plankton copper requirements and uptake in the subarctic Northeast Pacific Ocean

We undertook the first measurements of metabolic Cu requirements (net Cu:C assimilation ratios) and steady-state Cu uptake rates (ρCu_ss) of natural plankton assemblages in the northeast subarctic Pacific using the short-lived radioisotope ⁶⁷Cu. Size-fractionated net Cu:C assimilation ratios varied ～3 fold (1.35–4.21 μmol Cu mol C^?1) among the stations along Line P, from high Fe coastal waters to the Fe-limited open ocean. The variability in Cu:C was comparable to biogenic Fe:C ratios in this region. As previously observed for Fe uptake, the bacterial size class accounted for half of the total particulate ρCu_ss. Interestingly, carbon biomass-normalized rates of Fe uptake from the siderophore desferrioxamine B (DFB) (ρFe_DFB; a physiological proxy for Fe-limitation) by the >20 μm size class were positively correlated with the intracellular net Cu:C assimilation ratios in this size class, suggesting that intracellular Cu requirements for large phytoplankton respond to increased Fe-limitation. At Fe-limited Ocean Station Papa (OSP), we performed short-term Cu uptake (ρCu_L) assays to determine the relative bioavailability of Cu bound to natural and synthetic ligands. Like the volumetric ρCu_ss measured along Line P, the bacterial size class was responsible for at least 50% of the total ρCu_L. Uptake rates of Cu from the various organic complexes suggest that Cu uptake was controlled by the oxidation state of the metal and by the metal:ligand concentration ratio, rather than the concentration of inorganic species of Cu in solution. Collectively, these data suggest that Cu likely plays an important role in the physiology of natural plankton communities beyond the toxicological effects studied previously.     

Effects of detrital carbonate on stable oxygen and carbon isotope data from varved sediments of the interglacial Piànico palaeolake (Southern Alps,Italy)

Contamination with detrital matter is a well‐known bias in δ¹⁸O records from lake carbonates but quantitative information of this effect is yet lacking. Therefore, we developed a new methodological approach combining isotope analyses with microfacies, X‐ray diffraction and micro‐X‐ray fluorescence data and applied this in a case study for the Piànico interglacial lake record in order to provide a quantitative estimate of the effect of detrital carbonate on stable δ¹⁸O and δ¹³C data. The Piànico record contains a long series of distinct and well‐preserved calcite varves and is correlated to Marine Isotope Stage 11. Intercalated in the varve sequence are detrital layers triggered by surface erosion events. These detrital layers are mainly composed of dolomite, thus reflecting the mineralogical signature of the catchment. Microfacies analyses of a 9350 varve year interval allows the identification of detrital layers down to sub‐millimetre scale and a precise selection of three different types of samples for isotope analyses: (1) pure endogenic calcite varves (five varves per sample) without detrital contamination; (2) individual detrital layers; and (3) ‘mixed’ samples including five calcite varves and up to four thin detrital layers. Detrital samples show the isotopic signature of the catchment dolomite and are up to 5.7‰ enriched in δ¹⁸O values with respect to endogenic calcite samples. In mixed samples, the degree of isotopic enrichment is directly related to the amount of detrital contamination; δ¹⁸O of bulk carbonates is significantly biased when the detrital component amounts to more than 5% of the sample. It is also shown that samples containing detrital material have an influence on the calculation of the covariance between δ¹³C and δ¹⁸O. Covariance is high (r = 0.76) when the correlation coefficient is calculated on the base of all samples, but absent (r = ?0.43) when samples containing detrital dolomite are excluded. It has been demonstrated that microfacies analysis is a quick tool to avoid or reduce detrital contamination in bulk carbonate samples during sample selection. Copyright © 2009 John Wiley & Sons, Ltd.     

Quaternary palaeoenvironments and multi-storey valley fill architecture along the Mezen and Severnaya Dvina river valleys,Arkhangelsk region,NW Russia

The modern Severnaya Dvina and Mezen river systems in the Arkhangelsk region, NW Russia, are located within extensive palaeovalley systems. The palaeovalleys form depressions in bedrock and have controlled the drainage systems in the area at least since the Last Interglacial. Vertically stacked marine to fluvial sediments reflect deposition during fluctuating climate and sea levels.A compilation of lithostratigraphical data collected during the last decade has been coupled with bedrock topography and geomorphology from satellite images in order to describe the valley fill architecture for the two valley systems. Each system has been divided into a number of depositional units (storeys) separated by incision/non-deposition and used to investigate the timing of aggradational versus incisional phases. Time constraints for each phase are provided by optically stimulated luminescence (OSL) ages, and aggradation and incision are linked to independent records of climate and sea level change.The pattern of aggradation and erosion is regional and primarily driven by episodes of increasing and decreasing sediment supply. Aggradation is correlated to times of deglaciation with high sediment supply from the ice margin, release of sediment from ice-dammed lakes and low vegetation and degradation of permafrost on the flood plain. Incision is related to cold intervals with low sediment supply, delayed incision due to isostatic uplift and drainage of ice-dammed lakes. Relative sea level change controls the distribution of marine deposits, which show significant regional variations due to variable isostatic response across the region. Sea level change plays a limited role for fluvial aggradation/incision in the study area.