The Lateglacial and Holocene in Central Europe: a multi‐proxy environmental record from the Bohemian Forest,Czech Republic

The Hercynian mountain ranges were islands of mountain glaciation and alpine tundra in a Central European ice‐free corridor during the Late Pleistocene. Today they are notable areas of glacial landforms, alpine‐forest free areas, peatlands and woodlands. However, our knowledge of the Lateglacial and early Holocene environmental changes in this region is limited. We present a new multi‐proxy reconstruction of a mid‐altitude environment in the Bohemian Forest spanning this period. A core (5.2 m length) in the ?erné Lake cirque (1028 m a.s.l.) was subjected to lithological, geochemical, pollen and macrofossil analysis supplemented by two optically stimulated luminescence (OSL) and 10 AMS radiocarbon dates. We determined the impact of regional and supraregional climate changes on the environment. The two most significant changes in sedimentation during the Lateglacial (17.6 and 15.8–15.5 cal. ka BP) were synchronous with regional glacial chronostratigraphy. Unlike Central European mountain ranges, in the Bohemian Forest the Younger Dryas was not coincident with glacier re‐advance, but was a dry, cold episode with low lake levels, which prevailed until the early Preboreal. Plant macrofossils indicate local establishment of Betula nana and Betula pendula/pubescens at 15.4–13.4 cal. ka BP. Comparison with Holocene records from Central Europe shows a similar immigration history of vegetation at mid and higher altitudes. The tree line exceeded an altitude of ~1000 m a.s.l. around 10.5 cal. ka BP and coincided with rapid geochemical changes in the sediment. The 8.2 ka BP event did not have any response in the sedimentary record, but corresponded to stabilization of the Picea abies population and expansion of Fagus. Fagus colonized the Bohemian Forest earlier than other Hercynian mid‐mountains, but never predominated in the composition of the forest at higher elevations. Abies alba was the last tree species that immigrated to the study area.     

Nowcasting sunshine number using logistic modeling

In this paper, we present a formalized approach to statistical modeling of the sunshine number, binary indicator of whether the Sun is covered by clouds introduced previously by Badescu (Theor Appl Climatol 72:127–136, 2002). Our statistical approach is based on Markov chain and logistic regression and yields fully specified probability models that are relatively easily identified (and their unknown parameters estimated) from a set of empirical data (observed sunshine number and sunshine stability number series). We discuss general structure of the model and its advantages, demonstrate its performance on real data and compare its results to classical ARIMA approach as to a competitor. Since the model parameters have clear interpretation, we also illustrate how, e.g., their inter-seasonal stability can be tested. We conclude with an outlook to future developments oriented to construction of models allowing for practically desirable smooth transition between data observed with different frequencies and with a short discussion of technical problems that such a goal brings.     

Carbon and oxygen isotopic composition and foraminifers of condensed basal Zechstein (Upper Permian) strata in western Poland: environmental and stratigraphic implications

The basinal facies of the Lopingian Zechstein Limestone in SW Poland consists of thin (often less than 1 m thick) limestones and/or dolomites, often containing the Kupferschiefer (few tens of centimetres thick) at their base, and local thick (up to 90 m) reefal carbonates. The δ¹³C curve of these basal Zechstein deposits strongly suggests that even when the Kupferschiefer is lacking, the thin (condensed) sequences record the entire interval of the Zechstein prior to the onset of evaporite deposition, in contrast to the thick reef sequences which lack the characteristic δ¹³C curve for the lowermost part of the Zechstein. The calcite samples show considerable ranges of δ¹⁸O values. If the maximum δ¹⁸O values are considered to be the closest to the pristine original ones and if δ¹⁸O_water value = 0 is assumed, then the calculated range of palaeotemperatures for the Kupferschiefer and Zechstein Limestone calcite ranges from 19 to 34 °C. The faunal restriction, common dwarf foraminifers and the predominance of lagenids in the foraminiferal assemblage indicate continual dysaerobic conditions and possibly elevated salinity of seawater during deposition of thin basinal Zechstein Limestone deposits. The mixing of shallow and deeper waters in the stratified Zechstein Basin caused by upwelling could result in prolific carbonate precipitation in reefs located at the slope of the marginal carbonate platform of the Zechstein Limestone and in isolated reefs related to palaeohighs within the basin; however, there is no isotopic record of eventual upwelling. Copyright © 2014 John Wiley & Sons, Ltd.     

The Košice meteorite fall: Recovery and strewn field

We provide the circumstances and details of the fireball observation, search expeditions, recovery, strewn field, and physical characteristics of the Ko?ice meteorite that fell in Slovakia on February 28, 2010. The meteorite was only the 15th case of an observed bolide with a recovered mass and subsequent orbit determination. Despite multiple eyewitness reports of the bolide, only three videos from security cameras in Hungary were used for the strewn field determination and orbit computation. Multiple expeditions of professionals and individual searchers found 218 fragments with total weight of 11.3 kg. The strewn field with the size of 5 × 3 km is characterized with respect to the space distribution of the fragments, their mass and size‐frequency distribution. This work describes a catalog of 78 fragments, mass, size, volume, fusion crust, names of discoverers, geographic location, and time of discovery, which represents the most complex study of a fresh meteorite fall. From the analytical results, we classified the Ko?ice meteorite as an ordinary H5 chondrite.     

Ruthenium in komatiitic chromite

The distinction between Ru in solid solution and Ru-bearing inclusions is essential for the predictive modeling of platinum-group element (PGE) geochemistry in applications such as the lithogeochemical exploration for magmatic sulfide deposits in komatiites. This study investigates the role of chromite in the fractionation of Ru in ultramafic melts by analyzing chromite grains from sulfide-undersaturated komatiites and a komatiitic basalt from the Yilgarn Craton in Western Australia. In situ analysis using laser ablation ICP-MS yields uniform Ru concentrations in chromites both within-grain and on a sample scale, with concentrations between 220 and 540 ppb. All other platinum-group elements are below the detection limit of the laser ablation ICP-MS analysis. Carius tube digestion isotope dilution ICP-MS analysis of chromite concentrates confirms the accuracy of the in-situ method. Time resolved laser ablation ICP-MS analyses have identified the presence of sub-micron Ir-bearing inclusions in some chromite grains from the komatiitic basalt. However, Ru-bearing inclusions have not been recognized in the analyzed chromites and this combined with the in situ data suggests that Ru exists in solid solution in the crystal lattice of chromite. These results show that chromite can control the fractionation and concentration of Ru in ultramafic systems.     

Hydrologic and geologic factors controlling groundwater geochemistry in the Turonian aquifer (southern Tunisia)

Water in the fissured limestone and dolomite of the Turonian aquifer of Tunisia has been investigated using geochemical (major ions) and isotopic (δ¹⁸O, δ²H, ¹⁴C) data. To carry out a characterization of aquifer behaviour, 48 representative samples were collected at the end of the humid season. The evolution of chemical composition of groundwater from recharge areas to discharge areas is characterized by increasing sodium, chloride and sulphate contents as a result of leaching of evaporite rock. In the study, three distinct chemical trends in groundwater were identified. The major reactions responsible for the chemical evolution of groundwater in the investigated area fall into three categories: (1) calcite precipitation, (2) gypsum and halite dissolution, and (3) ion exchange. The stable isotope composition of water samples indicates large-scale interaction between the Continental Intercalaire and the Turonian aquifer and the presence of a young local component which probably enters the system via faults and/or fractures.     

Implications of tectonic subsidence models for crustal structure beneath the Mid-Polish Trough

Summary Tectonic subsidence analysis of the preserved and reconstructed stratigraphy of the Polish Basin indicates an initial Late Permian-Early Triassic (255-241 Ma) syn-rift phase of development with a subsequent extensional rejuvenation during the Late Jurassic (ca. 157-152 Ma). Forward modelling of the subsidence data, in view of existing geophysical interpretations which show the presence of a deep Moho and a very high seismic velocity lower crustal layer beneath the Mid-Polish Trough (MPT), suggest that Permo-Mesozoic basin development may be related at least in part to the intrusion of mantle material into and densification of the lower crust rather than exclusively to crustal extension and thinning.     

Solving the kriging problem by using the Gram-Schmidt orthogonalization

This paper presents an approach to solve the kriging problem, defined in terms of projections, by using Gram-Schmidt orthogonalization. The Gram-Schmidt orthogonalization allows us to find an optimal approximationY* in then-dimensional subspaceH _n of any vectorY element of a Hilbert spaceH. This approach requiresO(n ³) multiplication operations to obtain an orthogonal basis, andO(n ²) multiplications needed to calculate kriging solution for a given point.