Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ‐INTIMATE project)

It is widely recognised that the acquisition of high‐resolution palaeoclimate records from southern mid‐latitude sites is essential for establishing a coherent picture of inter‐hemispheric climate change and for better understanding of the role of Antarctic climate dynamics in the global climate system. New Zealand is considered to be a sensitive monitor of climate change because it is one of a few sizeable landmasses in the Southern Hemisphere westerly circulation zone, a critical transition zone between subtropical and Antarctic influences. New Zealand has mountainous axial ranges that amplify the climate signals and, consequently, the environmental gradients are highly sensitive to subtle changes in atmospheric and oceanic conditions. Since 1995, INTIMATE has, through a series of international workshops, sought ways to improve procedures for establishing the precise ages of climate events, and to correlate them with high precision, for the last 30 000 calendar years. The NZ‐INTIMATE project commenced in late 2003, and has involved virtually the entire New Zealand palaeoclimate community. Its aim is to develop an event stratigraphy for the New Zealand region over the past 30 000 years, and to reconcile these events against the established climatostratigraphy of the last glacial cycle which has largely been developed from Northern Hemisphere records (e.g. Last Glacial Maximum (LGM), Termination I, Younger Dryas). An initial outcome of NZ‐INTIMATE has been the identification of a series of well‐dated, high‐resolution onshore and offshore proxy records from a variety of latitudes and elevations on a common calendar timescale from 30 000 cal. yr BP to the present day. High‐resolution records for the last glacial coldest period (LGCP) (including the LGM sensu stricto) and last glacial–interglacial transition (LGIT) from Auckland maars, Kaipo and Otamangakau wetlands on eastern and central North Island, marine core MD97‐2121 east of southern North Island, speleothems on northwest South Island, Okarito wetland on southwestern South Island, are presented. Discontinuous (fragmentary) records comprising compilations of glacial sequences, fluvial sequences, loess accumulation, and aeolian quartz accumulation in an andesitic terrain are described. Comparisons with ice‐core records from Antarctica (EPICA Dome C) and Greenland (GISP2) are discussed. A major advantage immediately evident from these records apart from the speleothem record, is that they are linked precisely by one or more tephra layers. Based on these New Zealand terrestrial and marine records, a reasonably coherent, regionally applicable, sequence of climatically linked stratigraphic events over the past 30 000 cal. yr is emerging. Three major climate events are recognised: (1) LGCP beginning at ca. 28 000 cal. yr BP, ending at Termination I, ca. 18 000 cal. yr BP, and including a warmer and more variable phase between ca. 27 000 and 21 000 cal. yr BP, (2) LGIT between ca. 18 000 and 11 600 cal. yr BP, including a Lateglacial warm period from ca. 14 800 to 13 500 cal. yr BP and a Lateglacial climate reversal between ca. 13 500 and 11 600 cal. yr BP, and (3) Holocene interglacial conditions, with two phases of greatest warmth between ca. 11 600 and 10 800 cal. yr BP and from ca. 6 800 to 6 500 cal. yr BP. Some key boundaries coincide with volcanic tephras. Copyright © 2007 John Wiley & Sons, Ltd.     

Effect of bed surface roughness on longitudinal dispersion in artificial open channels

In several empirical and modelling studies on river hydraulics, dispersion was negatively correlated to surface roughness. In this study, it was aimed to investigate the influence of surface roughness on longitudinal dispersion under controlled conditions. In artificial flow channels with a length of 104 m, tracer experiments with variations in channel bed material were performed. By use of measured tracer breakthrough curves, average flow velocity, mean longitudinal dispersion, and mean longitudinal dispersivity were calculated. Longitudinal dispersion coefficients ranged from 0·018 m² s^?1 in channels with smooth bed surface up to 0·209 m² s^?1 in channels with coarse gravel as bed material. Longitudinal dispersion was linearly related to mean flow velocity. Accordingly, longitudinal dispersivities ranged between 0·152 ± 0·017 m in channels with smooth bed surface and 0·584 ± 0·015 m in identical channels with a coarse gravel substrate. Grain size and surface roughness of the channel bed were found to correlate positively to longitudinal dispersion. This finding contradicts several existing relations between surface roughness and dispersion. Future studies should include further variation in surface roughness to derive a better‐founded empirical equation forecasting longitudinal dispersion from surface roughness. Copyright © 2011 John Wiley & Sons, Ltd.     

Formation of Zn–Ca phyllomanganate nanoparticles in grass roots

It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere.     

Sediment budget-based estimates of trace metal inputs to a Chesapeake estuary

This article evaluates whether a sediment budget for the South River, Maryland, can be coupled with metals data from sediment cores to identify and quantify sources of historic metal inputs to marsh and subtidal sediments along the estuary. Metal inputs to estuarine marsh sediments come from fluvial runoff and atmospheric deposition. Metal inputs to subtidal sediments come from atmospheric deposition, fluvial runoff, coastal erosion, and estuarine waters. The metals budget for the estuary indicates that metal inputs from coastal erosion have remained relatively constant since 1840. Historical variations in metal contents of marsh sediments have probably resulted primarily from increasing atmospheric deposition in this century, but prior to 1900 may reflect changing fluvial sources, atmospheric inputs, or factors not quantified by the budget. Residual Pb, Cu, and Zn in the marsh sediments not accounted for by fluvial inputs was low to moderate in 1840, decreased to near zero circa 1910, and by 1987 had increased to levels that were one to ten times greater than those of 1840. Sources of variability in subtidal cores could not be clearly discerned because of geochemical fluxes, turbulent mixing, and bioturbation within the cores. The sediment-metal budgeting approach appears to be a viable method for delineating metal sources in small, relatively simple estuarine systems like the South River and in systems where recent deposition (for example, prograding marshes) prevents use of deep core analysis to identify background levels of metal. In larger systems or systems with more variable sources of sediment and metal input, however, assumptions and measurement errors in the metal budgeting approach suggest that deep core analysis and normalization techniques are probably preferable for identifying anthropogenic impacts.Field and laboratory research conducted at the Department of Geography, University of Maryland, College Park, Maryland, 20742, USAField and laboratory research conducted at the Marine and Estuarine Environmental Science Program, University of Maryland, College Park, Maryland, 20742, USA     

Latest Pleistocene and Holocene glacier variations in the European Alps

In the Alps, climatic conditions reflected in glacier and rock glacier activity in the earliest Holocene show a strong affinity to conditions in the latest Pleistocene (Younger Dryas). Glacier advances in the Alps related to Younger Dryas cooling led to the deposition of Egesen stadial moraines. Egesen stadial moraines can be divided into three or in some cases even more phases (sub-stadials). Moraines of the earliest and most extended advance, the Egesen maximum, stabilized at 12.2 ± 1.0 ka based on ¹⁰Be exposure dating at the Schönferwall (Tyrol, Austria) and the Julier Pass-outer moraine (Switzerland). Final stabilization of moraines at the end of the Egesen stadial was at 11.3 ± 0.9 ka as shown by ¹⁰Be data from four sites across the Alps. From west to east the sites are Piano del Praiet (northwestern Italy), Grosser Aletschgletscher (central Switzerland), Julier Pass-inner moraine (eastern Switzerland), and Val Viola (northeastern Italy). There is excellent agreement of the ¹⁰Be ages from the four sites. In the earliest Holocene, glaciers in the northernmost mountain ranges advanced at around 10.8 ± 1.1 ka as shown by ¹⁰Be data from the Kartell site (northern Tyrol, Austria). In more sheltered, drier regions rock glacier activity dominated as shown, for example, at Julier Pass and Larstig valley (Tyrol, Austria). New ¹⁰Be dates presented here for two rock glaciers in Larstig valley indicate final stabilization no later than 10.5 ± 0.8 ka. Based on this data, we conclude the earliest Holocene (between 11.6 and about 10.5 ka) was still strongly affected by the cold climatic conditions of the Younger Dryas and the Preboreal oscillation, with the intervening warming phase having had the effect of rapid downwasting of Egesen glaciers. At or slightly before 10.5 ka rapid shrinkage of glaciers to a size smaller than their late 20th century size reflects markedly warmer and possibly also drier climate. Between about 10.5 ka and 3.3 ka conditions in the Alps were not conducive to significant glacier expansion except possibly during rare brief intervals. Past tree-line data from Kaunertal (Tyrol, Austria) in concert with radiocarbon and dendrochronologically dated wood fragments found recently in the glacier forefields in both the Swiss and Austrian Alps points to long periods during the Holocene when glaciers were smaller than they were during the late 20th century. Equilibrium line altitudes (ELA) were about 200 m higher than they are today and about 300 m higher in comparison to Little Ice Age (LIA) ELAs. The Larstig rock glacier site we dated with ¹⁰Be is the type area for a postulated mid-Holocene cold period called the Larstig oscillation (presumed age about 7.0 ka). Our data point to final stabilization of those rock glaciers in the earliest Holocene and not in the middle Holocene. The combined data indicate there was no time window in the middle Holocene long enough for rock glaciers of the size and at the elevation of the Larstig site to have formed. During the short infrequent cold oscillations between 10.5 and 3.3 ka small glaciers (less than several km²) may have advanced to close to their LIA dimensions. Overall, the cold periods were just too short for large glaciers to advance. After 3.3 ka, climate conditions became generally colder and warm periods were brief and less frequent. Large glaciers (for example Grosser Aletschgletscher) advanced markedly at 3.0–2.6 ka, around 600 AD and during the LIA. Glaciers in the Alps attained their LIA maximum extents in the 14th, 17th, and 19th centuries, with most reaching their greatest LIA extent in the final 1850/1860 AD advance.     

Investigating groundwater flow components in an Alpine relict rock glacier (Austria) using a numerical model

Relict rock glaciers are complex hydrogeological systems that might act as relevant groundwater storages; therefore, the discharge behavior of these alpine landforms needs to be better understood. Hydrogeological and geophysical investigations at a relict rock glacier in the Niedere Tauern Range (Austria) reveal a slow and fast flow component that appear to be related to the heterogeneous structure of the aquifer. A numerical groundwater flow model was used to indicate the influence of important internal structures such as layering, preferential flow paths and aquifer-base topography. Discharge dynamics can be reproduced reasonably by both introducing layers of strongly different hydraulic conductivities or by a network of highly conductive channels within a low-conductivity zone. Moreover, the topography of the aquifer base influences the discharge dynamics, which can be observed particularly in simply structured aquifers. Hydraulic conductivity differences of three orders of magnitude are required to account for the observed discharge behavior: a highly conductive layer and/or channel network controlling the fast and flashy spring responses to recharge events, as opposed to less conductive sediment accumulations sustaining the long-term base flow. The results show that the hydraulic behavior of this relict rock glacier and likely that of others can be adequately represented by two aquifer components. However, the attempt to characterize the two components by inverse modeling results in ambiguity of internal structures when solely discharge data are available.     

Leaching and differential recrystallization of metamict zircon under experimental hydrothermal conditions

We report results of hydrothermal experiments on four alluvial zircons from Sri Lanka, which cover a wide range of radiation damage, at 450 °C and 1.3 kbar for 744 h with 2 M CaCl₂ solution as reactive fluid. After the hydrothermal treatment, the most metamict samples show micrometer-thick reaction rims, which surround apparently unreacted zircon, as revealed by cathodoluminescence (CL) and Nomarski differential interference contrast (NDIC) images. These rims have sharp, curved, and transgressive boundaries with unreacted zircon and are, in some cases, spread out along cracks. The thickness of reaction rims increases with increasing cumulated !-dosage of the starting materials. The reaction rims are strongly enriched in Ca (up to 7000 ppm) and a water species and depleted in radiogenic Pb, Zr, and Si, as revealed by electron microprobe analyses. A significant Th loss from the reaction rims was detected in the case of the most metamict sample, whereas U remained in the structure. FT-infrared spectrometry and X-ray diffraction measurements revealed that the bulk run products were recrystallized. Using micro-Raman spectrometry, we were able to demonstrate that differential recrystallization took place. The reaction rims are strongly recrystallized, whereas the unreacted grain interiors underwent only minor recrystallization. Recrystallization of the rims is accompanied by an enhancement of the integral CL intensity. It is suggested that recrystallization in the reaction rims was catalyzed by water infiltration and ion exchange and prevented significant congruent zircon dissolution under the given experimental conditions. Previous zircon studies have shown that (1) a transgressive morphology, (2) a reduced Th-U ratio, and (3) an enhanced CL emission are also characteristics of rims in zircons from high-grade metamorphic rocks. Based on these similarities between natural and experimentally produced rims, it is suggested that leaching-catalyzed recrystallization is an important alteration process in zircon under wet geological conditions and can account for many complex core-rim structures found in natural zircons. Furthermore, the strong enrichment of Ca in the reaction rims supports previous assumptions that high Ca concentrations in natural zircons are of secondary origin. It is suggested that lower U-Pb concordia intercept ages obtained from single-phase zircons with high Ca contents date a leaching event.