Micro-spectroscopic investigation of selenium-bearing minerals from the Western US Phosphate Resource Area

Mining activities in the US Western Phosphate Resource Area (WPRA) have released Se into the environment. Selenium has several different oxidation states and species, each having varying degrees of solubility, reactivity, and bioavailability. In this study we are investigating the speciation of Se in mine-waste rocks. Selenium speciation was determined using bulk and micro-x-ray absorption spectroscopy (XAS), as well as micro-x-ray fluorescence mapping. Rocks used for bulk-XAS were ground into fine powders. Shale used for micro-XAS was broken along depositional planes to expose unweathered surfaces. The near edge region of the XAS spectra (XANES) for the bulk rock samples revealed multiple oxidation states, with peaks indicative of Se(-II), Se(IV), and Se(+VI) species. Micro-XANES analysis of the shale indicated that three unique Se-bearing species were present. Using the XANES data together with ab initio fitting of the extended x-ray absorption fine structure region of the micro-XAS data (micro-EXAFS) the three Se-bearing species were identified as dzharkenite, a di-selenide carbon compound, and Se-substituted pyrite. Results from this research will allow for a better understanding of the biogeochemical cycling of Se in the WPRA.     

Fish assemblages in Tanzanian mangrove creek systems influenced by solar salt farm constructions

Deforestation of mangrove forests is common occurrence worldwide. We examined fish assemblage composition in three mangrove creek systems in Tanzania (East Africa), including two creeks where the upper parts were partly clear-cut of mangrove forest due to the construction of solar salt farms, and one creek with undisturbed mangrove forest. Fish were caught monthly for one year using a seine net (each haul covering 170 m²) within three locations in each creek, i.e. at the upper, intermediate and lower reaches. Density, biomass and species number of fish were lower in the upper deforested sites compared to the mangrove-fringed sites at the intermediate and lower parts in the two creeks affected by deforestation, whereas there were no differences among the three sites in the undisturbed mangrove creek system. In addition, multivariate analyses showed that the structure of fish assemblages varied between forested and clear-cut sites within the two disturbed creeks, but not within the undisturbed creek. Across the season, we found no significant differences except for a tendency of a minor increase in fish densities during the rainy season. At least 75% of the fishes were juveniles and of commercial interest for coastal fisheries and/or aquaculture. Mugil cephalus, Gerres oyena and Chanos chanos were the most abundant species in the forested sites. The dominant species in the clear-cut areas were M. cephalus and Elops machnata, which were both found in relatively low abundances compared to the undisturbed areas. The conversion of mangrove forests into solar salt farms not only altered fish assemblage composition, but also water and sediment conditions. In comparison with undisturbed areas, the clear-cut sites showed higher salinity, water temperature as well as organic matter and chlorophyll a in the sediments. Our results suggest that mangrove habitat loss and changes in environmental conditions caused by salt farm developments will decrease fish densities, biomass and species numbers as well as alter the overall fish assemblage composition in the salt farm area but not downstream in the creek.     

<Superscript>10</Superscript>Be surface exposure dating of the last deglaciation in the Aare Valley,Switzerland

The combined Rhone and Aare Glaciers presumably reached their last glacial maximum (LGM) extent on the Swiss Plateau prior to 24 ka. Two well-preserved, less extensive moraine stades, the Gurten and Bern Stade, document the last deglaciation of the Aare Valley, yet age constraints are very scarce. In order to establish a more robust chronology for the glacial/deglacial history of the Aare Valley, we applied ¹⁰Be surface exposure dating on eleven boulders from the Gurten and Bern Stade. Several exposure ages are of Holocene age and likely document post-depositional processes, including boulder toppling and quarrying. The remaining exposure ages, however yield oldest ages of 20.7 ± 2.2 ka for the Gurten Stade and 19.0 ± 2.0 ka for the Bern Stade. Our results are in good agreement with published chronologies from other sites in the Alps.     

Nebular mixing constrained by the Stardust samples

Abstract— Using X‐ray microprobe analysis of samples from comet Wild 2 returned by the Stardust mission, we determine that the crystalline Fe‐bearing silicate fraction in this Jupiter‐family comet is greater than 0.5. Assuming this mixture is a composite of crystalline inner solar system material and amorphous cold molecular cloud material, we deduce that more than half of Wild 2 has been processed in the inner solar system. Several models exist that explain the presence of crystalline materials in comets. We explore some of these models in light of our results.     

The parabolic wave equation in local helioseismology

In recent years methods of time-distance helioseismology have been used to produce maps of local flows in the surface layers of the Sun. Usually, these studies rely on ray theory to describe the propagation of sound waves. Ray theory, however, is a poor approximation of the acoustic wavefield near the surface of the Sun. In particular, it is inappropriate for the study of scattering and diffraction by inhomogeneities. But an exact solution of the acoustic wave equation in the Sun is not trivial. In this paper I present an approximation to the full wave equation, which transforms it into a parabolic equation. The parabolic equation is commonly used in ocean acoustics and geoseismology because it is much simpler to solve numerically. Here I discuss the parabolic approximation, its limitations and potential applications in helioseismology. Finally, I present some numerical results to demonstrate the capabilities of this method.     

Radio signature of cosmological structure formation shocks

In the course of the formation of cosmological structures, large shock waves are generated in the intracluster medium (ICM). In analogy to processes in supernova remnants, these shock waves may generate a significant population of relativistic electrons which, in turn, produce observable synchrotron emission. The extended radio relics found at the periphery of several clusters and possibly also a fraction of radio halo emission may have this origin. Here, we derive an analytic expression for (i) the total radio power in the downstream region of a cosmological shock wave, and (ii) the width of the radio-emitting region. These expressions predict a spectral slope close to −1 for strong shocks. Moderate shocks, such as those produced in mergers between clusters of galaxies, lead to a somewhat steeper spectrum. Moreover, we predict an upper limit for the radio power of cosmological shocks. Comparing our results to the radio relics in Abell 115, 2256 and 3667, we conclude that the magnetic field in these relics is typically at a level of 0.1 μG. Magnetic fields in the ICM are presumably generated by the shocks themselves; this allows us to calculate the radio emission as a function of the cluster temperature. The resulting emissions agree very well with the radio power–temperature relation found for cluster haloes. Finally, we show that cosmic accretion shocks generate less radio emission than merger shock waves. The latter may, however, be detected with upcoming radio telescopes.     

Remote sensing of rivers: the emergence of a subdiscipline in the river sciences

This article reports on the special issue of Earth Surface Processes and Landforms dedicated to remote sensing of rivers. This emerging subdiscipline of river science has grown at a rapid rate in recent years because of: (a) the growing desire and need for data to document and explore the full range of spatial and temporal variations in river systems; (b) evolving technologies that enable lower cost data acquisition, processing and analysis at reach to catchment to continental scales; and (c) the increasing engagement of river scientists with GIScience. The convergence of these factors and the ever growing number of practitioners speaks to the need for more communication among researchers, a major reason for creating this special issue. The 12 articles in the volume cover a broad spectrum of applications that use a variety of platforms and sensors, ranging from photogrammetric mapping of riffle‐pool morphology beneath forest canopy using a camera mounted on a hand held pole to satellite‐based synthetic radar mapping of subcontinental scale hydrology of large rivers. In this overview each of the 12 articles is briefly summarized. Based on these works and other research, it is concluded that the time for more widespread application of river remote sensing techniques is now. To promote more widespread use of remote sensing techniques for river science and management, the following are advocated: (a) developing stand alone or plug‐in software products that enable non‐expert users to implement these new methods, (b) incorporating remote sensing of rivers training into classes, workshops, and on‐line tutorials; and (c) promoting more intentional and formal collaboration among members of the river remote sensing community. Copyright © 2010 John Wiley & Sons, Ltd.     

Aluminum coordination in metaaluminous and peralkaline silicate melts

Incremental amounts of Na₂O and K₂O added to immiscible melts in the MgO-CaO-TiO₂-Al₂O₃ SiO₂ system cause a decrease in critical temperature, phase separation and change in the pattern of Al₂O₃ partitioning. Al₂O₃, which is concentrated in the low SiO₂ immiscible melts in the alkali-free system, is increasingly partitioned into the high-SiO₂ immiscible melt as the alkali/aluminium ratio is increased. However, K₂O is more effective than Na₂O in stabilizing Al₂O₂ in the SiO₂-rich melt. The coordination changes occurring in the aluminosilicate melts upon the addition of the alkali oxides are described by CaAl₂O₄+2SiOK=2KAlO₂+SiOCaOSi where K (or Na) displaces Ca as the charge-balancing cation for the networkforming AlO₄ tetrahedra. The increased stability of the AlO₄ species in the highly polymerized SiO₂-rich melt and the consequent shrinkage of the miscibility gap is ascribed to positive configurational entropy and negative enthalpy changes associated with the formation of K, Na-AlO₄ species. Element partition systematics indicate that (Na, K)AlO₂ species favor the more polymerized, CaAl₂O₄ and TiO₂ species, the less polymerized silicate structure in the melt.     

Electron microprobe dating of monazite substantiates ages of major geological events in the southern Brazilian shield

To obtain the chemical Th^*–Pb isochron ages and surface maps of monazite crystals in igneous and metamorphic rocks from the southern Brazilian Shield, we employ Th–U-total Pb dating by an electron probe microanalyzer. The ages of two Trans-Amazonian metamorphic events are given by a felsic, garnet-bearing granulite from the Santa Maria Chico granulitic complex. The age of the first event, at approximately 2.35 Ga, was obtained by surface mapping in a grain included in garnet. The dating of the second event, 1899±43 Ma, is in agreement with previous data obtained in zircon crystals with sensitive high-resolution ion microprobe. Other determinations belong to the Brasiliano cycle. In the São Gabriel block, an age of 643±129 Ma was obtained on monazite from a staurolite-garnet schist of the Cambaizinho Formation, whereas a staurolite-bearing schist from the Passo Feio complex yielded a 510±68 Ma age. Several units in the Dom Feliciano belt were dated, including the biotite-sillimanite gneisses of the Várzea do Capivarita complex (552±90 Ma), the sillimanite-garnet gneisses of Camboriú complex (565±77 Ma), the Três Figueiras granite (558±57 Ma), and the Plaza Itapema granite (545±55 Ma). The ages presented in this study, obtained through monazite chemical dating, are confirmed through comparison with previous data regarding zircon crystals from the same geological units.