Individual and Synergistic Effects of Metronidazole,Amoxicillin, and Ciprofloxacin on Methane Fermentation with Sewage Sludge

Methane fermentation is widely used to dispose of sewage sludge at wastewater treatment plants (WWTPs), due to production of renewable energy in the form of biogas. Antibiotics present in wastewater may accumulate in a sewage sludge. The aim of the present study is to investigate the impact of three antibiotics from different classes in three different doses on methane production from sewage sludge. For this purpose, metronidazole (MET), amoxicillin (AMO), and ciprofloxacin (CIP) are individually added to anaerobic reactors with sewage sludge collected from municipal WWTP. The antibiotics’ highest concentration (1024 mg kg^?1 of AMO; 512 mg kg^?1 of MET and CIP) lowers methane production and methane content in biogas. MET exerts the most marked effect and lowers methane production to 36.8 ± 3.7 mL CH₄ kg^?1 volatile solids. Tested antibiotics probably inhibit methanogenic archaea, which results in volatile fatty acids (VFAs) accumulation. Addition of MET results in accumulation of many kinds of VFAs with the highest concentration of acetic acid (17.52 ± 1.85 g L^?1). The addition of of AMO results in accumulation of butyric acid only (253.00 ± 15.89 g L^?1). However, addition of CIP results in accumulation of mainly acetic acid (7.58 ± 0.82 g L^?1) and isovaleric acid (2.01 ± 0.41 g L^?1). Next, synergistic effect of these antibiotics in a low concentration of 16 mg kg^?1 of AMO, 8 mg kg^?1 of MET, and 2 mg kg^?1 of CIP is measured in semi‐continuous conditions and causes inbibition of methane production and accumulation of VFAs.     

Time changes of the potential Love tidal parameters k2 and k3

The planet Earth is continuously changing in time, so there are phenomena that require continuous observation, including tidal parameters. The main goal of this study is to analyze time changes of the Love potential tidal parameters. This paper concerns an analysis of the estimated Love numbers k for the second and the third degree tides (numbers k₂ and k₃), associated with the tide variations of the satellite motion. The measured data used for determining the parameters k₂, k₃ were conducted within the period of January 1, 2014 until July 1, 2016 by LAGEOS-1 and LAGEOS-2 satellites. The results were compared with our previous determination of these parameters from LAGEOS data during the period from January 1, 2005 until July 1, 2007 to examine whether any systematic differences and time evolution occur. The adjusted values for k₂ equalling 0.29842 ± 0.00008 and k₃ equalling 0.0901 ± 0.0034 are discussed and compared with the nominal values given in International Earth Rotation and Reference Systems Service standards. The differences between the k₂ and k₃ values obtained for the time interval 2005.0–2007.5 and the results for 2014.0–2016.5 interval are –0.00288 for k₂ and 0.0042 for k₃. The obtained differences in the k₂ and k₃ values may indicate their evolution in time.     

Refinement of the Hardening Soil model within the small strain range

Acta Geotechnica - The popularity of the elasto-plastic Hardening Soil (HS) model is based on simple parameter identification from standard testing and empirical formulas. The HS model is...     

Identification of seismic anomalies caused by gas saturation on the basis of theoretical P and PS wavefield in the Carpathian Foredeep,SE Poland

The thin-layer build of the Carpathian Foredeep Miocene formations and large petrophysical parameter variation cause seismic images of gas-saturated zones to be ambiguous, and the location of prospection wells on the basis of anomalous seismic record is risky. A method that assists reservoir interpretation of standard recorded seismic profiles (P waves) can be a converted wave recording (PS waves). This paper presents the results of application of a multicomponent seismic survey for the reservoir interpretation over the Chałupki Dębniańskie gas deposit, carried out for the first time in Poland by Geofizyka Kraków Ltd. for the Polish Oil and Gas Company. Seismic modeling was applied as the basic research tool, using the SeisMod program based on the finite-difference solution of the acoustic wave equation and equations of motion. Seismogeological models for P waves were developed using Acoustic Logs; S-wave model (records only from part of the well) was developed on the basis of theoretical curves calculated by means of the Estymacja program calibrated with average S-velocities, calculated by correlation of recorded P and PS wavefields with 1D modeling. The conformity between theoretical and recorded wavefields makes it possible to apply the criteria established on the basis of modeling for reservoir interpretation. Direct hydrocarbon indicators (bright spots, phase change, time sag) unambiguously identify gas-prone layers within the ChD-2 prospect. A partial range of the indicators observed in the SW part of the studied profile (bright spot that covers a single, anticlinally bent seismic horizon) points to saturation of the horizon. The proposed location is confirmed by criteria determined for converted waves (continuous seismic horizons with constant, high amplitude) despite poorer agreement between theoretical and recorded wavefields.     

Pleistocene sandur rhythms,cycles and megacycles: Interpretation of depositional scenarios and palaeoenvironmental conditions

The Drawa sandur, which is the largest, coarse‐grained sandur in Poland, dates from the Pomeranian phase of the Weichselian glaciation (c. 16 ka BP). Using Markov chain analysis we infer that five cycles and five rhythms occur in its proximal part. The cycles dominated by Gt and St lithofacies in the lower part of the sandur succession and by a GDm lithofacies in the upper part, are fining‐upward cycles deposited in braided channels during large ablation floods. Three groups of cycles are distinguished based on their genesis: (i) cycles due to channel‐sheet evolution during large floods; (ii) cycles due to braid‐bar development during initial and advanced diminishing of floods; and (iii) cycles developed in the thalweg or interbar channels. The succession as a whole forms a large‐scale coarsening‐up megacycle (‘sandur megacycle’) which corresponds to a phase of ice‐sheet advance. Because the cyclicity was evident from Markov chain analysis of the sedimentary succession, we suggest that this statistical tool is valuable for reconstruction of glacifluvial sedimentary conditions, particularly as it can shed new light on the palaeogeographical development of sandar.     

Crustal and uppermost mantle S-wave velocity below the East European Craton in northern Poland from the inversion of ambient-noise records

International Journal of Earth Sciences - The P-wave velocities (Vp) within the East European Craton in Poland are well known through several seismic experiments which permitted to build a...     

Periglacial structures within fluvio‐aeolian successions of the end of the Last Glaciation – examples from SE Poland and NW Ukraine

The nature of permafrost and related environmental conditions in the Weichselian Late Pleniglacial and Lateglacial are reconstructed based on the assessment of frost structures that are best documented in the Loess Belt and in plateau areas composed of glacial till. Investigations were conducted in the central‐eastern part of the European Sand Belt (SE Poland and NW Ukraine) on a fluvio‐aeolian sedimentary succession and took into account its chronological context given by luminescence dating. Various generations of periglacial structures found in these deposits indicate not only the development of permafrost (ice‐wedge pseudomorphs) and decreased humidity (composite wedge casts) but also the degradation of permafrost (large‐scale involutions) and, finally, the establishment of deep seasonal frost (frost cracks). The diversity of structures in the study region appears to result from local conditions rather than increasing continentality of climate towards the east.     

Longitudinal asymmetry of craters' density distributions on the icy satellites

Crater's density distribution versus satellitographical longitude was searched for seven icy satellites: two of Jupiter (Ganymede and Callisto) and five of Saturn (Mimas, Tethys, Dione, Rhea and Iapetus). Craters were classified according to their size. Four bins of the craters' diameter were used. Density distributions were found in the longitudinal sectors of the near-equatorial stripes that circumscribe the satellites. The size distributions (R-plots) were done independently for each of the eight longitudinal sectors of the satellites. Searching for the leading/trailing (apex/antapex) and the near-side/far-side asymmetry was done. It was found that the crater density is longitudinally asymmetric for all seven satellites being studied. However, the apex–antapex asymmetry is much less pronounced than predicted by theory of Zahnle et al. (2003), for impacts on the satellites by ecliptic comets. We conclude that the impact craters observed on the considered satellites are mostly originated from planetocentric swarm of debris. In that case longitudinal asymmetry is not expected, as stated by Horedt and Neukum, 1984a, Horedt and Neukum, 1984b. However, cratering longitudinal asymmetry that we observe for Mimas perfectly agrees with calculations of Alvarellos et al. (2005). It is very likely that important part of craters on Mimas were formed due to impacts of ejecta originated from crater Herschel.     

Studies of aerosols advected to coastal areas with the use of remote techniques

This paper presents the results of the studies of aerosol optical properties measured using lidars and sun photometers. We describe two case studies of the combined measurements made in two coastal zones in Crete in 2006 and in Rozewie on the Baltic Sea in 2009. The combination of lidar and sun photometer measurements provides comprehensive information on both the total aerosol optical thickness in the entire atmosphere as well as the vertical structure of aerosol optical properties. Combination of such information with air mass back-trajectories and data collected at stations located on the route of air masses provides complete picture of the aerosol variations in the study area both vertically and horizontally. We show that such combined studies are especially important in the coastal areas where depending on air mass advection directions and altitudes the influence of fine or coarse mode (in this case possibly sea-salt) particles on the vertical structure of aerosol optical properties is an important issue to consider.     

Study of vertical structure of aerosol optical properties with sun photometers and ceilometer during the MACRON campaign in 2007

This paper presents the measurements of a vertical structure of aerosol optical properties performed during the MACRON (Maritime Aerosol, Clouds and Radiation Observation in Norway) campaign, which took place in July and August 2007 at ALOMAR observatory on Andøya island (69.279°N, 16.009°E, elevation 380 m a.s.l.). The mean value of the aerosol optical thickness (AOT) at 500 nm during campaign was 0.12. Significant increase of the AOT above longtime mean value was observed on 7 and 8 August 2007 when the AOT exceeded 0.4 at 500 nm. Analyses of back trajectories show the aerosol transported from over Africa and Central Europe. The aerosol extinction coefficient obtained from the synergy of ceilometer and sun photometer observations reached 0.05–0.08 km^?1 (at 1064 nm) in the dust layer. The single scattering albedo at the ALOMAR observatory decreased during the dust episode to 0.93–0.94, which indicates some absorptive aerosols in the lower PBL.