Carbon isotopes and geochemical processes in CO2-rich cold mineral water,N-Portugal

This paper summarizes a new outlook on the conceptual model of Melgaço–Messegães CO₂-rich cold (≈18 °C) mineral water systems, issuing in N of Portugal, based on their isotopic (²H, ³H, ¹³C, ¹⁴C and ¹⁸O) and geochemical features. Stable isotopes indicate the meteoric origin of these CO₂-rich mineral waters. Based on the isotopic fractionation with the altitude, a recharge altitude between 513 up to 740 m a.s.l. was estimated, corroborating the tritium results. The lowest ³H content (0 TU) is found in the groundwater samples with the highest mineralization. The mineral waters circulation are mainly related to a granitic and granodioritic environment inducing two different groundwater types (Ca/Na–HCO₃ and Na/Ca–HCO₃), indicating different underground flow paths. Calcium dissolution is controlled by hydrolysis of rock-matrix silicate minerals (e.g. Ca-plagioclases) and not associated to anthropogenic sources. The shallow dilute groundwaters exhibit signatures of anthropogenic origins (e.g. NO₃) and higher Na/Ca ratios. The stable isotopes together with the geochemistry provided no indication of mixing between the regional shallow cold dilute groundwater and mineral water systems. The heavy isotopic signatures identified in the δ¹³C data (δ¹³C = 4.7 ‰, performed on the total dissolved inorganic carbon (TDIC) of CO₂-rich mineral waters) could be derived from a deep-seated (upper mantle) source or associated to methanogenesis (CH₄ source). The negligible ¹⁴C content (≈2 pmC) determined in the TDIC of the mineral waters, corroborates the hypothesis of a mantle-derived carbon source to the mineral groundwater systems or dissolution of carbonate layers at depth.     

Exploring the policy and social factors fueling the expansion and shift of sugarcane production in the Brazilian Cerrado

Within the past decade, the sugarcane ethanol industry in Brazil has increased its production capacity to meet rising domestic demand for ethanol. However, to achieve this growth the industry has had to expand into new frontiers in the Brazilian Cerrado, specifically in the states of Goiás and Mato Grosso do Sul, which is now the second largest producing area of ethanol in Brazil. We argue that the expansion into the Brazilian Cerrado is a result of the interactions between the increase in demand, governmental policies, infrastructure, and factors that have prevented traditional sugarcane producing regions from meeting the increasing demand for ethanol. This paper analyzes the policies that have shaped the sugarcane industry in Brazil and the expansion of the industry across the country. The policies and issues examined include those that led to the concentration and consolidation of the sugarcane industry in the state of São Paulo and the consequences of this consolidation; the influence of governmental policies on the decision-making process of producers and industry; the state-level policies designed to expand the industry into Goiás and Mato Grosso do Sul states; infrastructure development; and the Sugarcane Agroecological Zoning policies. Through this study we conclude that the ethanol industry identified the Cerrado states as an opportunity for investment, given the good agricultural conditions for producing sugarcane, affordable land prices and favorable state-level fiscal incentive policies. In addition, there is a need for further regional development policies as the interaction between the sugarcane sector and regional government is likely to continue into the future.