Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Laboratory studies on the sputtering contribution to the sodium atmospheres of Mercury and the Moon

To ascertain the importance of sputtering by solar wind ions on the formation of a sodium exosphere around Mercury and the Moon, we have irradiated with 4 keV He ions, the Na bearing tectosilicates: albite, labradorite, and anorthoclase, as well as adsorbed Na layers deposited on albite and on olivine (a neosilicate that does not contain Na). Sodium at the surface and near surface (<40 Å) was quantified with X-ray photoelectron spectroscopy before and after each irradiation to determine the depletion cross section. We measured a cross section for sputtering of Na adsorbed on mineral surfaces, σ_s ≈ 1 × 10^?15 cm² atom^?1. In addition, mass spectrometric analyses of the sputtered flux show that a large fraction of the Na is sputtered as ions rather than as neutral atoms. These results have strong implications for modeling the sodium population within the mercurian and the lunar exospheres.     

Distribution and sources of aliphatic hydrocarbons in surface sediments of Sergipe River estuarine system

The assessment of aliphatic hydrocarbons was performed in the Sergipe River estuarine system, northeastern Brazil. Aliphatic hydrocarbons concentration ranged from 9.9 ug g?1 up to 30.8 ug g?1 of dry sediment. The carbon preference index (CPI, based on nC?? to nC?? range), indicated predominance of petrogenic input in two of the sites analyzed (P4 and P5). The unresolved complex mixture (UCM) was found to be present in seven of the nine sites sampled (except for P4 and P5). Overall, the results of this work suggest that there is a mix of organic matter sources to the sediment. Although the coast of Sergipe has an intense off shore petroleum exploration and the Sergipe River crosses the entire city of Aracaju, the capital city of Sergipe, non-significant anthropogenic fingerprint was assessed.     

Crustal thickness estimation beneath the southern central Andes at 30°S and 36°S from S wave receiver function analysis

We have used the S wave receiver function (SRF) technique to investigate the crustal thickness beneath two seismic profiles from the CHARGE project in the southern central Andes. A previous study employing the P wave receiver function method has observed the Moho interface beneath much of the profiles. They found, however, that the amplitude of the P to S conversion was diminished in the western part of the profiles and have attributed it to a reduction of the impedance contrast at the Moho due to lower crustal ecologitization. With SRF, we have successfully detected S to P converted waves from the Moho as well as possible conversions from other lithospheric boundaries. The continental South American crust reaches its maximum thickness of ∼70 km (along 30°S between 70°W and 68.5°W) beneath the Principal Cordillera and the Famatina system and becomes thinner towards the Sierras Pampeanas with a thickness of ∼40 km. Negative phases, possibly related to the base of the continental and oceanic lithosphere, can be recognized in the summation traces at different depths. By comparing our results with data obtained from previous investigations, we are able to further constrain the thickness of the crust and lithosphere beneath the central Andes.     

Forest Fire Alert System: a Geo Web GIS prioritization model considering land susceptibility and hotspots – a case study in the Carajás National Forest,Brazilian Amazon

To increase the monitoring potential of forest fires, an alert classification methodology using satellite-mapped hotspots has been established to help forest managers in the prioritization of which hotspot to be verified in the field, thus potentially improving the distribution of fire-fighting resources. A computer application was developed based on web-distributed geographical information technology whose main function is to interact automatically generated satellite hotspots and risk areas indicated in fire-susceptibility maps and classify them into five alert levels. The location of the hotspots is available continuously every 4 h, and a susceptibility map is produced daily through map algebra algorithm, which uses static (topography, vegetation and land use) and dynamic (weather) variables. Every process runs through automated geoprocessing routines. The methodology was tested during the dry period of 2007 in the Carajás National Forest, in the Brazilian Amazon, within an area of 400,000 ha. It is a critical area constantly threatened by fires caused by invasions and deforestation owing to intense agribusiness advances and mining activities in its surroundings. This situation results in observations of many hotspots inside the study area for the same day and almost the same time period, in places of extreme opposites, demanding complex rapid analysis and hindering the decision of the displacement of fire-fighting teams. Further, a major mining company operates within the National Forest area, maintaining actions of protection as part of its environmental mining license. Results are presented under three aspects: (i) the credibility of the daily susceptibility map (algorithm), which showed strong correlation between areas of greatest risks and the confirmed forest fires; (ii) the reliability of hotspots (alert levels), confirming 71% of fires; (iii) accuracy in the decision of which hotspot to be checked, which revealed the same number of verifications at different alert levels, 82% confirmed alert 5 hotspots (maximum) and only 50% from alert 1 (minimum), resulting in faster fire-fighting actions, minimizing burned areas and, in some cases, allowing fire control before its spreading. Therefore, the methodology demonstrated that GIS routines are able to determine the relationship between a reality-based, interpreted susceptibility map of the area and satellite-generated hotspots, highlighting the ones of highest hazard level through the alert classification, becoming an important tool to help decisions from the fire-control center, especially for high-risk regions. The methodology may be extrapolated to other forested areas.     

Anisotropy of Unstably Stratified Near-Surface Turbulence

Boundary-Layer Meteorology - Classic Monin–Obukov similarity scaling states that in a stationary, horizontally homogeneous flow, in the absence of subsidence, turbulence is dictated by the...     

Upper Pleistocene to Holocene peatland evolution in Southern Brazilian highlands as depicted by radar stratigraphy,sedimentology and palynology

Paleoenvironmental interpretation of proxy data derived from peatlands is largely based upon an evolutionary model for ombrotrophic bogs, in which peat accumulates in still environments. Reports on proxies obtained from minerotrophic fens, where hydrologic inputs are variable, are less common. In this study, a highland peatland in southern Brazil is presented through ground penetrating radar (GPR) and sedimentological, palynological and geochronologic data. The radar stratigraphic interpretation suggests a relatively complex history of erosion and deposition at the site since the beginning of Marine Isotope Stage 3 (MIS 3) interstadial period. In spite of this, radar stratigraphic and palynologic interpretations converge. Electromagnetic reflections tend to group in clusters that show lateral coherence and correlate with different sediment types, while pollen grains abound and are well preserved. As a result, the study of minerotrophic fens provides a source of proxies, suggesting that ombrotrophic bogs are not the only reliable source of data in wetlands for palynological analysis.     

Retrowedge-related Carboniferous units and coeval magmatism in the northwestern Neuquén province, Argentina

The studied Carboniferous units comprise metasedimentary (Guaraco Norte Formation), pyroclastic (Arroyo del Torreón Formation), and sedimentary (Huaraco Formation) rocks that crop out in the northwestern Neuquén province, Argentina. They form part of the basement of the Neuquén Basin and are mostly coeval with the Late Paleozoic accretionary prism complex of the Coastal Cordillera, south-central Chile. U–Pb SHRIMP dating of detrital zircon yielded a maximum depositional age of 374?Ma (Upper Devonian) for the Guaraco Norte Formation and 389?Ma for the Arroyo del Torreón Formation. Detrital magmatic zircon from the Guaraco Norte Formation are grouped into two main populations of Devonian and Ordovician (Famatinian) ages. In the Arroyo del Torreón Formation, zircon populations are also of Devonian and Ordovician (Famatinian), as well as of Late Neoproterozoic and Mesoproterozoic ages. In both units, there is a conspicuous population of Devonian magmatic zircon grains (from 406?±?4?Ma to 369?±?5?Ma), indicative of active magmatism at that time range. The ε_Hf values of this population range between ?2.84 and ?0.7, and the TDM-(Hf) are mostly Mesoproterozoic, suggesting that the primary sources of the Devonian magmatism contained small amounts of Mesoproterozoic recycled crustal components. The chemical composition of the Guaraco Norte Formation corresponds to recycled, mature polycyclic sediment of mature continental provenance, pointing to a passive margin with minor inputs from continental margin magmatic rocks. The chemical signature of the Huaraco Formation indicates that a magmatic arc was the main provenance for sediments of this unit, which is consistent with the occurrence of tuff—mostly in the Arroyo del Torreón Formation and very scarcely in the Huaraco Formation—with a volcanic-arc signature, jointly indicating the occurrence of a Carboniferous active arc magmatism during the deposition of the two units. The Guaraco Norte Formation is interpreted to represent passive margin deposits of mostly Lower Carboniferous age (younger than 374?Ma and older than 326?Ma) that precede the onset of the accretionary prism in Chile and extend into the earliest stage of the accretion, in a retrowedge position. The Arroyo del Torreón and Huaraco formations are considered to be retrowedge basin deposits to the early frontal accretionary prism (Eastern Series) of Chile. The presence of volcanism with arc signature in the units provides evidence of a Mississippian magmatic arc that can be correlated with limited exposures of the same age in the Frontal Cordillera (Argentina). The arc would have migrated to the West (Coastal Batholith) during Pennsylvanian–Permian times (coevally with the later basal accretionary prism/Western Series). The source of a conspicuous population of Devonian detrital zircon interpreted to be of magmatic origin in the studied units is discussed in various possible geotectonic scenarios, the preferred model being a magmatic arc developed in the Chilenia block, related to a west-dipping subduction beneath Chilenia before and shortly after its collision against Cuyania/Gondwana, at around 390?Ma and not linked to the independent, Devonian–Mississippian arc, developed to the south, in Patagonia.