Validation of present-day regional climate simulations over Europe: LAM simulations with observed boundary conditions

 Nested limited-area modelling is one method of down-scaling general circulation model (GCM) climate change simulations. To give credibility to this method the nested limited-area model (LAM) must be shown to simulate local present-day climate conditions fairly accurately. Here seven different European limited-area models driven by observed boundary conditions (operational weather forecast analyses) are validated against observations, and inter-compared for summer and winter months. Relatively large biases are found. In summer large positive surface air temperature biases are found over southeast Europe. The main reason is deficiencies in the surface hydrological schemes causing an unrealistic drying of the soil. In at least one of the models, most likely several of them, an additional factor is an overestimation of incoming solar radiation. Apart from excessive precipitation in mountainous areas in some models they generally show a negative bias due to the drying and decreased advection from the Atlantic. In winter most models have a positive precipitation bias which seems to be caused by an enhancement of advection from the Atlantic and enhanced cyclone activity. Surface air temperature biases are negative probably due to an underestimation of the incoming longwave radiation. Received: 11 December 1996 / Accepted: 17 March 1997     

Hydrofluoric Acid‐Free Digestion of Geological Samples for the Quantification of Rare Earth Elements by Inductively Coupled Plasma‐Optical Emission Spectrometry

Rare earth elements (REEs) are very important to technological development as well as to geochemical and environmental studies. In this work, hydrofluoric acid (HF) was replaced by condensed phosphoric acid (CPA) in the digestion of geological samples, and the quantification of REEs was performed by inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Six international reference materials (RMs), named DC86318, CGL 111, CGL 124, CGL 126, OKA‐2 and COQ‐1 and three Brazilian ore samples, named Araxá, Catalão and Pitinga were analysed. Only zircon and xenotime, which are potential REE‐bearing minerals, were not completely dissolved. Nevertheless, no REE associated with zircon was detected. The investigated digestion method presented many advantages: It was relatively fast (3 h), avoided fluoride precipitation, it was less hazardous because handling diluted H₃PO₄ is safer than HF, NH₄F or NH₄HF₂ aqueous solutions, it preserved the quartz fittings of the measurement equipment and the final solution contained lower levels of total dissolved solids than those produced by the fusion method.     

Correction to: Numerical Analysis of Infiltration in One‑Dimensional Unsaturated Soil–Geotextile Column

Geotechnical and Geological Engineering -