This paper gives several new and strong arguments in favour of the possibility of fixation of anhydrous lithium in the interlayer space of trioctahedral potassium micas. From the chemical viewpoint Li+ can replace K+, but is located out of the alkaline cation site; it enters pseudo-octahedral cavities limited by the triangular bases of two aluminous tetrahedra of two consecutive sheets. The solubility limit of Li+ in the interlayer is a function of the AlIV content of the mica. It is given by the relation (Li/Li + K)max = 2[(Al/Si + Al)IV]2. In both micas investigated — phlogopite, KMg3(Si3Al)O10(OH)2, and eastonite, K(Mg2.5Al1.5)(Si2.5Al1.5)O10(OH)2 — there is a remarkable agreement between the calculated values of the solubility limits and those measured by exchange reactions with hydrothermal solutions, at 600°C, 2 kbar. In high-Al micas, the interlayer Li content can be very important, with about one-third of K+ replaced by Li+.
The fixation of Li+ according to this model provokes a strong flattening of the interlayer (strong decrease of the reticular distance d005) and a slight increase of the reticular distance d060. Infra-red (IR) absorption spectrometry shows that vacant K+ sites are created when Li+ enters the interlayer; one observes low-frequency OH stretching bands attributed to OH dipoles lying towards these empty sites. Fixation of Li+ does not provoke any modification of the IR spectra in the region 1200-300 cm−1, indicating that Li+ is really out of the sheet. For both cell dimensions and IR spectra, a comparison is made with “ordinary” lepidolites, having Li+ in the octahedral sheet; it provides a guide for the distinction between the two species of Li-bearing micas. 相似文献
Resonantly driven Alfvén waves are studied in non-uniform stationary magnetic flux tubes. Analytic dissipative MHD solutions are obtained for the Lagrangian displacement and the Eulerian perturbation of the total pressure. These analytic solutions are valid in the dissipative layer and in the two overlap regions to the left and the right of the dissipative layer. From these analytic solutions we obtain the fundamental conservation law and the jump conditions for resonantly driven Alfvén waves in magnetic flux tubes with an equilibriun flow. The fundamental conservation law and the jump conditions depend on the equilibrium flow in a more complicated way than just a Doppler shift. The effects of an equlibrium flow are not to be predicted easily in general terms with the exception that the polarization of the driven Alfvén waves is still in the magnetic surfaces and perpendicular to the magnetic field lines as it is in a static flux tube. 相似文献
The present paper discusses the implementation of the SGHR method (Sakurai, Goossens, and Hollweg, 1991; Goossens, Ruderman, and Hollweg, 1995) in a numerical scheme for determining resonantly driven Alfvén waves in nonuniform magnetic flux tubes. This method is based on jump conditions over the dissipative layer which are obtained from an asymptotic analysis of analytical solutions to simplified versions of the linear non-ideal MHD equations in this dissipative layer. The emphasis is on the computational simplicity and the accuracy of the method. The method derives its computational simplicity from the fact that it circumvents the numerical integration of the non-ideal MHD equations. The implementation only requires the numerical integration of the ideal MHD equations away from the resonant position. There is no need for a special integration scheme and a PC suffices as a hardware tool.The accuracy of the method is verified by means of test computations. These test computations deal with the loss of power of acoustic waves in sunspots by resonant absorption of Alfvén waves. Results for the absorption coefficients obtained with the SGHR method are compared with known results in the literature obtained by integration of the full set of the linearized non-ideal MHD equations. The agreement is excellent and identifies the SGHR method as a powerful and extremely easy to use tool for studying resonant Alfvén waves. 相似文献
Considerable research has examined the social, cultural, economic, and community benefits of urban gardening. Few studies, however, have empirically assessed factors that influence urban community garden agrodiversity or its relationship to these dimensions of gardening. We conducted an interdisciplinary study of agrodiversity and cultural identity, based certain markers of identity, including how people see themselves with respect to race, ethnicity, or place of origin, in community gardens in Philadelphia, Pennsylvania. We conducted fifty‐six semistructured interviews with gardeners with different cultural identities in eight community gardens on their motivations for urban community gardening during 2014. We conducted plant inventories of the corresponding garden plots and found 104 cultivated edible and ornamental species and 28 varieties representing 34 families. We find that although gardens with culturally diverse gardeners did not have higher species richness, the cultural identity of the gardeners influenced species selection and reason for gardening. Further, the structure, design and species composition of garden plots reflected the identities of garden members. These finding have implications for the recent institutionalization of urban agriculture into city land policies in Philadelphia and other cities in North America. 相似文献
In South Africa, fishery managers have struggled with a number of challenges in terms of compliance amidst a process of legal and policy reform since the democratic elections of 1994. The past 10 years, and more specifically the past five, have seen a significant change in compliance effort, with a particular focus on increasing law enforcement activities and capacity. This paper highlights two case studies that have been instrumental in restructuring fisheries compliance in South Africa. Although law enforcement has been significantly strengthened, greater political will and government commitment is required to implement alternative strategies that will have a long-term impact on levels of compliance. 相似文献
Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L− 1 dFe, 3 nmol L− 1 dMn and 40 nmol L− 1 dAl and returned to 0.6 nmol L− 1 dFe, 0.5 nmol L− 1 dMn and 10 nmol L− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m− 2 yr− 1 (range 1.0–2.9 g m− 2 yr− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise. 相似文献
Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded 207Pb/235U and 206Pb/238U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded 207Pb/235U and 206Pb/238U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future. 相似文献