Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

Evidence for MTBE in Heating Oil

"Contamination of heating oil with MTBE could result in increasing the environmental impact of subsurface heating oil releases."     

A first Holocene leaf wax isotope-based paleoclimate record from the semi-humid to semi-arid south-eastern Caucasian lowlands

The Holocene paleoclimate of the Caucasus region is rather complex and not yet well understood: while existing studies are mainly based on pollen records from high-altitude and humid lowland regions, no records are available from the semi-humid to semi-arid south-eastern Caucasian lowlands. Therefore, this study investigated compound-specific δ²H and δ¹³C isotopes of leaf wax biomarkers from Holocene floodplain soils in eastern Georgia. Our results show that the leaf wax δ²H signal from the paleosols mostly reflects changes in the moisture source and its isotopic composition. Depleted δ²H values before ~8 cal ka bp change towards enriched values after ~5 cal ka bp and become again depleted after ~1.6 cal ka bp. This trend could be caused by Holocene changes of the isotopic compositions of the Black and eastern Mediterranean Sea, and/or by varying contribution of both moisture sources linked with the North Atlantic Oscillation. The leaf wax δ¹³C signal from the paleosols directly indicates varying local water availability and drought stress. Depleted δ¹³C values before ~8 and after ~5 cal ka bp indicate wetter local conditions with higher water availability, whereas more enriched values during the middle Holocene (~8 until at least 5 cal ka bp ) indicate drier conditions with increased drought stress.     

Provenance discrimination of fine sediments by mid-infrared spectroscopy: Calibration and application to fluvial palaeo-environmental reconstruction

Determining sediment provenance allows a better understanding of fluvial palaeo-dynamics, and identifying involved watersheds, at broad spatio-temporal scales. Conventional approaches for source identification are usually based on the physical, mineralogical, geochemical, magnetic or isotopic properties of sediments. Rapid, non-destructive and, in well-established contexts, highly accurate, mid-infrared spectroscopy is an alternative method for investigating sediment sources. The present research objectives are: (i) to use the mid-infrared spectroscopy method to discriminate the provenance of fine sediments, by applying discriminant analysis on a large set of reference samples from three different watersheds in the Upper Rhine area (associated with the Rhine, Ill and Vosges tributaries); (ii) to clarify whether the provenance spectra signatures are influenced by riverine depositional contexts (bars versus banks) and, to some extent, by grain size and/or high organic matter content; and (iii) to apply the mid-infrared spectroscopy – discriminant analysis method to a study of fluvial palaeo-dynamics and determine the provenance of palaeo-channel infillings. Three main sedimentary sources, divided into eight sub-categories, have been characterized by 196 modern reference samples from 78 collecting sites. Discriminant analysis displayed a strong separating power by classifying correctly the origin of samples without any inter-group overlap, independently from the geomorphological context (bar or bank) and associated slight changes in organic matter contents or grain size. Mid-infrared spectroscopy – discriminant analysis investigations of the palaeo-channel infill, complemented by radiocarbon dates and mineralogical data, allowed reconstructing general trends for the local morpho-sedimentary dynamics over the last ca 12 millennia.     

Determination of Radiogenic 87Sr/86Sr and Stable δ88/86SrSRM987 Isotope Values of Thirteen Mineral,Vegetal and Animal Reference Materials by DS‐TIMS

This work presents new ⁸⁷Sr/⁸⁶Sr and δ^88/86Sr_SRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ^88/86Sr_SRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ^88/86Sr_SRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ^88/86Sr_SRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ^88/86Sr_SRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ^88/86Sr_SRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.     

Numerical Modeling of Ice Fog in Interior Alaska Using the Weather Research and Forecasting Model

An ice microphysics parameterization scheme has been modified to better describe and understand ice fog formation. The modeling effort is based on observations in the Sub-Arctic Region of Interior Alaska, where ice fog occurs frequently during the cold season due to abundant water vapor sources and strong inversions existing near the surface at extremely low air temperatures. The microphysical characteristics of ice fog are different from those of other ice clouds, implying that the microphysical processes of ice should be changed in order to generate ice fog particles. Ice fog microphysical characteristics were derived with the NCAR Video Ice Particle Sampler during strong ice fog cases in the vicinity of Fairbanks, Alaska, in January and February 2012. To improve the prediction of ice fog in the Weather Research and Forecasting model, observational data were used to change particle size distribution properties and gravitational settling rates, as well as to implement a homogeneous freezing process. The newly implemented homogeneous freezing process compliments the existing heterogeneous freezing scheme and generates a higher number concentration of ice crystals than the original Thompson scheme. The size distribution of ice crystals is changed into a Gamma distribution with the shape factor of 2.0, using the observed size distribution. Furthermore, gravitational settling rates are reduced for the ice crystals since the crystals in ice fog do not precipitate in a similar manner when compared to the ice crystals of cirrus clouds. The slow terminal velocity plays a role in increasing the time scale for the ice crystals to settle to the surface. Sensitivity tests contribute to understanding the effects of water vapor emissions as an anthropogenic source on the formation of ice fog.     

Assessment of extreme drought and human interference on baseflow of the Yangtze River

Attention has been given to baseflow in large rivers, but up to now, no study on baseflow for the Yangtze River in combination with extreme drought and extensive human activities has been carried out. Discharge data in 2000–2005 and in the extreme drought years, 1978 and 2006, at stations along the main stream, lakes and distributaries of the Yangtze River were collected to analyse the features of baseflow in 2006 by using baseflow separation technique, HYSEP. It can be seen that the baseflow relative to the streamflow in 2006 was greater than those in other years. The variation of baseflow discharge in the Upper Yangtze River Stream (UYRS) was larger than that in the Mid‐Lower Yangtze River Stream (MLYRS). Human activities in MLYRS are more intensive than that in the UYRS and the baseflow discharge was greater. The baseflow is influenced by the extreme climate and human activities along the Yangtze River with the former being the dominant factor in 2006. The contribution of human interference to baseflow discharge was about 10% in 2006. Copyright © 2009 John Wiley & Sons, Ltd.     

Generalized LSG models with spatially varying Coriolis parameter

In this paper, we derive and study approximate balance models for nearly geostrophic shallow water flow where the Coriolis parameter is permitted to vary across the domain as long as it remains nondegenerate. This situation includes, for example, the β-plane approximation to the shallow water equations at mid-latitudes. Our approach is based on changing configuration space coordinates in the underlying variational principle in such a way that consistent asymptotics in the transformed Lagrangian leads to a degenerate Lagrangian structure. In this paper, we restrict our attention to first-order models. We show that the resulting models can be formulated in terms of an advected potential vorticity with a nonlinear vorticity inversion relation. We study the associated solvability conditions and identify a subfamily of models for which these conditions are satisfied without additional restrictions on the data. Finally, we provide the link between our framework and the theory of constrained Hamiltonian systems.