Petrology and geochronology of basalt breccia from the 1996 earthquake swarm of Loihi seamount, Hawaii: magmatic history of its 1996 eruption

 Samples of basalt were collected during the Rapid Response cruise to Loihi seamount from a breccia that was probably created by the July to August 1996 Loihi earthquake swarm, the largest swarm ever recorded from a Hawaiian volcano. ²¹⁰Po–²¹⁰Pb dating of two fresh lava blocks from this breccia indicates that they were erupted during the first half of 1996, making this the first documented historical eruption of Loihi. Sonobuoys deployed during the August 1996 cruise recorded popping noises north of the breccia site, indicating that the eruption may have been continuing during the swarm. All of the breccia lava fragments are tholeiitic, like the vast majority of Loihi's most recent lavas. Reverse zoning at the rim of clinopyroxene phenocrysts, and the presence of two chemically distinct olivine phenocryst populations, indicate that the magma for the lavas was mixed just prior to eruption. The trace element geochemistry of these lavas indicates there has been a reversal in Loihi's temporal geochemical trend. Although the new Loihi lavas are similar isotopically and geochemically to recent Kilauea lavas and the mantle conduits for these two volcanoes appear to converge at depth, distinct trace element ratios for their recent lavas preclude common parental magmas for these two active volcanoes. The mineralogy of Loihi's recent tholeiitic lavas signify that they crystallized at moderate depths (∼8–9 km) within the volcano, which is approximately 1 km below the hypocenters for earthquakes from the 1996 swarm. Taken together, the petrological and seismic evidence indicates that Loihi's current magma chamber is considerably deeper than the shallow magma chamber (∼3–4 km) in the adjoining active shield volcanoes. Received: 21 August 1997 / Accepted: 15 February 1998     

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.     

Canadian gravimetric geoid model 2010

A new gravimetric geoid model, Canadian Gravimetric Geoid 2010 (CGG2010), has been developed to upgrade the previous geoid model CGG2005. CGG2010 represents the separation between the reference ellipsoid of GRS80 and the Earth’s equipotential surface of $W_0=62{,}636{,}855.69~\mathrm{m}^2\mathrm{s}^{-2}$ W 0 = 62 , 636 , 855.69 m 2 s ? 2 . The Stokes–Helmert method has been re-formulated for the determination of CGG2010 by a new Stokes kernel modification. It reduces the effect of the systematic error in the Canadian terrestrial gravity data on the geoid to the level below 2 cm from about 20 cm using other existing modification techniques, and renders a smooth spectral combination of the satellite and terrestrial gravity data. The long wavelength components of CGG2010 include the GOCE contribution contained in a combined GRACE and GOCE geopotential model: GOCO01S, which ranges from $-20.1$ ? 20.1 to 16.7 cm with an RMS of 2.9 cm. Improvement has been also achieved through the refinement of geoid modelling procedure and the use of new data. (1) The downward continuation effect has been accounted accurately ranging from $-22.1$ ? 22.1 to 16.5 cm with an RMS of 0.9 cm. (2) The geoid residual from the Stokes integral is reduced to 4 cm in RMS by the use of an ultra-high degree spherical harmonic representation of global elevation model for deriving the reference Helmert field in conjunction with a derived global geopotential model. (3) The Canadian gravimetric geoid model is published for the first time with associated error estimates. In addition, CGG2010 includes the new marine gravity data, ArcGP gravity grids, and the new Canadian Digital Elevation Data (CDED) 1:50K. CGG2010 is compared to GPS-levelling data in Canada. The standard deviations are estimated to vary from 2 to 10 cm with the largest error in the mountainous areas of western Canada. We demonstrate its improvement over the previous models CGG2005 and EGM2008.     

Two oxygen isotopic components with extra-selenial origins observed among lunar metallic grains - In search for the solar wind component

Oxygen isotopic analyses were performed in the surface layers of lunar metallic grains from lunar regolith samples 71501 and 79035, presumably exposed at the Moon surface at different times. We were able to reproduce the two extreme O components previously found [Hashizume K. and Chaussidon M. (2005) A non-terrestrial ¹⁶O-rich isotopic composition for the protosolar nebula. Nature434, 619-622; Ireland T. R., Holden P., Norman M. D. and Clarke J. (2006) Isotopic enhancements of ¹⁷O and ¹⁸O from solar wind particles in the lunar regolith. Nature440, 776-778], with a range observed of −12 ± 5 < Δ¹⁷O < +33 ± 3‰ (1σ). The relatively minor ¹⁶O-rich component corresponding to an end-member Δ¹⁷O value lower than −20‰ is likely the solar component. This comes from the fact that its concentration roughly agrees with the maximum solar wind abundance expected among the grains from the two samples. At variance the ¹⁶O-poor component is 5-10 times more abundant and thus likely non-solar. The δ¹⁸O range found for the ¹⁶O-poor component may reflect various processes such as isotope exchange reaction during oxidation of metallic iron and/or isotope fractionation by evaporation/condensation at the surface of the Moon or during implantation at depth in the lunar metallic grains. The present study suggests that planetary solid materials in bulk are systematically depleted in ¹⁶O relative to the solar isotopic composition, suggesting the existence of non-mass-dependent isotopic fractionations associated to the formation of solids in the accretion disk.     

Importance of the oxidation/maturation pair in the evolution of humic coals

The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO₂ and H₂O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena.     

Early Permian extensional shearing of an Ordovician granite: The Saint-Eutrope “C/S-like” orthogneiss (Montagne Noire,French Massif Central)

Dating the magmatic events in the Montagne Noire gneiss dome is a key point to arbitrate between the different interpretations of the Late Carboniferous–Early Permian tectonics in this southern part of the Variscan belt. The Saint-Eutrope orthogneiss crops out along the northern flank of the dome. We show that the protolith of this orthogneiss is an Ordovician granite dated at 455 ± 2 Ma (LA-ICP-MS U-Pb dating on zircon). This age is identical to that previously obtained on the augen orthogneiss of the southern flank, strongly suggesting that both orthogneiss occurrences have the same Ordovician protolith. The Saint-Eutrope orthogneiss experienced intense shearing along the Espinouse extensional detachment at ca. 295 Ma (LA-ICP-MS U-Pb-Th on monazite), an age close to that determined previously on mica by the ³⁹Ar-⁴⁰Ar method and contemporaneous with the emplacement age of the syntectonic Montalet granite farther to the west. This normal sense shearing reworked previous fabrics related to Variscan thrusting that can be still observed in the augen orthogneiss of the southern flank, and is responsible for the spectacular “C/S-like” pattern of the Saint-Eutrope orthogneiss. This work also shows that care is needed when dealing with C/S-type structures, since they can develop not only in syntectonic intrusions, but also in orthogneisses affected by an intense secondary deformation, at decreasing temperature.     

Stormwater harvesting in ephemeral streams: how to bypass clogging and unsaturated layers

To cope with water scarcity in drylands, stormwater is often collected in surface basins and subsequently stored in shallow aquifers via infiltration. These stormwater harvesting systems are often accompanied by high evaporation rates and hygiene problems. This is commonly a consequence of low infiltration rates, which are caused by clogging layers that form on top of the soil profile and the presence of a thick vadose zone. The present study aims to develop a conceptual solution to increase groundwater recharge rates in stormwater harvesting systems. The efficiency of vadose-zone wells and infiltration trenches is tested using analytical equations, numerical models, and sensitivity analyses. Dams built in the channel of ephemeral streams (wadis) are selected as a study case to construct the numerical simulations. The modelling demonstrated that vadose-zone wells and infiltration trenches contribute to effective bypassing of the clogging layer. By implementing these solutions, recharge begins 2250–8100% faster than via infiltration from the bed surface of the wadi reservoir. The sensitivity analysis showed that the recharge rates are especially responsive to well length and trench depth. In terms of recharge quantity, the well had the best performance; it can infiltrate up to 1642% more water than the reservoir, and between 336 and 825% more than the trench. Moreover, the well can yield the highest cumulative recharge per dollar and high recharge rates when there are limitations to the available area. The methods investigated here significantly increased recharge rates, providing practical solutions to enhance aquifer water storage in drylands.

     

Abundance and distribution of PGE and Au in the island-arc mantle: implications for sub-arc metasomatism

Ultramafic xenoliths from a veined mantle wedge beneath the Kamchatka arc have non-chondritic, fractionated chondrite-normalized platinum-group element (PGE) patterns. Depleted (e.g., low bulk-rock Al₂O₃ and CaO contents) mantle harzburgites show clear enrichment in the Pd group relative to the Ir group PGEs and, in most samples, Pt relative to Rh and Pd. These PGE signatures most likely reflect multi-stage melting which selectively concentrates Pt in Pt–Fe alloys while strongly depleting the sub-arc mantle wedge in incompatible elements. Elevated gold concentrations and enrichment of strongly incompatible enrichment (e.g., Ba and Th) in some harzburgites suggest a late-stage metasomatism by slab-derived, saline hydrous fluids. Positive Pt, Pd, and Au anomalies coupled with Ir depletions in heavily metasomatized pyroxenite xenoliths probably reflect the relative mobility of the Pd and Ir groups (especially Os) during sub-arc metasomatism which is consistent with Os systematics in arc mantle nodules. Positive correlations between Pt, Pd, and Au and various incompatible elements (Hf, U, Ta, and Sr) also suggest that both slab-derived hydrous fluids and siliceous melts were involved in the sub-arc mantle metasomatism beneath the Kamchatka arc.