Investigation of groundwater mineralization in the Hammamet–Nabeul unconfined aquifer,north-eastern Tunisia: geochemical and isotopic approach

Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO₄–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process; and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted δ ¹⁸O and δ ²H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large contamination by organic ¹⁴C corroborate the recent origin of the groundwaters in the study area.     

Base flow hydrology and water quality of an Ozarks spring and associated recharge area,southern Missouri,USA

Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some sites. For most of the year, nutrient levels were less than the eutrophic threshold (ET) of 0.075 mg/l total phosphorus (TP) and 1.5 mg/l total nitrogen (TN). Sites that consistently displayed concentrations of TP and TN higher than the ET were influenced by wastewater treatment plants (WTP) or OWS. Sites with nutrient concentrations above the ET were likely influenced by the re-release of nonpoint source related TP and TN delivered to streams during storm events. Water quality and discharge at the spring outlet remained consistent over the sampling period suggesting diffuse recharge from a deep aquifer source is able to dilute shallow ground water sources carrying nonpoint pollutants at base flow. Historical and regional data comparisons show these trends have been consistent over at least the last two decades.     

Use of inhibitors for coastal bacteria and phytoplankton: Application to nitrogen uptake measurement

For several decades, prokaryotic and eukaryotic inhibitors have been used to exclude bacteria from microalgal cultures and for investigating prey-predator relationships. Recently there has been considerable interest in using specific inhibitors for studying the interactions between bacteria and phytoplankton, by selective repression of either organism’s activity. The effectiveness of chemical inhibitors must be tested before applying them to natural communities to partition metabolic activities between functional groups. Six different antibiotics selected from the most commonly reported in the literature were tested, at concentrations varying from 12.5 to 100 mg L⁻¹, for their effect on bacterial growth and functional diversity of natural communities from Mediterranean coastal waters. Penicillin and streptomycin each at a final concentration of 100 mg L⁻¹ significantly reduced bacterial growth within 2 h. There was a greater impact on bacterial functional diversity when both antibiotics were mixed together. This mixture did not have any significant effect on the growth of selected cultured phytoplankton strains, whereas the eukaryote inhibitor cycloheximide at 100 mg L⁻¹ reduced growth within 2 h of incubation. The penicillin–streptomycin mixture and cycloheximide alone successfully partitioned NH₄⁺ and NO₃⁻ uptake between bacteria and phytoplankton bi-weekly sampled in a coastal lagoon in Autumn, where bacterial contribution to total NH₄⁺ and NO₃⁻ uptake averaged 46 and 41%, respectively. The use of specific inhibitors may be a valuable method for studying interactions, such as competition and mutualism, or lack of interaction between the different components of microbial communities and could be used to study their relative importance in biogeochemical fluxes.     

A noble gas and cosmogenic radionuclide analysis of two ordinary chondrites from Almahata Sitta

Abstract– We present the results of a noble gas (He, Ne, Ar) and cosmogenic radionuclide (¹⁰Be, ²⁶Al, ³⁶Cl) analysis of two chondritic fragments (#A100, L4 and #25, H5) found in the Almahata Sitta strewn field in Sudan. We confirm their earlier attribution to the same fall as the ureilites dominating the strewn field, based on the following findings: (1) both chondrite samples indicate a preatmospheric radius of approximately 300 g cm^?2, consistent with the preatmospheric size of asteroid 2008 TC₃ that produced the Almahata Sitta strewn field; (2) both have, within error, a ²¹Ne/²⁶Al‐based cosmic ray exposure age of approximately 20 Ma, identical to the reported ages of Almahata Sitta ureilites; (3) both exhibit hints of ureilitic Ar in the trapped component. We discuss a possible earlier irradiation phase for the two fragments of approximately 10–20 Ma, visible only in cosmogenic ³⁸Ar. We also discuss the approximately 3.8 Ga (⁴He) and approximately 4.6 Ga (⁴⁰Ar) gas retention ages, measured in both chondritic fragments. These imply that the two chondrite fragments were incorporated into the ureilite host early in solar system evolution, and that the parent asteroid from which 2008 TC₃ is derived has not experienced a large break‐up event in the last 3.8 Ga.     

Intrinsic bioremediation of a petroleum-impacted wetland

Following the 1994 San Jacinto River flood and oil spill in southeast Texas, a petroleum-contaminated wetland was reserved for a long-term research program to evaluate bioremediation as a viable spill response tool. The first phase of this program, presented in this paper, evaluated the intrinsic biodegradation of petroleum in the contaminated wetland. Sediment samples from six test plots were collected 11 times over an 11-month period to assess the temporal and spatial petroleum concentrations. Petroleum concentrations were evaluated using gas chromatography-mass spectrometer analyses of specific target compounds normalized to the conservative biological marker, C(30)17alpha,21beta(H)-hopane. The analyses of specific target compounds were able to characterize that significant petroleum biodegradation had occurred at the site over the one-year period. Total resolved saturate and total resolved aromatic hydrocarbon data indicated the petroleum was degraded more than 95%. In addition, first-order biodegradation rate constants were calculated for the hopane-normalized target compounds and supported expected biodegradation patterns. The rapid degradation rates of the petroleum hydrocarbons are attributed to conditions favorable to biodegradation. Elevated nutrient levels from the flood deposition and the unconsolidated nature of the freshly deposited sediment possibly provided a nutrient rich, oxic environment. Additionally, it is suggested that an active and capable microbial community was present due to prior exposure to petroleum. These factors provided an environment conducive for the rapid bioremediation of the petroleum in the contaminated wetland.     

Reconstructing Phreatic Palaeogroundwater Levels in a Geoarchaeological Context: A Case Study in Flanders,Belgium

The complex debate on prehistoric settlement decisions is no longer tackled from a purely archaeological perspective but from a more landscape‐oriented manner combined with archaeological evidence. Therefore, reconstruction of several components of the former landscape is needed. Here, we focus on the reconstruction of the groundwater table based on modeling. The depth of the phreatic aquifer influences, for example, soil formation processes and vegetation type. Furthermore, it directly influences settlement by the wetness of a site. Palaeogroundwater modeling of the phreatic aquifer was carried out to produce a series of full‐coverage maps of the mean water table depth between 12.7 ka and the middle of the 20th century (1953) in Flanders, Belgium. The research focuses on the reconstruction of the input data and boundary conditions of the model and the model calibration. The model was calibrated for the 1924–1953 time period using drainage class maps. Archaeological site data and podzol occurrence data act as proxies for local drainage conditions over periods in the past. They also served as a control on the simulated phreatic palaeogroundwater levels. Model quality testing on an independent validation data set showed that the model predicts phreatic water table levels at the time of soil mapping well (mean error of 1.8 cm; root mean square error of 65.6 cm). Simulated hydrological conditions were in agreement with the occurrence of archaeological sites of Mesolithic to Roman age at 96% of the validation locations, and also with the occurrence of well‐drained podzols at 97% of the validation locations.     

Theoretical study of OH-defects in pure enstatite

The infrared spectroscopic properties of selected defects in orthoenstatite are investigated by first-principles calculations. The considered defects include doubly protonated Mg vacancies at M1 and M2 sites, fully protonated SiA and SiB vacancies (hydrogarnet defects), and doubly protonated SiA and SiB vacancies associated with interstitial Mg²⁺ cations. The bands observed at 3,070 and 3,360 cm^?1 in the spectrum of synthetic enstatite samples are ascribed to O2A–H and O2B–H groups, respectively, associated with M2 vacancies. The theoretical models suggest that bands observed at 3,590 and 3,690 cm^?1 in the spectrum of enstatite samples synthesized under low silica-activity conditions correspond to O2H and O1H groups associated with SiB vacancies partially compensated by interstitial Mg²⁺ cations in fivefold coordination. The theoretical relation between the integrated absorption coefficient of OH-defects and vibrational frequencies is consistent with previous observations indicating that the absorption coefficients of OH-defects are comparatively stronger in enstatite than in the olivine polymorphs.     

Assessing hyporheic exchange and associated travel times by hydraulic, chemical, and isotopic monitoring at the Steinlach Test Site, Germany

First results of a multi-disciplinary hyporheic monitoring study are presented from the newly established Steinlach Test Site in Southern Germany. The site is located in a bend of the River Steinlach (mean discharge of 1.8 m³/s) underlain by an alluvial sandy gravel aquifer connected to the stream. The overall objective is a better understanding of hyporheic exchange processes at the site and their interrelations with microbial community dynamics and biochemical reactions at the stream–groundwater interface. The present paper focuses on the distribution of lateral hyporheic exchange fluxes and their associated travel times at the Steinlach Test Site. Water level dynamics in various piezometers correspond to the different domains of hydraulic conductivity in the shallow aquifer and confirms hyporheic exchange of infiltrated stream water across the test site. Hydrochemical compositions as well as increased damping of continuous time series of electrical conductivity (EC) and temperature at the respective piezometers confirmed the inferred distribution of hyporheic flowpaths. Mean travel times ranging from 0.5 days close to the stream to more than 8 days in the upstream part of the test site could be estimated from deconvolution of EC and δ¹⁸O–H₂O data. The travel times agree well with the presumed flowpaths. Mg/Ca ratios as well as model fits to the EC and δ¹⁸O data indicate the presence of an additional water component in the western part of the test site which most likely consists of hillslope water or groundwater. Based on the mean travel times, the total lateral hyporheic exchange flux at the site was estimated to be of the order of 1–2 L/s.     

Catchments as reactors: a comprehensive approach for water fluxes and solute turnover

Sustainable water quality management requires a profound understanding of water fluxes (precipitation, run-off, recharge, etc.) and solute turnover such as retention, reaction, transformation, etc. at the catchment or landscape scale. The Water and Earth System Science competence cluster (WESS, http://www.wess.info/) aims at a holistic analysis of the water cycle coupled to reactive solute transport, including soil–plant–atmosphere and groundwater–surface water interactions. To facilitate exploring the impact of land-use and climate changes on water cycling and water quality, special emphasis is placed on feedbacks between the atmosphere, the land surface, and the subsurface. A major challenge lies in bridging the scales in monitoring and modeling of surface/subsurface versus atmospheric processes. The field work follows the approach of contrasting catchments, i.e. neighboring watersheds with different land use or similar watersheds with different climate. This paper introduces the featured catchments and explains methodologies of WESS by selected examples.     

Turbidity as a proxy for total suspended solids (TSS) and particle facilitated pollutant transport in catchments

Transport of hydrophobic organic pollutants in rivers is mainly coupled to transport of suspended particles. Turbidity measurements are often used to assess the amount of suspended solids in water. In this study, a monitoring campaign is presented where the total concentration of polycyclic aromatic hydrocarbons (PAHs), the amount of total suspended solids (TSS), and turbidity was measured in water samples from five neighboring catchments in southwest Germany. Linear correlations of turbidity and TSS were obtained which were in close agreement to the literature data. From linear regressions of turbidity versus total PAH concentrations in water, mean concentrations of PAH on suspended particles could be calculated and these varied by catchment. These values furthermore comprise a robust measure of the average sediment quality in a given catchment. Since in the catchments investigated in this study, PAH concentrations on suspended particles were stable over a large turbidity range (1–114 Nephelometric Turbidity Units), turbidity could be used as a proxy for total PAHs and likely other highly hydrophobic organic pollutants in river water if the associated correlations are established. Based on that, online monitoring of turbidity (e.g., by optical backscattering sensors) seems very promising to determine annual pollutant fluxes.