Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.     

Large Earthquakes at the Ibero-Maghrebian Region: Basis for an EEWS

Large earthquakes (M_w > 6, I_max > VIII) occur at the Ibero-Maghrebian region, extending from a point (12ºW) southwest of Cape St. Vincent to Tunisia, with different characteristics depending on their location, which cause considerable damage and casualties. Seismic activity at this region is associated with the boundary between the lithospheric plates of Eurasia and Africa, which extends from the Azores Islands to Tunisia. The boundary at Cape St. Vincent, which has a clear oceanic nature in the westernmost part, experiences a transition from an oceanic to a continental boundary, with the interaction of the southern border of the Iberian Peninsula, the northern border of Africa, and the Alboran basin between them, corresponding to a wide area of deformation. Further to the east, the plate boundary recovers its oceanic nature following the northern coast of Algeria and Tunisia. The region has been divided into four zones with different seismic characteristics. From west to east, large earthquake occurrence, focal depth, total seismic moment tensor, and average seismic slip velocities for each zone along the region show the differences in seismic release of deformation. This must be taken into account in developing an EEWS for the region.     

Aftershock seismic assessment taking into account postmainshock residual drifts

This paper introduces and evaluates a methodology for the aftershock seismic assessment of buildings taking explicitly into account residual drift demands after the mainshock (i.e., postmainshock residual interstory drifts, RIDR_o). The methodology is applied to a testbed four‐story steel moment‐resisting building designed with modern seismic design provisions when subjected to a set of near‐fault mainshock–aftershock seismic sequences that induce five levels of RIDR_o. Once the postmainshock residual drift is induced to the building model, a postmainshock incremental dynamic analysis is performed under each aftershock to obtain its collapse capacity and its capacity associated to demolition (i.e., the capacity to reach or exceed a 2% residual drift). The effect of additional sources of stiffness and strength (i.e., interior gravity frames and slab contribution) and the polarity of the aftershocks are examined in this study. Results of this investigation show that the collapse potential under aftershocks strongly depends on the modeling approach (i.e., the aftershock collapse potential is modified when additional sources of lateral stiffness and strength are included in the analytical model). Furthermore, it is demonstrated that the aftershock capacity associated to demolition (i.e., the aftershock collapse capacity associated to a residual interstory drift that leads to an imminent demolition) is lower than that of the aftershock collapse capacity, which mean that this parameter should be a better measure of the building residual capacity against aftershocks. Copyright © 2014 John Wiley & Sons, Ltd.