Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

The influence of sea waves on the wind profile

From wind profile and wave measurements performed during the JONSWAP II experiment, relations between the dimensionless profile slope and the significant wave height are derived. It is shown that the wind profile is distorted by the waves especially in the vicinity of the water surface. The wave influence on the profile seems to be restricted to heights below about three wave heights. Above this level, the dimensionless profile slope is an approximately constant value corresponding to a drag coefficient of about 1.15 × 10^–3.     

What determines farmers’ resilience towards ENSO-related drought? An empirical assessment in Central Sulawesi, Indonesia

Crop production in the tropics is subject to considerable climate variability caused by the El Niño-Southern Oscillation (ENSO) phenomenon that is likely to become even more pronounced during the twenty-first century. Little is known about the impact of ENSO-related drought on crop yields and food security, especially at the household level. This paper seeks to contribute to closing this knowledge gap with a case study from Central Sulawesi, Indonesia. Its main objective is to measure household resilience towards drought periods and to identify its influencing factors to deduce policy implications. Using indicators for consumption expenditures, we construct an index measuring household drought resilience; we then apply an asset-based livelihood framework to identify its determinants. Most of the drought-affected farm households are forced to substantially reduce expenditures for food and other basic necessities. Households’ drought resilience is strengthened by the possession of liquid assets, access to credit, and the level of technical efficiency in agricultural production. The results suggest a number of policy recommendations, namely improvement of the farmers’ access to ENSO forecasts, the provision of credit and savings products to facilitate consumption smoothing, and the intensification of agricultural extension in view of low levels of productivity found in agricultural production.     

Using panel data to estimate the effect of rainfall shocks on smallholders food security and vulnerability in rural Ethiopia

Ethiopia??s agriculture is predominantly rainfed and hence any irregularity in weather conditions has adverse welfare implications. Using panel data, this paper analyzes the effect of rainfall shocks on Ethiopian rural households?? food security and vulnerability over time while controlling for a range of other factors. To this end, we generate a time-variant household food security index which is developed by principal components analysis. Based on this index, households are classified into relative food security groups and their socioeconomic differences are assessed. The exploratory results show that compared to the less secured households, the more secured ones have male and literate household heads, tend to have a greater number of economically active household members, own more livestock, experience better rainfall outcome, and participate in local savings groups. Using the food security index as the dependent variable, we use a fixed effects instrumental variable regression model to identify determinants of households?? food security over time and find that rainfall variability is an important factor. Moreover, household size, participation in local savings groups, and livestock ownership positively affect food security. Results from multinomial logistic regression model complement the fixed effects instrumental variable regression results by showing that the level and variability of rainfall are important determinants of persistent food insecurity and vulnerability. The results highlight the need for efficient risk reduction and mitigation programs to improve risk exposure and coping ability of rural households. Careful promotion of investment in infrastructure to support irrigation and water resources development is one aspect worth considering.     

Geochronology of Middle and Upper Pleistocene Loess Sections in Hungary

The application of both thermoluminescence and infrared stimulated luminescence dating to the extensively studied “classical” Hungarian loess/paleosol sequences from Basaharc, Mende, and Paks provides a reliable chronological framework and climatostratigraphic reconstruction for the last interglacial/glacial cycle. Based on this combined luminescence dating study a new chronology is proposed for the “Young Loess” in Hungary. Luminescence dating suggests that the loess below the MF2 horizon formed during the penultimate glaciation. The MF1 horizon probably formed during an interstade within oxygen isotope stage 3. For the youngest loess, overlying MF1, a very high accumulation rate was determined. Large time gaps occur above MF2 and MF1, indicating that most of the record of the last glaciation is missing in the standard sections at Basaharc, Mende, and Paks. Either large discontinuities or a very low accumulation rate occurred in all three type sections during the soil-forming periods. High-resolution studies of climatic proxies using this combined luminescence dating approach provide a reliable chronological framework for loess and loess derivatives of the last glacial cycle in Hungary, although a precise and complete chronostratigraphic reconstruction cannot be achieved from the incomplete records found at these sites.     

Income distribution dynamics and cross-region convergence in Europe

This paper presents a continuous version of the model of distribution dynamics to analyse the transition dynamics and implied long-run behaviour of the EU-27 NUTS-2 regions over the period 1995–2003. It departs from previous research in two respects: first, by introducing kernel estimation and three-dimensional stacked conditional density plots as well as highest density regions plots for the visualisation of the transition function, based on Hyndman et al. (J Comput Graph Stat 5(4):315–336, 1996), and second, by combining Getis’ spatial filtering view with kernel estimation to explicitly account for the spatial dimension of the growth process. The results of the analysis indicate a very slow catching-up of the poorest regions with the richer ones, a process of shifting away of a small group of very rich regions, and highlight the importance of geography in understanding regional income distribution dynamics.

On the possibility of earth-type habitable planets around 47 UMa

We investigate whether Earth-type habitable planets can in principle exist in the planetary system of 47 UMa. The system of 47 UMa consists of two Jupiter-size planets beyond the outer edge of the stellar habitable zone, and thus resembles our own Solar System most closely compared to all exosolar planetary systems discovered so far. Our study of habitability deliberately follows an Earth-based view according to the concept of Franck and colleagues, which assumes the long-term possibility of photosynthetic biomass production under geodynamic conditions. Consequently, a broad variety of climatological, biogeochemical, and geodynamical processes involved in the generation of photosynthesis-driven life conditions is taken into account. The stellar luminosity and the age of the star/planet system are of fundamental importance for planetary habitability. Our study considers different types of planetary continental growth models and takes into account a careful assessment of the stellar parameters. In the event of successful formation and orbital stability, two subjects of intense research, we find that Earth-type habitable planets around 47 UMa are in principle possible! The likelihood of those planets is increased if assumed that 47 UMa is relatively young (?6 Gyr) and has a relatively small stellar luminosity as permitted by the observational range of those parameters.     

Tourism resources and their development in Maldive Islands

Maldive Islands are characterized by a unique coral nature and thus they posses unique tourism resources though in a one-sided way, namely in the submarine and littoral environment of the islands, lagoons and reefs, associated with the year-round tropical climate. Therefore, not only divers and snorklers enjoy the profuse underwater resources, but also beach tourists are attracted by the nature of the beaches and the climatic conditions as well. This environment really guarantees relaxation and recreation. Tourism in Maldives which was introduced in 1972 only, has successfully developed so far. Proof is given by the rapidly growing number of tourists and tourist resorts (islands) over the past 10 year period. On the European market, Maldives today rank among the most attractive tourist destinations in the tropics. Maldives offer large natural resources for tourism to be further developed in the future. The sensitive environment does however call for most considerate measures.