Seismostratigraphy and structural framework of the SW Baltic Sea

The SW part of the Baltic Sea between Scania, Rügen, Bornholm and Mön constitutes a complex crustal transition between the Baltic Shield and the accreted Phanerozoic provinces of the West European Platform. An integrated interpretation of marine reflection seismic data sets from the BABEL AC line and two commercial surveys offshore NE Germany and S Sweden have resulted in a complete view of the structural framework in the area. The general seismic picture can best be detected by two characteristic sets of reflection phases. The lower set is dominated by slightly dipping and vertically displaced prominent reflectors corresponding to downfaulted Lower Palaeozoic strata on top of the Precambrian basement. The upper set represents Mesozoic and Cenozoic coherent reflection phases including a thick Upper Cretaceous unit. The Caledonian deformation front is identified in the southern part of the investigated area as the border against which basement rocks have been affected by Caledonian metamorphism and deformation. Major structural elements also include the N–S trending Agricola–Svedala Fault and North Rügen-Skurup Fault. Several NW–SE trending faults are also identified including the Nordadler–Kamien Fault, Jutland–Mön Fault, Carlsberg Fault, Romeleåsen Fault Zone and the Fyledalen Fault Zone. The sedimentary record from NE German offshore wells and Scanian boreholes is compared with the seismic data. The Cambro-Silurian strata are composed mainly of quartzitic sandstones, shales and biomicritic limestones. The Silurian is dominated by grey, micaceous shale and micaceous siltstone deposited in a marginal basin. Upper Palaeozoic strata are merely encountered in the southernmost part of the investigated area. These include Zechstein strata. The Mesozoic deposits are dominated by a thick Cretaceous sequence of mainly limestones with interbedded sandstones.     

Carbon isotope geochemistry of the Precambrian Lomagundi carbonate province,Rhodesia

Carbon isotope measurements carried out on 67 dolomite samples from the Middle Precambrian Lomagundi Group (Rhodesia) have yielded a δ¹³C mean of +8.2 ± 2.6%. vs PDB. With the outcrop of these dolomites extending over a distance of almost 300 km, the Lomagundi dolomite faces is likely to represent the largest isotopically anomalous sedimentary carbonate province ever recorded. It is concluded that the anomalous carbonates formed in a closed basin whose δ¹³C level had been substantially increased as a result of a preferential removal (within sedimentary organics) of the light carbon isotope.     

Avoiding deforestation in Panamanian protected areas: An analysis of protection effectiveness and implications for reducing emissions from deforestation and forest degradation

Reducing greenhouse gas emissions from deforestation and forest degradation (REDD) is likely to be central to a post-Kyoto climate change mitigation agreement. As such, identifying conditions and factors that will shape the success or failure of a reduced deforestation scheme will provide important insights for policy planning. Given that protected areas (PAs) are a cornerstone in forest conservation, we draw on interviews and secondary data to analyze the effects of available PA resources, governance ability, the level of community involvement, and provincial deforestation rates on land-cover change in nine PAs in Panama. Our results illustrate that coupling surveillance measures with greater funding and strong governance are paramount to reducing deforestation. Alone, however, these factors are insufficient for forest protection. We argue that conservation approaches that complement effective surveillance with community participation and equitable benefit sharing will address the wider issues of leakage and permanence.     

Evolution of photoautotrophy and early atmospheric oxygen levels

Current photochemical models suggest that oxygen levels in the prebiological atmosphere were extremely low, most probably remaining in the range 10⁻⁸–10⁻¹⁴ PAL (present atmospheric level). It is, therefore, reasonable to assume that only life processes were able to overwhelm these minor O₂-pressures, with free oxygen resulting from the reduction of carbon dioxide to the carbohydrate level during photoautotrophic carbon fixation using water as an electron donor (

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). It is by now well established that reduced (organic) carbon is a common constituent of sedimentary rocks from the very start of the geological record 3.8 Ga ago. Both direct assays and inferences derived from a carbon isotope mass balance suggest that the C_org-content of Archaean sediments was not basically different from that of geologically younger rocks. This poses the problem of the existence 3.5 Ga ago of an oxidation equivalent of such a formidable ancient C_org-reservoir which, depending on the model adopted for the growth of the sedimentary mass through time, might have amounted to between 20 and 100% of the present one. Low atmospheric oxygen pressures in the Early Precambrian that are inferred from retarded oxidation reactions, notably in the ancient continental weathering cycle, are likely, therefore, to indicate extremely rapid processes of oxygen consumption in other parts of the system (e.g., hydrosphere) rather than the general absence of photosynthetic oxidation equivalents during this time.     

(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.     

Skin toxins in coral‐associated Gobiodon species (Teleostei: Gobiidae) affect predator preference and prey survival

Predation risk is high for the many small coral reef fishes, requiring successful sheltering or other predator defence mechanisms. Coral‐dwelling gobies of the genus Gobiodon live in close association with scleractinian corals of the genus Acropora. Earlier studies indicated that the low movement frequency of adult fishes and the development of skin toxins (crinotoxicity) are predation avoidance mechanisms. Although past experiments showed that predators refuse food prepared with goby skin mucus, direct predator–prey interactions have not been studied. The present study compares the toxicity levels of two crinotoxic coral gobies – Gobiodon histrio, representative of a conspicuously coloured species, and Gobiodon sp.3 with cryptic coloration – using a standard bioassay method. The results show that toxin levels of both species differ significantly shortly after mucus release but become similar over time. Predator preferences were tested experimentally in an aquarium in which the two gobies and a juvenile damselfish Chromis viridis were exposed to the small grouper Epinephelus fasciatus. Video‐analysis revealed that although coral gobies are potential prey, E. fasciatus clearly preferred the non‐toxic control fish (C. viridis) over Gobiodon. When targeting a goby, the predator did not prefer one species over the other. Contrary to our expectations that toxic gobies are generally avoided, gobies were often captured, but they were expelled quickly, repeatedly and alive. This unusual post‐capture avoidance confirms that these gobies have a very good chance of surviving attacks in the field due to their skin toxins. Nonetheless, some gobies were consumed: the coral shelter may therefore also provide additional protection, with toxins protecting them mainly during movement between corals. In summary, chemical deterrence by crinotoxic fishes seems to be far more efficient in predation avoidance than in physical deterrence involving body squamation and/or strong fin spines.     

Eddy viscosity and turbulent Schmidt number by kink-type instabilities of toroidal magnetic fields

The potential of the non-axisymmetric magnetic instability to transport angular momentum and to mix chemicals is probed considering the stability of a nearly uniform toroidal field between conducting cylinders with different rotation rates. The fluid between the cylinders is assumed as incompressible and to be of uniform density. With a linear theory, the neutral-stability maps for   m = 1  are computed. Rigid rotation must be sub-Alfvénic to allow instability, while for differential rotation also an unstable domain with faster rotation exists [azimuthal magnetorotational instability (AMRI)]. The rotational quenching of the magnetic instability is strongest for magnetic Prandtl number of the order of unity.
The effective angular momentum transport by the instability is directed outwards for subrotation. The resulting magnetic-induced eddy viscosity exceeds the microscopic values by factors of 10–100. This is only true for AMRI; in the opposite case of Tayler instability, the viscosity results are very small.
The same instability also quenches concentration gradients of chemicals by dynamic fluctuations. The corresponding diffusion coefficient always remains smaller than the magnetic-generated eddy viscosity. A Schmidt number of the order of 30 is found as the ratio of the effective viscosity and the diffusion coefficient. For not too strong magnetic fields in the radiation zone of young solar-type stars, the magnetic instability transports much more angular momentum than that it mixes chemicals.