On the Vp/Vs–Mg# correlation in mantle peridotites: Implications for the identification of thermal and compositional anomalies in the upper mantle

We use thermodynamically self-consistent and hybrid methods to analyze the correlation of important physical parameters (e.g. bulk density, elastic moduli) with bulk Mg# and modal composition in mantle peridotites at upper mantle conditions. Temperature (anharmonic and anelastic), pressure and compositional derivatives for all these parameters are evaluated. The results show that the widely used correlations between Vp/Vs and Mg# in peridotites are strictly valid only for garnet-bearing assemblages at temperatures < 900 °C. The correlation breaks down when: i) spinel is the stable Al-rich phase in the assemblage and ii) when anelastic attenuation of seismic velocities becomes important (T ? 900 °C). This implies that the range of applicability of published Vp/Vs–Mg# correlations for the upper mantle is limited to a depth interval between the spinel–garnet phase transition and the 900 °C isotherm. We use numerical simulations to show that this depth interval is virtually nonexistent in lithospheres thinner than ～ 140 km and can comprise up to ～ 50% of the lithospheric mantle in thick (> 220 km) lithospheric domains. In addition, we show that for most of the upper mantle the expected Δ(Vp/Vs) values associated with compositional variations are smaller than the resolution limit of current seismological methods. All these considerations suggest that the Vp/Vs ratio is not a reliable measure of compositional variations and that for large parts of the upper mantle compositional anomalies cannot be separated from thermal anomalies on the basis of seismological studies only. We further confirm that the only reliable indicator of compositional anomalies in a peridotitic mantle is the ratio of density to shear wave velocities (ρ/Vs). Our results demonstrate that geophysical–petrological models (forward or inverse) that model these two fields (i.e. density and Vs) self-consistently within a robust thermodynamic framework are necessary for characterizing the small-scale thermal and compositional structure of the lithosphere and sublithospheric upper mantle.     

PCBs and organochlorine pesticides in Hector’s (Cephalorhynchus hectori hectori) and Maui’s (Cephalorhynchus hectori maui) dolphins

Polychlorinated biphenyls (PCBs) and organochlorine (OC) pesticide levels were determined in blubber samples collected from stranded and incidentally by-caught Hector’s (Cephalorhynchus hectori hectori) and Maui’s (Cephalorhynchus hectori maui) dolphins from New Zealand waters between 1997 and 2009. PCBs (45 congeners) and a range of OC pesticides including dieldrin, hexachlorocyclohexane (HCH) and dichlorodiphenyltrichloroethane (DDT), along with its metabolites DDE and DDD were determined. OC pesticides dieldrin, p,p′-DDE, p,p′-DDD and p,p′-DDT were present at the highest concentrations. Sum DDT concentrations ranged from 93.7 to 8210 (Mean = 1358, S.D = 1974) and 252.4 to 57,390 (Mean = 12,389, S.D = 18,161) μg/kg wet weight in females and males, respectively. Similarly, Σ45CB concentrations ranged from 45.5 to 981.3 (Mean = 333.2, S.D = 265.8) and 60.5 to 5574 (Mean = 1833, S.D = 1659) μg/kg wet weight in females and males, respectively. The transfer of ΣDDTs and summed PCBs (both as ΣICES7CBs and Σ45CBs) between a pregnant female and her unborn fetus was calculated at 5.7% and 4.3%, respectively. As the fetus was close to term, this likely represents the degree of placental transfer. Concentrations of OC pesticides determined in the present study are higher than those previously reported for Hector’s dolphins. Sum DDT and DDE/ΣDDT levels calculated reveal New Zealand’s legacy of DDT usage, particularly off the east coast of the South Island.     

Insights in the exhumation history of the NW Zagros from bedrock and detrital apatite fission‐track analysis: evidence for a long‐lived orogeny

We present the first fission‐track (FT) thermochronology results for the NW Zagros Belt (SW Iran) in order to identify denudation episodes that occurred during the protracted Zagros orogeny. Samples were collected from the two main detrital successions of the NW Zagros foreland basin: the Palaeocene–early Eocene Amiran–Kashkan succession and the Miocene Agha Jari and Bakhtyari Formations. In situ bedrock samples were furthermore collected in the Sanandaj‐Sirjan Zone. Only apatite fission‐track (AFT) data have been successfully obtained, including 26 ages and 11 track‐length distributions. Five families of AFT ages have been documented from analyses of in situ bedrock and detrital samples: pre‐middle Jurassic at ～171 and ～225 Ma, early–late Cretaceous at ～91 Ma, Maastrichtian at ～66 Ma, middle–late Eocene at ～38 Ma and Oligocene–early Miocene at ～22 Ma. The most widespread middle–late Eocene cooling phase, around ～38 Ma, is documented by a predominant grain‐age population in Agha Jari sediments and by cooling ages of a granitic boulder sample. AFT ages document at least three cooling/denudation periods linked to major geodynamic events related to the Zagros orogeny, during the late Cretaceous oceanic obduction event, during the middle and late Eocene and during the early Miocene. Both late Cretaceous and early Miocene orogenic processes produced bending of the Arabian plate and concomitant foreland deposition. Between the two major flexural foreland episodes, the middle–late Eocene phase mostly produced a long‐lasting slow‐ or nondepositional episode in the inner part of the foreland basin, whereas deposition and tectonics migrated to the NE along the Sanandaj‐Sirjan domain and its Gaveh Rud fore‐arc basin. As evidenced in this study, the Zagros orogeny was long‐lived and multi‐episodic, implying that the timing of accretion of the different tectonic domains that form the Zagros Mountains requires cautious interpretation.     

The interstellar extinction and distance modulus to M10 from infrared photometry

From a new infrared photometry of the globular cluster M10 its interstellar extinction and distance modulus are discussed. This is done by comparison with the well-studied clusters M3, M13, and M92. Final values ofE(B-V)=0.17±0.05 and (M _v-V)=14.0±0.3 are proposed. The dependence on metallicity of these values is briefly discussed.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain     

Lower Paleozoic extensional tectonics in the limit between the West Asturian-Leonese and Central Iberian Zones of the Variscan Fold-Belt in NW Spain

The limit between the West Asturian-Leonese and Central-Iberian Zones in the NW of the Iberian Peninsula is described in the area of Caurel-Truchas (Provinces of Orense and León). From the distribution of the sedimentary formations and the Variscan structures it is inferred that the transition between the two zones was a fault system, which was active during, at least, the Ordovician and Lower Silurian. The faults were supposedly normal, though they had probably some strike-slip component, and gave rise to a half-graben in which a syn-rift sequence was deposited. The latter underwent inversion at the onset of the Variscan tectonism, producing a ramp anticline-syncline pair that forms the more important folds in the area. The varying geometry of these folds is interpreted partly as being due to the existence of previous en échelon folds related to the strike-slip component of the faults and, partly, as a result of the variable intensity of the shear strain undergone during the first variscan phase.

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Zusammenfassung Die Grenze zwischen der West-Asturischen-Leonesischen und Zentral-Iberischen Zone im NW der Iberischen Halbinsel wird aus dem Gebiet von Caurel-Truchas (Provinz Orense und León) beschrieben. Aufgrund der Verteilung der sedimentären Formationen, sowie der variszischen Strukturen wird abgeleitet, daß der Übergang zwischen den beiden Zonen durch ein Störungssystem bedingt wurde, das zumindest zwischen Ordovizium und Untersilur aktiv war. Dabei handelte es sich vermutlich um Abschiebungen mit einer Horizontalverschiebungskomponente. Diese Ausbildung führte zu einem Halbgraben mit darin abgelagerter sedimentärer Syn-Riftsequenz. Letztere wurde während der Anfangsphase der variszischen Tektonik invertiert, so daß es zu einem Rampen-Antiklinal-Synklinal Paar kam, welches die wichtigsten Falten der Gegend bildet. Die variable Geometrie der Falten wird zum einen der Existenz von frühen En-échelon Falten zugeschrieben, die durch die Horizontalverschiebungskomponente der Störungen hervorgerufen wurden; zum anderen sind sie das Resultat der veränderlichen Intensität der Scherspannung während der ersten variszischen Phase.

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Resumen Se describe el límite entre las Zonas Asturoccidental-Leonesa y Centroibérica en el NO de la Península Ibérica en el área del Caurel-Truchas (Provincias de Orense y León). Partiendo de la distribución de las formaciones sedimentarias y de la geometría de las estructuras varíscicas, se deduce que la transición entre las dos zonas fue un sistema de fallas, que fue activo al menos durante el Ordovício y el Silúrico Inferior. Se supone que la principal componente de las fallas fue normal, aunque debió de existir también una componente de desgarre, y su juego originó un semi-graben en el que se acumuló una secuencia sin-rift. Esta última experimentó una inversión al principio de la tectogénesis Varíscica, formándose un par de pliegues de rampa que son los pliegues más importantes del área. La geometría variable de esos pliegues se interpreta como debida, en parte, a la existencia previa de pliegues en escalón relacionados con la componente de desgarre de las fallas y, en parte, como consecuencia de la variable intensidad de la deformación por cizallamiento sufrida durante la primera fase de deformación varíscica.

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The oldest galactic open clusters: New CCD photometry and colour-magnitude diagrams

We present CCD photometry for stars in three fields centered on the old open cluster NGC 188 and in four fields on the intermediate-age cluster NGC 7789, which has been performed with the aim of investigating the HR diagram distribution of the cluster's Main-Sequence (MS) stars. A sufficiently well-defined sequence of subgiant, turn-off (TO), and MS stars have been detected, extending the observed lower MS down to aboutV=20 mag.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Direct barite determination using SEM/EDS-ACC system: implication for constraining barium carriers and barite preservation in marine sediments

Barite (BaSO₄) in marine sediments is considered as a proxy of surface ocean productivity and is widely used for paleo-productivity reconstructions. However, direct barite determination is not achieved by currently used methods, which rely on the measurement of total barium by inductively coupled plasma–mass spectrometry (ICP-MS) and instrumental neutron activation analysis (INAA) and correction from the allogenic Ba contribution. We report here on a technique that directly counts individual barite crystals using a scanning electron microscope (SEM) coupled to an energy dispersive spectrometer (EDS) equipped with an automated particle counting and classification (ACC) system. We show that barite–Ba concentrations can be deduced from the abundance, shape and size distributions of barite crystals with current precision and sensitivity as high as ±5 wt.% (2σ confidence limit) and 10 ppm, respectively. This technique, coupled with ICP-MS and INAA techniques for total Ba measurements, was applied to sediment samples from the tropical North Atlantic and the Central North Pacific oceans. Results show that: (1) barite and detrital aluminosilicates are the two main carriers of Ba in the investigated sediments; (2) calculated Ba/Al ratios range from 0.005 to 0.008 with an average value around 0.0066, in close agreement with previously reported values; (3) barite might not be the major source for released barium out of sediments and we suggest instead adsorbed barium as a potential source.     

Marine systems: moving into the genomics era

The study of biological systems has been revolutionized by the use of genomic technologies. Most of the knowledge gathered over the last few years refers to terrestrial models. The study of marine systems using genomic technologies has, apart from a focus on microbial systems, been generally neglected although there are signs that this situation may be changing. This review analyses recent progress made in the field of marine genomics and identifies the broad areas in which this new technology is having the greatest impacts. These studies include comparative, functional and environmental genomics of metazoan animals. In many cases, as well as benefiting marine science, studies on marine taxa are having wide‐ranging impacts on our global understanding of genomes and genomics.     

Wavimeter

A method of extracting wave parameters from surface displacement measured from a moving platform is presented. The article first presents a method for accurately measuring surface displacement using a single beam altimeter and heave sensor. A least squares approach is presented to estimate wave parameters using vessel velocity and perceived wave frequency that eliminates Doppler due to vessel motion. Two techniques for estimating wave frequency are presented: a block data method using MUSIC and a real-time method using demodulation. Sea trial results demonstrate that this method is as effective as a WaveRider buoy for estimating wave parameters.     

Benzo[a]pyrene-dione-stimulated oxyradical production by microsomes of digestive gland of the common mussel, Mytilus edulis L

The potential of benzo[ a]pyrene (BaP) quinones (diones) to stimulate NAD(P)H-dependent hydroxyl radical (·OH) production (2-keto-4-methiolbutyric acid (KMBA) oxidation) by digestive gland microsomes of M. edulis was studied using iron/EDTA as a promotor of the Haber-Weiss reaction (O₂⁻ + H₂O₂ = ·OH + OH⁻ + O₂). Stimulation of basal rates of KMBA oxidation was observed for all three diones. Stimulation was similar for the 1,6- and 3,6-diones, but much less for the 6,12-dione, and greater for the NADH than the NADPH-dependent reaction, viz. % increases of 78 to 333 (NADH) compared to 0 to 78 (NADPH). Maximal KMBA oxidation was obtained at dione concentrations of 12.5 to 50 μm. Inhibition of KMBA oxidation by Superoxide dismutase and catalase indicated the involvement of respectively Superoxide anion radical (O₂⁻) and hydrogen peroxide (H₂O₂) in 1,6-dione stimulated NADPH-dependent · OH formation. The apparent K_m values of xenobiotic-stimulated KMBA oxidation were lower for BaP-diones than for the model redox cycling quinone menadione (2-methyl-1,4-naphthoquinone), viz. in μm, 0.6 to 14.6 (NADH) and 4.4 to 28.5 (NADPH) compared to 315 to 457 (NADH) and 72 to 103 (NADPH). The results are consistent with metabolism of BaP to diones and resultant enhanced generation of oxyradicals being a potential mechanism of pollutant-mediated toxicity in molluscs.