Atmospheric Pb pollution in N Iberia during the late Iron Age/Roman times reconstructed using the high-resolution record of La Molina mire (Asturias, Spain)

Extensive mining took place in Spain during the Iron Age and Roman times, although a detailed chronology is still lacking due to the inherent difficulties in dating mining structures. In this study we sampled and analyzed a core from La Molina mire in the Asturias region, northern Spain. Because more than 100 Roman mines have thus far been found within 20 km of the mire, our aim was to shed light on local mining history, which we can then compare to the wider narrative of early mining pollution in Spain. We focus on the section from ~500 BC to AD ~600, which has a high temporal resolution of 6–15 year per sample. Geochemical analyses included the determination of major, minor and trace lithogenic elements (Si, Al, Fe, Ti, Ga, Rb, Y, Zr, Th) as markers of mineral content of the peat, and trace metals/metalloids (Mn, Cu, Ni, As, Pb) as well stable Pb isotopes, as potential markers of atmospheric metal pollution. The use of principal components analysis enabled the identification of a dominant geogenic component and a secondary pollution component. The earliest pollution signal of the covered period was recorded by ~300 BC, coinciding with the late local Iron Age. Average ²⁰⁶Pb/²⁰⁷Pb ratios of samples with ages older than this date was 1.204 ± 0.002, while all samples with a younger age had a less radiogenic ratio. Based on the metal pollution component four phases were identified: I, ~500 to 300 BC; II, ~300 to 20 BC; III, ~20 BC–AD 480; IV, AD ~480 to 600. The lowest isotopic ratio and highest proportion of pollution Pb (²⁰⁶Pb/²⁰⁷Pb ratio of 1.157 and 89 % of total accumulated Pb) was reached at peak Pb production during Roman times (AD ~180 to 340), indicating that this was the period of most intense metal contamination in the area over the studied period. It is remarkable that the La Molina record shows a more extended period (two centuries) of active mining in comparison with other areas in Iberia, and a pattern of repeated shifts in Pb pollution of short duration, which is likely related to the local history of exploitation and exhaustion of mines within the area.     

Book review

Past, Present and Future Trends in Geophysical Research: Selected Papers from the Symposia of the Interdivisional Commission on History of IAGA during the IUGG General Assembly held in Vancouver, 1987. Ed. Wilfried Schroder     

Induction in arbitrarily shaped oceans — IV. Sq for a simple case

Summary. World curves are presented of electric currents induced in electrically insulated oceans by Sq using a perfectly conducting sphere to simulate the underlying mantle. The curves are valid everywhere away from those coastal regions at which the sea bed rises steeply. In such cases an edge correction may be needed. The numerical computations are for periods of 6, 8, 12 and 24 hr and comparison is made with results obtained by others for a 24-hr period. Circulation conditions around the island are ignored in this note.     

Geomagnetic variations with the period of a sidereal day

Recent determinations of sidereal-day variations in the geomagnetic field have been attributed to galactic sources of ionisation. Alternative mechanisms that could equally well account for the observed variations are presented, based on solar and lunar tides.     

Changes in geomagnetic multipole parameters 1942.5–1962.5

Summary From a smooth series of spherical harmonic coefficients for the geomagnetic potential, the corresponding multipole parameters have been calculated for five epochs from 1942.5 until 1962.5, at five year intervals. Changes in multipole parameters are discussed in relation to the secular variation field and to theSchmidt eccentric dipole.     

Assessment of regional geomagnetic field modelling methods using a standard data set: spherical cap harmonic analysis

Various methods that take account of the potential nature of the field have been proposed for modelling geomagnetic data on a regional scale. Several of these have been applied to a standard data set based on annual mean values from observatories in Europe. Here, we examine some of the properties of spherical cap harmonic analysis when applied to this data set, and compare the quality of fit with that of the other models. It is found that, for this data set, rectangular polynomial analysis provides a compact fit to main field data, but that in most other cases, for both main field and anomaly data, spherical cap harmonic analysis provides the better fit. Although relatively insensitive to chosen cap size, spherical cap harmonic analysis deteriorates more rapidly than the other methods when the number of coefficients is reduced.     

Observed geomagnetic field intensity in London since 1820

Our main purpose is to collect all magnetic intensity data observed in the vicinity of London and to adjust these to a common site (Greenwich) to complement the 400-year series of declination ( D ) and inclination ( I ) data of Malin & Bullard (1981 ). The present series is necessarily shorter, since a method for the measurement of intensity in absolute units was not devised until 1832. We have also supplemented the D and I series of Malin & Bullard with recently acquired data.
We have also made observations of D , I and total intensity ( F ) at a number of the sites, partly to bring the series up to date and partly to check on the site differences. With the increasing urbanization of London it is necessary to seek data from remoter sites. It is shown that the site differences change significantly with time, but that allowance can be made for this.
We present curves of our best estimates of the variation of D , I , F and the horizontal intensity ( H ) that define the complete geomagnetic vector at Greenwich for the interval 1820–1998. Frequency analysis shows little support for a 60-year line in the power spectrum. Within the uncertainty of their determinations, there is good continuity between archaeomagnetic intensity measures and the present results. The moving eddy hypothesis of Malin & Bullard is found to be untenable.     

Determinations of dimethylsulphoniopropionate (DMSP) lyase activity using headspace analysis of dimethylsulphide (DMS)

The osmolyte dimethylsulphoniopropionate (DMSP) can be enzymatically cleaved to dimethylsulphide (DMS), acrylate and a proton. The enzyme involved in this reaction is dimethylpropiothetin dethiomethylase (DMSP lyase; enzyme classification number 4.4.1.3.). Although the importance of this reaction for the global sulphur cycle, the influence of DMS on atmospheric acidity and the possible effect on climate regulation have been widely recognised, our knowledge of DMSP lyases is limited to just a few studies. Activity measurements of DMSP lyases offer an important step towards a better understanding of the conditions under which DMS is produced. In the available published data somewhat similar methods have been used before, but a critical examination of the method limitations has not been reported. To encourage further research on this enzyme, we suggest and detail two protocols for measurements of DMSP lyase activity: An in vitro assay for crude cell extracts or purified enzyme and an in vivo method for whole cells, which we recently started to use. After addition of DMSP, samples incubated in a gas tight vial may produce DMS from enzymatic cleavage under suitable conditions, and a DMS production rate can be estimated from time-series measurements of DMS in the headspace of the vial. Headspace analysis of DMS is a useful and rapid technique to estimate and compare DMSP lyase activities from different sources. The relative rates of DMS production in the liquid and of the gas transfer between liquid and headspace, determine the rate of DMS production measured via headspace analysis. If DMS production in the liquid is higher than the rate of transfer, headspace measurements will not reflect the actual amount of DMS produced in the liquid. In this case, extracts have to be diluted to a level that ensures linearity between dilution factor and reduction of enzyme activity. Additionally, incubation volumes and vials should be selected to provide a high surface-to-volume ratio to ensure maximum flux of DMS from the aqueous phase into the headspace. The methods can be adapted to further investigate species- and strain-specific activities, biogeographical distribution, cellular location and biochemical properties of various DMSP lyases.