Stepwise mass extinctions: the case for the Late Cenomanian event

The various extinctions of marine taxa in the Late Cenomanian can be shown as conforming to the 'step-wise extinction' model. The order of such extinctions is, however, compatible with the presence of an expanded oxygen minimum zone in the world ocean. The occurrence of iridium anomalies at this level in the succession may, however, indicate a volcanogenic control on the global environment. Detailed time-analysis of the Late Cenomanian event has been used to produce a correlation of some key successions.     

A three-dimensional numerical model of particulate transport for coastal waters

A Lagrangian marker particle in Eulerian finite difference cell solution to the three-dimensional incompressible mass transport equation was developed for predicting particulate transport in coastal and estuarine waters. Special features of the solution procedure include a finite difference grid network which translates horizontally and vertically with the mean particle motion and expands with the dispersive growth of the marker particle cloud. The cartesian vertical coordinate of the three-dimensional mass transport equation has been transformed, using instantaneous water column depth to allow adaptation to flow situations with a temporally and spatially varying bottom topography and free surface. Results from this model for turbulent diffusion and advection of a uniform plug flow of sediment in an unbounded uniform flow field with various sediment settling velocities were in excellent agreement with the corresponding analytic solutions. Using current information from a two-dimensional vertically averaged hydrodynamic's model, the model was utilized to predict the long term diffusion and advection of dilute neutrally and negatively buoyant suspended sediment clouds resulting from a hypothetical instantaneous release of dredge spoil waste at Brown's Ledge in Rhode Island Sound.     

An integrated approach for evaluating the effectiveness of landslide risk reduction in unplanned communities in the Caribbean

Despite the recognition of the need for mitigation approaches to landslide risk in developing countries, the delivery of ‘on-the-ground’ measures is rarely undertaken. With respect to other ‘natural’ hazards, it is widely reported that mitigation can pay. However, the lack of such an evidence base in relation to landslides in developing countries hinders advocacy amongst decision makers for expenditure on ex-ante measures. This research addresses these limitations directly by developing and applying an integrated risk assessment and cost–benefit analysis of physical landslide mitigation measures implemented in an unplanned community in the Eastern Caribbean. In order to quantify the level of landslide risk reduction achieved, landslide hazard and vulnerability were modelled (before and after the intervention), and project costs, direct and indirect benefits were monetised. It is shown that the probability of landslide occurrence has been substantially reduced by implementing surface-water drainage measures and that the benefits of the project outweigh the costs by a ratio of 2.7–1. This paper adds to the evidence base that ‘mitigation pays’ with respect to landslide risk in the most vulnerable communities—thus strengthening the argument for ex-ante measures. This integrated project evaluation methodology should be suitable for adoption as part of the community-based landslide mitigation project cycle, and it is hoped that this resource, and the results of this study, will stimulate further such programmes.     

Phosphate defects and apatite inclusions in coral skeletal aragonite revealed by solid-state NMR spectroscopy

Recent development of paleo-nutrient proxies based on the phosphorus/calcium (P/Ca) ratio in tropical- and deep-water corals (also known as cold-water corals) require an understanding of the processes by which P is incorporated into the coral skeletal aragonite. Here, we apply single- and double-resonance solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the speciation of P in coral aragonite. The results show that the majority of P occurs as phosphate defects in the aragonite structure, but in many samples a significant fraction of the P occurs also in crystalline hydroxylapatite inclusions. Quantification of the amount of hydroxylapatite indicates that its presence is not related simply to external environmental factors and that it can occur at varying abundances in different parts of the same corallite. Since there is currently no model available to describe the relationship between dissolved inorganic phosphate and its incorporation as apatite inclusions into carbonates, careful screening of samples which contain only phosphate in the aragonite structure or selective microsampling could improve proxy development.     

Feasibility of AFC models for the petrogenesis of calc-alkaline magma series

 One of the most popular petrogenetic concepts is that of simultaneous assimilation and fractional crystallisation (AFC). The equations governing these processes are well known and widely applied. The power and attraction of the model are that, with the minimum of constraints, petrogenetic schemes can be erected for essentially any group of rocks. These models are usually based on the observed variations in a small number of trace elements and/or isotopic systems. In this paper we have generated well-constrained AFC models for the Variscan, calc-alkaline Quérigut complex in the French Pyrénées. Our models are based on geological constraints on the identities of the parent magma and candidate assimilants, and the Sm-Nd and Rb-Sr isotope systematics of the rocks. The modelling is successful in mimicking the isotope array for the actual rocks. However, the results are massively inconsistent with those produced using the major- and trace-element concentrations. Our major conclusion is that AFC modelling should be undertaken only with robust initial constraints on the compositions of the parent magma and the proposed assimilant, with due respect for crystal-liquid partition coefficients, in so far as they are known. The results should then be accepted only if the isotope-based model parameters are consistent with those derived from major- and trace-element variations. Received: 19 August 1994/Accepted: 23 March 1995     

A powder neutron diffraction study of the crystal structure of the fluoroperovskite NaMgF<Subscript>3</Subscript> (neighborite) from 300 to 3.6 K

The cell dimensions and crystal structures of the fluoroperovskite NaMgF₃ (neighborite), synthesized by solid state methods, have been determined by powder neutron diffraction and Rietveld refinement over the temperature range 300–3.6 K using Pt metal as an internal standard for calibration of the neutron wavelength. These data show that Pbnm NaMgF₃ does not undergo any phase transitions to structures of lower symmetry with decreasing temperature. The cell dimensions and atomic coordinates together with polyhedron volumes and distortion indices are given for Pbnm NaMgF₃ at 25 K intervals from 300 to 3.6 K. Decreases in the a and c cell dimensions reach a saturation point at 50 K, whereas the b dimension becomes saturated at 150 K. The distortion of the structure of Pbnm NaMgF₃ from the aristotype cubic structure is described in terms of the tilting of the MgF₆ octahedra according to the tilt scheme a ⁻ a ⁻ c ⁺ . With decreasing temperature the antiphase tilt (a ⁻) increases from 14.24° to 15.39°, whereas the in-phase tilt (c ⁺ ) remains effectively constant at ∼10.7°. Changes in the tilt angles are insufficient to cause changes in the coordination sphere of Na that might induce a low temperature phase transition. The structure of Pbnm NaMgF₃ is also described in terms of normal mode analysis and displacements of the condensed normal modes are compared with those of Pbnm KCaF₃.