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61.
Measurement of Ba isotope ratios of widely available reference materials is required for interlaboratory comparison of data. Here, we present new Ba isotope data for thirty‐four geological reference materials, including silicates, carbonates, river/marine sediments and soils. These reference materials (RMs) cover a wide range of compositions, with Ba mass fractions ranging from 6.4 to 1900 µg g?1, SiO2 from 0.62% to 90.36% m/m and MgO from 0.08% to 41.03% m/m. Accuracy and precision of our data were assessed by the analyses of duplicate samples and USGS rock RMs. Barium isotopic compositions for all RMs were in agreement with each other within uncertainty. The variation of δ138/134Ba in these RMs was up to 0.7‰. The shale reference sample, affected by a high degree of chemical weathering, had the highest δ138/134Ba (0.37 ± 0.03‰), while the stream sediment obtained from a tributary draining carbonate rocks was characterised by the lowest δ138/134Ba (?0.30 ± 0.05‰). Geochemical RMs play a fundamental role in the high‐precision and accurate determination of Ba isotopic compositions for natural samples with similar matrices. Analyses of these RMs could provide universal comparability for Ba isotope data and enable assessment of accuracy for interlaboratory data. 相似文献
62.
Delphine Yeghicheyan Cécile Bossy Martine Bouhnik Le Coz Chantal Douchet Guy Granier Alexie Heimburger Francois Lacan Aurélie Lanzanova Tristan C. C. Rousseau Jean‐Luc Seidel Mickaël Tharaud Frédéric Candaudap Jérôme Chmeleff Christophe Cloquet Sophie Delpoux Marie Labatut Rémi Losno Catherine Pradoux Yann Sivry Jeroen E. Sonke 《Geostandards and Geoanalytical Research》2013,37(4):449-467
The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. 相似文献
63.
Weihan Li Jian‐Ming Zhu Decan Tan Guilin Han Zhouqiao Zhao Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535
The high‐precision δ60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ60/58Ni NIST SRM 986 values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories. 相似文献
64.
The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma. 相似文献
65.
Fang‐Yue WANG Cong‐Ying LI Ming‐Xing LING Hong ZHANG Ya‐Li SUN Weidong SUN 《Resource Geology》2011,61(4):414-423
Xihuashan tungsten deposit is one of the earliest explored tungsten deposits in southeastern China. It is a vein type deposit genetically associated with the Xihuashan granite pluton. Here we report new dating and zircon geochemistry results. Re–Os isotopic dating for molybdenite intergrowth with wolframite in the oldest generation of the Xihuashan pluton yielded an isochron age of 157.0 ± 2.5 Ma (2σ). Zircon U–Pb laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) dating shows that the pluton crystallized at 155.7 ± 2.2 Ma (2σ). This age is similar to the molybdenite Re–Os age for the ore deposit within error. This, together with published data, suggests that the major W(Mo)‐Sn mineralization occurred between 160–150 Ma in southeastern China. These deposits constitute a major part of the magmatic‐metallogenic belt of eastern Nanlin. The lower Re content in molybdenite of the Xihuashan tungsten deposit shows crustal origin for the ore‐forming material. The limited direct contributions from the subducting slab for the tungsten mineralization in the Nanling region suggest a change of the style of the paleo‐Pacific plate beneath southeastern China. 相似文献
66.
In this study we analyzed runoff and sediment yield from land under various traditional and current land uses in Mediterranean mountain areas, using long‐term data from an experimental station in the Aísa Valley, Central Spanish Pyrenees. Monitoring at this station has provided 20 years of data that can help explain the hydrological and geomorphological changes that have been observed at larger spatial scales, and also the changes that have occurred to some of the most characteristic landscapes of the Mediterranean middle mountains. In spite of the problems associated with the use of small experimental plots, the results obtained are consistent with other studies in the Mediterranean region, and confirm the strong influence of land use changes on runoff generation and sediment yield. The results indicate that: (i) cereal cultivation on steep slopes (both alternating cereal cultivation and fallow on sloping fields and shifting agriculture on the steepest slopes) represents a major problem for soil conservation. This explains the occurrence throughout the Mediterranean mountains of many degraded hillslopes, which show evidence of sheet wash erosion, rilling, gullying and shallow landsliding; (ii) farmland abandonment has led to a marked reduction in runoff and sediment yield as a consequence of rapid plant recolonization, particularly by dense shrubs; (iii) the natural transformation of abandoned fields into grazing meadows has reduced runoff and sediment yield. Land use trends in the Mediterranean mountains are mainly characterized by generalized farmland abandonment and a decrease in livestock pressure. From a hydrological and geomorphological point of view the main consequences have been a reduction in overland flow from the hillslopes, and a reduction in sediment sources, with differences up to one order of magnitude in sediment yield from dense shrub cover and grazing meadow areas compared with areas under shifting agriculture. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
67.
Stephane C. Alfaro Valentina Flores‐Aqueveque Gilles Foret Sandrine Caquineau Gabriel Vargas Jose A. Rutllant 《地球表面变化过程与地形》2011,36(7):923-932
As previously observed in marine sediments collected downwind of African or South American continental sources, recent studies of sediment cores collected at the bottom of Mejillones Bay in north Chile (23°S) show a laminated structure in which the amount of particles of aeolian origin and their size create significant differences between the layers. This suggests inter‐annual to inter‐decadal variations in the strength of the local southerly winds responsible for (1) the erosion of the adjacent hyperarid surface of the Mejillones Pampa, and (2) the subsequent transport of the eroded particles towards the bay. A simple model accounting for the vertical uptake, transport, and deposition of the particles initially set into motion by wind at the surface of the pampa is proposed. This model, which could be adapted to other locations, assumes that the initial rate of (vertical) uptake is proportional to the (horizontal) saltation flux quantified by means of White's equation, that particles are lifted to a height (H), increasing with the magnitude of turbulence, and that sedimentation progressively removes the coarsest particles from the air column as it moves towards the bay. In this model, the proportionality constant (A) linking the vertical flux of particles with the horizontal flux, and the injection height (H) control the magnitude and size distribution of the deposition flux in the bay. Their values are determined using the wind speed measured over the pampa and the size distribution of particles collected in sediment traps deployed in the bay as constraints. After calibration, the model is used to assess the sensitivity of the deposition flux to the wind intensity variations. The possibility of performing such quantitative studies is necessary for interpreting precisely the variability of the aeolian material in the sediment cores collected at the bottom of Mejillones Bay. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
68.
How to select a limited number of strong ground motion records (SGMRs) is an important challenge for the seismic collapse capacity assessment of structures. The collapse capacity is considered as the ground motion intensity measure corresponding to the drift‐related dynamic instability in the structural system. The goal of this paper is to select, from a general set of SGMRs, a small number of subsets such that each can be used for the reliable prediction of the mean collapse capacity of a particular group of structures, i.e. of single degree‐of‐freedom systems with a typical behaviour range. In order to achieve this goal, multivariate statistical analysis is first applied, to determine what degree of similarity exists between each selected small subset and the general set of SGMRs. Principal Component analysis is applied to identify the best way to group structures, resulting in a minimum number of SGMRs in a proposed subset. The structures were classified into six groups, and for each group a subset of eight SGMRs has been proposed. The methodology has been validated by analysing a first‐mode‐dominated three‐storey‐reinforced concrete structure by means of the proposed subsets, as well as the general set of SGMRs. The results of this analysis show that the mean seismic collapse capacity can be predicted by the proposed subsets with less dispersion than by the recently developed improved approach, which is based on scaling the response spectra of the records to match the conditional mean spectrum. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
69.
70.
Wafa Abouchami Stephen J. G. Galer Tristan J. Horner Mark Rehkämper Frank Wombacher Zichen Xue Myriam Lambelet Melanie Gault‐Ringold Claudine H. Stirling Maria Schönbächler Alyssa E. Shiel Dominique Weis Philip F. Holdship 《Geostandards and Geoanalytical Research》2013,37(1):5-17
Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio 114Cd/110Cd for NIST SRM 3108 lies within ~ 10 ppm Da?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use. 相似文献