Methane,carbon monoxide and methylchloroform in the southern hemisphere

New observational data on CH₄, CO and CH₃CCl₃ in the southern hemisphere are reported. The data are analysed for long term trends and seasonal cycles. CH₃CCl₃ data are used to scale the OH fields incorporated in a two dimensional model, which in turn, is used to constrain the magnitude of a global CH₄ source function. The possible causes of observed seasonality of CH₃CCl₃, CH₄ and CO are identified, and several other aspects of observed CH₄ variability are discussed.Possible future research directions are also given.     

Simulation of groundwater level in a coastal aquifer

Abstract

The groundwater levels can have a significant impact on structures and infrastructures of coastal areas. The simulation of the hydraulic behavior of coastal aquifers is very important due to its specific boundary conditions. In this study, the groundwater level in the Bandar-e-Gaz coastal aquifer in the Gorgan Gulf region located in northern Iran is simulated using the MODFLOW mathematical model. The modeling of the coastal aquifer behavior carried out in two calibrations (steady and unsteady states). The validation periods (unsteady state), the mean absolute error (MAE) and mean bias error (MBE) were used to evaluate the results. The values of MAE and MBE criteria for the steady state were 0.31 (m) and –0.08 (m), while the average of these criteria in the unsteady state in calibration period were 0.46 and –0.39, and in the validation period were 0.42 (m) and –0.31 (m), respectively. The mentioned results confirm the precision of the model for the entire simulation period, they also indicate that the simulation has a limited underestimation behavior. Moreover, it shows that the precision of the results has a negligible variability, which means the simulation also has considerable reliability. The highest and lowest amount of error in the winter and summer seasons are in accordance with the lowest and highest seawater levels, and it shows the significant sea effect on the hydraulic behavior of the coastal aquifer.     

Structural control on syn-rift sedimentation,northwestern Red Sea margin,Egypt

Detailed field mapping of a 120-km-long segment of the northwestern Red Sea margin reveals the existence of a number of sediment-input sites where Lower Miocene sediments form coarse-grained fan delta systems. Localizations of the fan deltas at the sediment-input sites (Wadis Gassus, Guesis, Quwyh and Sharm El Bahari) are controlled by structural and topographic elements, including relay ramps between interacting normal fault segments, cross-trend transfer faults, reactivated Precambrian basement fabrics and the plunge directions of tilted fault blocks. Sedimentary facies and geometrical characteristics of the fan deltas indicate that they are progradational and “Gilbert-type” fan delta systems. Variations in size and composition of the conglomerate clasts reflect the heterogeneous lithologies of the Precambrian basement and pre-rift strata in the source areas along the rift margin. Palaeocurrent data show marked changes in paleoflow directions, from northeast in the northernmost fans to east and southeast directions in the southern fans. This change occurs across the Duwi accommodation zone which formed a topographic high separating the oppositely dipping half-grabens in the study area. The data presented in this paper clearly demonstrates that the structural architecture of the northwestern Red Sea margin together with its related topographic expressions played a fundamental role in controlling the drainage network systems, sediment dispersal and localization of the fan deltas in this part of the rift system.     

Real surface conductivity component as indicator for the hydraulic conductivity

Estimation of hydraulic conductivity from surface resistivity measurements is one of the most difficult and challenging hydrogeophysical targets. The promising side of this relation is the analogy between electric current flow and water flow, whereas the grand ambiguity is the non-dimensionality between both two quantities. Imaginary surface conductivity component is used recently to deduce the hydraulic conductivity via complex resistivity measurements. Since there are similar properties between imaginary (out-of-phase) and real (in-phase) surface conductivity components, the latter is used in this paper to predict the hydraulic conductivity. Two mathematical parameters were determined to express the electrical equivalent of hydraulic conductivity in sand and clay systems based on the mode of electrical double-layer formation in both systems. The reliability of the proposed method is tested through applying on two datasets representing sand and clay systems. The first dataset is a clean sand and gravel aquifer in the Keritis basin in Chania, Crete, Greece. The second is mostly clayey sand aquifer in Wadi El-Assuity, Egypt. Application of the present approach in these two cases resulted in promising nearly identical values with the measured hydraulic conductivity via pumping test or geometric hydraulic conductivity via grain size analysis.     

Leachability of radium-226 from industrial phosphogypsum waste using some simulated natural environmental solutions

This study investigated the leaching of radium-226 from phosphogypsum (PG) waste produced from the fertilizer industry by synthetic solutions that replicate water that may contact the waste in natural conditions. The results indicated that the activity concentration of Ra-226 in the PG was 461 ± 12 Bq kg^?1 and compared with other studies carried out worldwide. The leached percentage of Ra-226 represents the exchangeable fraction loosely bounded in the matrix of the PG waste. The leached fraction of Ra-226 was 6.5 ± 0.6 and 9.0 ± 0.5% when the waste was exposed to rainwater and saline solution, respectively. It is also found that the leaching fraction increased 10–12 ± 0.4% when the waste was exposed to the admixture of saline solution containing Sr²⁺ or Ba²⁺ cations, whereas it was lowered to 4–5 ± 0.5% in the presence of carbonate or sulfate anions. When the PG is used as an economic fertilizer, the irrigation water can leach 7.8 ± 0.6% of Ra-226 that could contribute to plant uptake, thereby to animal and/or human consumption. The primary tests of the drinking water (well and tap resources) consumed by the populations surround the PG facility showed that the activity concentration of Ra-226 was below the minimum detectable activity.     

A quantitative assessment of groundwater resources in the Middle East and North Africa region

The Middle East and North Africa (MENA) region is the world’s most water-stressed region, with its countries constituting 12 of the 15 most water-stressed countries globally. Because of data paucity, comprehensive regional-scale assessments of groundwater resources in the MENA region have been lacking. The presented study addresses this issue by using a distributed ArcGIS model, parametrized with gridded data sets, to estimate groundwater storage reserves in the region based on generated aquifer saturated thickness and effective porosity estimates. Furthermore, monthly gravimetric datasets (GRACE) and land surface parameters (GLDAS) were used to quantify changes in groundwater storage between 2003 and 2014. Total groundwater reserves in the region were estimated at 1.28 × 10⁶ cubic kilometers (km³) with an uncertainty range between 816,000 and 1.93 × 10⁶ km³. Most of the reserves are located within large sedimentary basins in North Africa and the Arabian Peninsula, with Algeria, Libya, Egypt, and Saudi Arabia accounting for approximately 75% of the region’s total freshwater reserves. Alternatively, small groundwater reserves were found in fractured Precambrian basement exposures. As for groundwater changes between 2003 and 2014, all MENA countries except for Morocco exhibited declines in groundwater storage. However, given the region’s large groundwater reserves, groundwater changes between 2003 and 2014 are minimal and represent no immediate short-term threat to the MENA region, with some exceptions. Notwithstanding this, the study recommends the development of sustainable and efficient groundwater management policies to optimally utilize the region’s groundwater resources, especially in the face of climate change, demographic expansion, and socio-economic development.     

A comparison of two models to predict soil moisture from remote sensing data of RADARSAT II

This study investigates the performance of empirical and semiempirical models to predict soil moisture from the data of RADARSAT II synthetic aperture radar (SAR) for the Yarmouk basin in Jordan. Data of SAR were obtained for May and June 2010 and were processed to obtain backscatter (σ ^o ) data for the study area. Results showed significant correlations between soil moisture content (m _v ) and horizontally polarized σ ^o , with coefficient of determination (R ²) of 0.64. The root mean square error for the SAR volumetric soil moisture content was 0.09 and 0.06 m³/m³ for the empirical and semiempirical regression models, respectively. Both models had different clustering patterns in the soil moisture maps in the study area. The spatial agreement between maps of soil moisture was in the range of 55 to 65 % when the maps were reclassified based on intervals of 5 % m _v for both models. In terms of soil moisture interval, both models showed that most of soil moisture changes between the two images (dates) were in the range of ±5 %. Some high differences in ?m _v were observed between the two models. These were mainly attributed to the non-inverted pixels in the soil moisture maps produced by the semiempirical model. Therefore, this model may be applied for a limited range of soil moisture prediction. The use of regression model could predict a wider range for soil moisture when compared with the semiempirical model. However, more work might be needed to improve the empirical model before scaling it up to the whole study area.     

An overview of the diagenesis of the Upper Jurassic carbonates of Jubaila and Hanifa formations, central Saudi Arabia

The Jubaila Formation (Upper Jurassic) in central Saudi Arabia has been divided into lower, middle, and upper parts purely on lithologic grounds. Each part consists of a major lower unit of lime mudstone and a minor upper unit of grainstone. This persistent change in the limestone facies is interpreted as a reflection of repeated shoaling up in the depositional shelf environment. It is a normal marine carbonate sequence that varies in thickness from 85 to 126 m. In the Hanifa Formation, the lowermost brown ledges in the section comprise a series of coarsening upward sequences which generally terminate in a fossiliferous/peloidal packstone and grainstone and subordinately lime mudstone facies. The middle slope member is yellow, blocky weathered shale and marl. Above this slope member are several thick beds of brown-coated fossiliferous wackestone, packstone, and grainstone with the association of lime mudstone in certain levels. These are fairly resistant ledges due to the occurrence of stromatoporoids. Dedolomitization occurs in the Jubaila Formation in various textural forms which include composite calcite rhombohedra, zonal dedolomitization, regeneration of predolomitization fabric of the limestone, and coarsely crystalline calcite mosaics with or without ferric oxide rhombic zones. Rhombohedral pores commonly occur in intimate association with dolomite, possibly resulting from the leaching of calcitized dolomite rhombohedra. The regional dedolomitization was most likely brought about by calcium sulfate solutions reacting with dolomites. The source of sulfate solutions is the dissolved anhydrite deposits of the Arab–Hith Formations, sometime before their erosion, and it takes place at or near an exposed surface. The Hanifa Formation shows various diagenetic features. These include dolomitization, dedolomitization, micritization, cementation, and recrystallization. Most of the examined samples of the Hanifa carbonates are dolomitized and subsequently dedolomitized as evidenced by the presence of iron-coated dolomite rhombs partially or completely calcitized. Dolomite also occurs in the lime mudstone, wackestone, packstone, and grainstone facies, while leaching of wackestone and packstone and dedolomitization of dolomite and dolomitic limestone followed by recrystallization are common processes.     

The structure of the crust in TESZ area by kriging interpolation

A precise 3D model of the crust is necessary to start any tectonic or geodynamic interpretation. It is also essential for seismic interpretations of structures lying below as well as for correct analysis of shallow structures using reflection seismics. During the last decades, a number of wide-angle refraction experiments were performed on the territory of central and eastern Europe (POLONAISE’97, CELEBRATION 2000, SUDETES 2003), resulting in many high quality 2D models. It is an interesting and complicated transition zone between Precambrian and Palaeozoic Platforms. This paper presents 3D model of the velocity distribution in the crust and upper mantle interpolated from 2D models of the structure along 33 profiles. The obtained model extends to a depth of 50 km and accurately describes the main features of the crustal structures of Poland and surrounding areas. Different interpolation techniques (Kriging, linear) are compared to assure maximum precision. The final model with estimated uncertainty is an interesting reference of the area for other studies.