Assessment of groundwater contamination from a hazardous dump site in Ranipet, Tamil Nadu, India

Tanneries located in an industrial development area of Ranipet (India) manufactured chromate chemicals during 1976?C1996. A large quantity of associated hazardous solid wastes has been stacked about 5-m high above ground level, spread over 3.5?ha inside one of the factory premises. The study area receives an average annual rainfall of 1,100?mm. The granitic formation in the northern part of Palar River catchment has high infiltration rates and has resulted in fast migration of the contamination to the water table. Chromium levels in the groundwater were found up to 275?mg/l. The available hydrogeological, geophysical and groundwater quality data bases have been used to construct a groundwater flow and mass transport model for assessing the groundwater contamination and it has been calibrated for the next 30?years. The migration has been found to be very slow, with a groundwater velocity of 10?m/year. This is the first field-scale study of its kind in this industrial area. The findings are of relevance to addressing the groundwater pollution due to indiscriminate disposal practices of hazardous waste in areas located on the phreatic aquifer. Further, it has been reported that the untreated effluent discharge adjacent to the chromium dump site is most influential in the migration of contaminants.     

Multivariate statistical analysis for assessment of groundwater quality in Talcher Coalfield area, Odisha

In order to assess the impact of coal mining on groundwater quality in Talcher Coalfield area, seventeen groundwater samples for pre and post monsoon seasons were collected from borewells/dugwells and analysed for major ions and trace elements. Water quality analysis of major ions and trace elements shows elevated concentration in few groundwater samples. The water quality data was analysed using multivariate statistical techniques viz., factor analysis and cluster analysis. The result clearly shows that the variation in the season is due to recharge of rain water during monsoon. The factor and cluster analysis brought out impact of intensity by mining activity on groundwater regime. Discharge of mining seepage effluents and its interaction with the groundwater contaminate the surrounding groundwater regime. Multivariate statistical techniques are potential tools and provide greater precision for identifying contaminant parameters linkages with mining environment.     

Unusual circulation pattern during Indian summer monsoon failure in July 2002 and June 2009

The circulation patterns over the Indian Ocean and the surrounding continents have been studied during June 2009 and July 2002 to explain the failure of Indian summer monsoon (ISM) rainfall. This study presents evidences that the failure of the ISM during these 2?months was probably due to the development of cyclonic circulation anomaly over the Western Asia and anticyclonic circulation anomalies downstream of Eastern Asia. These circulation anomalies were associated with the equatorward advection of cold air up to 10°N. This may be due to the equatorward intrusion of midlatitude Rossby waves. We hypothesize that the intrusion of midlatitude Rossby wave is responsible for breaking the east?Cwest circulation cell over the Indian region into two cells and weakening it. The weak east?Cwest cell reduces the strength of the easterly wind field usually present over the monsoonal region, thus reducing the cross-equatorial moisture transport into the Indian subcontinent and decreasing monsoon rainfall.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

M5 model tree based modelling of reference evapotranspiration

This paper investigates the potential of M5 model tree based regression approach to model daily reference evapotranspiration using climatic data of Davis station maintained by California irrigation Management Information System (CIMIS). Four inputs including solar radiation, average air temperature, average relative humidity, and average wind speed whereas reference evapotranspiration calculated using a relation provided by the CIMIS was used as output. To compare the performance of M5 model tree in predicting the reference evapotranspiration, FAO–56 Penman–Monteith equation and calibrated Hargreaves–Samani relation was used. A comparison of results suggests that M5 model tree approach works well in comparison to both FAO–56 and calibrated Hargreaves–Samani relations. To judge the generalization capability of M5 model tree approach, model created by using the Davis data set was tested with the datasets of four different sites. Results from this part of the study suggest that M5 model tree could successfully be employed in modeling the reference evapotranspiration. Further, sensitivity analysis with M5 model tree approach suggests the suitability of solar radiation, average air temperature, average relative humidity, and average wind speed as input parameters to model the reference evapotranspiration Copyright © 2009 John Wiley & Sons, Ltd.     

Study of thermal properties of supraglacial debris and degree-day factors on Lirung Glacier,Nepal

The extensive debris that covers glaciers in the ablation zone of the Himalayan region plays an important part in regulating ablation rates and water availability for the downstream region. The melt rate of ice is determined by the amount of heat conducted through debris material lying over the ice. This study presents the vertical temperature gradients, thermal properties in terms of thermal diffusivity and thermal conductivity, and positive degree-day factors for the debris-covered portion of Lirung Glacier in Langtang Valley, Nepal Himalaya using field-based measurements from three different seasons.Field measurements include debris temperatures at different debris thicknesses, air temperature, and ice melt during the monsoon(2013), winter(2013), and pre-monsoon(2014) seasons. We used a thermal equation to estimate thermal diffusivity and thermal conductivity, and degree-day factors(DDF) were calculated from cumulative positive temperature and ice melt of the measurement period. Our analysis of debris temperature profiles at different depths of debris show the daily linear gradients of-20.81 °C/m, 4.05 °C/m, and-7.79 °C/m in the monsoon, winter, and pre-monsoon seasons, respectively. The values of thermal diffusivity and thermal conductivity in the monsoon season were 10 times greater than in the winter season. The large difference in these values is attributed to surface temperature and moisture content within the debris. Similarly, we found higher values of DDFs at thinner debris for the pre-monsoon season than in the monsoon season although we observed less melting during the pre-monsoon season. This is attributed to higher cumulative temperature during the monsoon season than in the pre-monsoon season. Our study advances our understanding of heat conductivity through debris material in different seasons, which supports estimating ice melt and discharge from glacierized river basins with debris-covered glaciers in the Himalayan region.     

Monitoring and modelling of urban sprawl using remote sensing and GIS techniques

The concentration of people in densely populated urban areas, especially in developing countries, calls for the use of monitoring systems like remote sensing. Such systems along with spatial analysis techniques like digital image processing and geographical information system (GIS) can be used for the monitoring and planning purposes as these enable the reporting of overall sprawl at a detailed level.     

Palyno-petrographical facet and depositional account of Gondwana sediments from East Bokaro coalfield,Jharkhand

Palynological and petrological studies have been undertaken on the Gondwana coal and associated lithologies encountered in borehole EBM-2 of East Bokaro coalfield of Damodar Basin, India. The palynological investigation resulted in the recognition of Assemblage–III (Densipollenites, 27.9 m–214.30 m), Assemblage–II (Striatopodocarpites + Faunipollenites, 225.00 m–297.60 m) and Assemblage–I (Faunipollenites + Scheuringipollenites, 307.00m–433.00 m). Lithofacies study was also done for better understanding of the preservation and abundance/paucity of the spores and pollen in different lithologies as the current borehole has significant thickness of mudstones, shales and siltstone. Palynofacies study and Petrographical studies of coal samples encountered in the borehole were used to determine the depositional environment of the coal precursor peat swamp. Palynological data has revealed the presence of younger Raniganj palynoflora between 27.00-214.30 m depth that is lithologically defined as Barren Measures Formation. This spore pollen study has proved that these sediments were deposited during late early Permian to late Permian period. Further the maceral analysis of organic sediments as well as the Thermal Alteration Index (TAI) has revealed that the coaly shale at 336.5 m depth has hydrocarbon generation potential.     

Advanced oxidation of catechol in reverse osmosis concentrate generated in leather wastewater by Cu–graphite electrode

Reverse osmosis (RO) concentrate generated from tannery was treated by advanced electrochemical oxidation using graphite electrodes. Catechol was selected as model organic pollutant in the RO concentrate. The influence of applied current density, catechol concentration, pH, temperature and inner electrode space of electrodes was investigated in electrochemical oxidation system. The optimized conditions were found to be current density (j), 100 mA/cm²; electrolysis time (t _eco), 60 min; pH, 7.0; and temperature, 25 °C at an inner electrode space, 2 cm. The average mass transport coefficient for the removal of catechol as COD was found to be 3.0 × 10^?5 m/s at optimum conditions. Faradic efficiency and specific energy consumption were also calculated for the applied current density. Further, the treatment of catechol was confirmed through Fourier transform infrared spectroscopy. Theoretical evaluation of current density suggested that the removal of catechol was controlled when supplied at above limiting applied current densities and mass transport controlled at lower of limiting current densities.     

Mapping rice-fallow cropland areas for short-season grain legumes intensification in South Asia using MODIS 250 m time-series data

The goal of this study was to map rainfed and irrigated rice-fallow cropland areas across South Asia, using MODIS 250?m time-series data and identify where the farming system may be intensified by the inclusion of a short-season crop during the fallow period. Rice-fallow cropland areas are those areas where rice is grown during the kharif growing season (June–October), followed by a fallow during the rabi season (November–February). These cropland areas are not suitable for growing rabi-season rice due to their high water needs, but are suitable for a short -season (≤3 months), low water-consuming grain legumes such as chickpea (Cicer arietinum L.), black gram, green gram, and lentils. Intensification (double-cropping) in this manner can improve smallholder farmer’s incomes and soil health via rich nitrogen-fixation legume crops as well as address food security challenges of ballooning populations without having to expand croplands. Several grain legumes, primarily chickpea, are increasingly grown across Asia as a source of income for smallholder farmers and at the same time providing rich and cheap source of protein that can improve the nutritional quality of diets in the region. The suitability of rainfed and irrigated rice-fallow croplands for grain legume cultivation across South Asia were defined by these identifiers: (a) rice crop is grown during the primary (kharif) crop growing season or during the north-west monsoon season (June–October); (b) same croplands are left fallow during the second (rabi) season or during the south-east monsoon season (November–February); and (c) ability to support low water-consuming, short-growing season (≤3 months) grain legumes (chickpea, black gram, green gram, and lentils) during rabi season. Existing irrigated or rainfed crops such as rice or wheat that were grown during kharif were not considered suitable for growing during the rabi season, because the moisture/water demand of these crops is too high. The study established cropland classes based on the every 16-day 250?m normalized difference vegetation index (NDVI) time series for one year (June 2010–May 2011) of Moderate Resolution Imaging Spectroradiometer (MODIS) data, using spectral matching techniques (SMTs), and extensive field knowledge. Map accuracy was evaluated based on independent ground survey data as well as compared with available sub-national level statistics. The producers’ and users’ accuracies of the cropland fallow classes were between 75% and 82%. The overall accuracy and the kappa coefficient estimated for rice classes were 82% and 0.79, respectively. The analysis estimated approximately 22.3?Mha of suitable rice-fallow areas in South Asia, with 88.3% in India, 0.5% in Pakistan, 1.1% in Sri Lanka, 8.7% in Bangladesh, 1.4% in Nepal, and 0.02% in Bhutan. Decision-makers can target these areas for sustainable intensification of short-duration grain legumes.